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Influence of Glycine on Cu2+ Adsorption by Microcrystalline Gibbsite and Boehmite

Published online by Cambridge University Press:  02 April 2024

M. B. McBride
M. B. McBride*
Affiliation:
Department of Agronomy, Cornell University, Ithaca, New York 14853
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Abstract

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The adsorption of Cu2+ on microcrystalline gibbsite and boehmite from aqueous solutions having 2/1 and 5/1 glycine/Cu ratios has been studied using electron spin resonance (ESR). The presence of glycine inhibited metal adsorption on gibbsite above pH 5, apparently by reducing Cu hydrolysis. The preferred adsorbed species on gibbsite and boehmite, based upon the ESR parameters, were probably Cu(gly)+ and Cu(gly)20, respectively. In both experiments, rigidly-bound ternary complexes formed with Cu2+ simultaneously bonding to the surface and one or more ligands. A large excess of glycine destabilized the ternary complex and caused the desorption of Cu2+. The preferred orientation of the Cu complex on gibbsite suggests that the adsorption occurred at crystal steps and that the glycine molecule hydrogen bonded to hydroxyls of the (001) surface.

Keywords

AdsorptionBoehmiteCopperElectron spin resonanceGibbsiteGlycineHydrolysis
Type
Research Article
Information
Clays and Clay Minerals , Volume 33 , Issue 5 , October 1985 , pp. 397 - 402
Copyright
Copyright © 1985, The Clay Minerals Society

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