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Hybrid Films Consisting of a Clay and a Diacetylenic, Two-Photon Absorptive Dye

Published online by Cambridge University Press:  01 January 2024

Yasutaka Suzuki ,
Shoichiro Hirakawa ,
Yusuke Sakamoto ,
Jun Kawamata ,
Kenji Kamada  and
Koji Ohta
Yasutaka Suzuki
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Shoichiro Hirakawa
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Yusuke Sakamoto
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Jun Kawamata*
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Kenji Kamada
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, 563-8577, Japan
Koji Ohta
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, 563-8577, Japan
*
* E-mail address of corresponding author: [email protected]
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Abstract

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Hybrid films consisting of Sumecton SA smectite (SSA) and a diacetylenic two-photon absorptive dye; 1,4-bis(2,5-dimethoxy-4-{2-[4-(N-methyl)pyridinium]ethenyl}phenyl) butadiyne triflate (MPPBT) were fabricated. The MPPBT-clay composites were prepared by the cation exchange method in a dimethylsulfoxide (DMSO)-water mixed solvent. A low-light-scattering film, suitable for use in optical devices, was obtained by filtration of the dispersion of the MPPBT-clay composites. Estimation of the two-photon absorption cross-section (σ(2)) by means of the open-aperture Z-scan technique was performed using the present film. The σ(2) value of MPPBT in the film fabricated at the MPPBT loading levels vs. 20% cation exchange capacity was 1030 GM (1 GM= 1 × 1050 cm4 s photon−1 molecule−1) at an excitation wavelength of 800 nm. The value was 1.3 times greater than the maximum value of the σ(2) of MPPBT diss lved in DMSO with ut clay.

Keywords

Diacetylenic DyeFilmSynthetic SaponiteTwo-photon Absorption
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 5 , October 2008 , pp. 487 - 493
Copyright
Copyright © The Clay Minerals Society 2009

