Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-23T07:25:41.340Z Has data issue: false hasContentIssue false
  • English
  • Français

Fourier Transform Raman Spectroscopy of Kaolinite, Dickite and Halloysite

Published online by Cambridge University Press:  28 February 2024

Ray L. Frost
Ray L. Frost*
Affiliation:
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, 2 George St, Brisbane, GPO box 2434 Qld 4001, Australia
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The vibrational modes of clay minerals are uniquely accessible to FT Raman spectroscopy, but this potentially powerful technique has found limited application to the study of clay mineral structure. Raman spectra in the 50 to 3800 cm−1 region were obtained for a number of kandite clays. The kandite clay minerals are characterised by relatively intense bands centred at 142.7 cm−1 for kaolinite, 143 cm−1 for halloysite and 131.2 cm−1 for dickite with prominent shoulders at 129, 127, and 120 cm−1 respectively. These vibrational modes are attributed to the O-Al-O and O-Si-O symmetric bends. Differences in the lattice modes for the kandite clay minerals in the 200 to 1200 cm−1 were obtained. Four OH bands were obtained for kaolinite 3621, 3652, 3668, and 3695 cm−1; three OH bands were found