References

Akiba, M. Morinaga, N. Takizawa, H. Ogiyama, M. Ichijima, S. Tani, T. Harada, A. and Inagaki, Y., 2005 A novel chromophore with a large two-photon absorption cross-section: 2,7-bis[3-(4-N,N-dimethylaminophenyl)propenylidene]cyclohepta-3,5-dien-1-one Nonlinear Optics, Quantum Optics 34 179–182.Google Scholar
Bhawalkar, J.D. Kumar, N.D. Zhao, C.-F. and Prasad, P.N., 1997 Two-photon photodynamic therapy Journal of Clinical Laser Medicine and Surgery 15 201–204 10.1089/clm.1997.15.201.CrossRefGoogle ScholarPubMed
Bujdák, J. and Iyi, N., 2002 Visible spectroscopy of cationic dyes in dispersions with reduced-charge montmorillonites Clays and Clay Minerals 50 446–454 10.1346/000986002320514172.CrossRefGoogle Scholar
Bujdák, J. and Iyi, N., 2006 Molecular aggregation of rhodamine dyes in dispersions of layered silicates: influence of dye molecular structure and silicate properties Journal of Physical Chemistry B 110 2180–2186 10.1021/jp0553378.CrossRefGoogle ScholarPubMed
Bujdák, J. Janek, M. Madejová, J. and Komadel, P., 2001 Methylene blue interactions with reduced-charge smectites Clays and Clay Minerals 49 244–254 10.1346/CCMN.2001.0490307.CrossRefGoogle Scholar
Carpenter, M.A. Willand, C.S. Penner, T.L. Williams, D.J. and Mukamel, S., 1992 Aggregation in hemicyanine dye Langmuir-Blodgett films: ultraviolet-visible absorption and second harmonic generation studies Journal of Physical Chemistry 96 2801–2804 10.1021/j100186a005.CrossRefGoogle Scholar
Caylor, C.L. Dobrianov, I. Kimmer, C. Thorne, R.E. Zipfel, W. and Webb, W.W., 1999 Two-photon fluorescence imaging of impurity distributions in protein crystals Physical Review E 59 3831–3834 10.1103/PhysRevE.59.R3831.CrossRefGoogle Scholar
Cumpston, B.H. Ananthavel, S.P. Barlow, S. Dyer, D.L. Ehrlich, J.E. Erskine, L.L. Heikal, A.A. Kuebler, S.M. Lee, I-YS McCord-Maughon, D. Qin, J. Röckel, H. Rumi, M. Wu, X.-L. Marder, S.R. and Perry, J.W., 1999 Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication Nature 398 51–54 10.1038/17989.CrossRefGoogle Scholar
Kamada, K. Ohta, K. Iwase, Y. and Kondo, K., 2003 Two-photon absorption properties of symmetric substituted diacetylene: drastic enhancement of the cross section near the one-photon absorption peak Chemical Physics Letters 372 386–393 10.1016/S0009-2614(03)00413-5.CrossRefGoogle Scholar
Kamada, K. Tanamura, Y. Ueno, K. Ohta, K. and Misawa, H., 2007 Enhanced two-photon absorption of chromophores confined in two-dimensional nanospace Journal of Physical Chemistry C 111 11193–11198 10.1021/jp072103a.CrossRefGoogle Scholar
Kawamata, J. and Hasegawa, S., 2006 Clay-assisted disaggregation and stabilization in hemicyanine Langmuir-Blodgett films Journal of Nanoscience and Nanotechnology 6 1620–1624 10.1166/jnn.2006.235.CrossRefGoogle ScholarPubMed
Kawamata, J. Seike, R. Higashi, T. Inada, Y. Sasaki, J. Ogata, Y. Tani, S. and Yamagishi, A., 2006 Clay templating Langmuir-Blodgett films of a nonamphiphilic ruthenium(II) complex Colloids and Surfaces A: Physicochemical and Engineering Aspects 284–285 135–139 10.1016/j.colsurfa.2005.10.092.CrossRefGoogle Scholar
Kawata, S. Sun, H.-B. Tanaka, T. and Takada, K., 2001 Finer features for functional microdevices Nature 412 697–698 10.1038/35089130.CrossRefGoogle ScholarPubMed
Kuang, W. Facey, G.A. Detellir, C. Casal, B. Serratosa, J.M. and Ruiz-Hitzky, E., 2003 Nanostructured hybrid materials formed by sequestration of pyridine molecules in the tunnels of sepiolite Chemistry of Materials 15 4956–4967 10.1021/cm034867i.CrossRefGoogle Scholar
Lee, K.-S. Yang, H. Lee, J.H. Kim, O. Woo, H.Y. Choi, H. Cha, M. and Blanchard-Desce, M., 2003 Optical power limiting properties of two-photon absorbing fluorene and dithieno-thiophene-based chromophores Proceedings of SPIE — The International Society for Optical Engineering 4991 175–182.Google Scholar
Lei, H. Wang, H.Z. Wei, Z.C. Tang, X.J. Wu, L.Z. Tung, C.H. and Zhou, G.Y., 2001 Photophysical properties and TPA optical limiting of two new organic compounds Chemical Physics Letters 333 387–390 10.1016/S0009-2614(00)01381-6.CrossRefGoogle Scholar
Ogawa, K. Ohashi, A. Kobuke, Y. Kamada, K. and Ohta, K., 2005 Two-photon absorption properties of self-assemblies of butadiyne-linked bis(imidazolylporphyrin) Journal of Physical Chemistry B 109 22003–22012 10.1021/jp054444z.CrossRefGoogle ScholarPubMed
Reinhardt, B.A. Brott, L.L. Clarson, S.J. Dillard, A.G. Bhatt, J.C. Kannan, R. Yuan, L. He, G.S. and Prasad, P.N., 1998 Highly active two-photon dyes: design, synthesis, and characterization toward application Chemistry of Materials 10 1863–1874 10.1021/cm980036e.CrossRefGoogle Scholar
Screen, T.E.O. Thorne, J.R.G. Denning, R.G. Bucknall, D.G. and Anderson, H.L., 2002 Amplified optical non-linearity in a self-assembled double-strand conjugated porphyrin polymer ladder Journal of the American Chemical Society 124 9712–9713 10.1021/ja026205k.CrossRefGoogle Scholar
Sheik-Bahae, M. Said, A.A. Wei, T.-H. Hagan, D.J. and Stryland, E.W.V., 1990 Sensitive measurement of optical nonlinearities using a single beam IEEE Journal of Quantum Electronics 26 760–769 10.1109/3.53394.CrossRefGoogle Scholar
Spangler, C.W., 1999 Recent development in the design of organic materials for optical power limiting Journal of Materials Chemistry 9 2013–2020 10.1039/a902802a.CrossRefGoogle Scholar
Sun, H.-B. Matsuo, S. and Misawa, H., 1999 Three-dimensional photonic crystal structures achieved with two-photon-absorption photopolymerization of resin Applied Physics Letters 74 786–788 10.1063/1.123367.CrossRefGoogle Scholar
Takagi, S. Shimada, T. Eguchi, M. Yui, T. Yoshida, H. Tryk, D.A. and Inoue, H., 2002 High-density adsorption of cationic porphyrins on clay layer surfaces without aggregation: the size-matching effect Langmuir 18 2265–2272 10.1021/la011524v.CrossRefGoogle Scholar
Takagi, S. Eguchi, M. Tryk, D.A. and Inoue, H., 2006 Porphyrin photochemistry in inorganic/organic hybrid materials: clays, layered semiconductors, nanotubes, and mesoporous materials Journal of Photochemistry and Photobiology C 7 104–126 10.1016/j.jphotochemrev.2006.04.002.CrossRefGoogle Scholar
Woo, H.Y. Liu, B. Kohler, B. Korystov, D. Mikhailovsky, A. and Bazan, G.C., 2005 Solvent effects on the two-photon absorption of distyrylbenzene chromophores Journal of the American Chemical Society 127 14721–14729 10.1021/ja052906g.CrossRefGoogle ScholarPubMed
Zugel, S.A. Burke, B.J. Regnier, F.E. and Lytle, F.E., 2000 Electrophoretically mediated microanalysis of leucine aminopeptidase using two-photon excited fluorescence detection on amicrochip Analytical Chemistry 72 5731–5735 10.1021/ac000801k.CrossRefGoogle Scholar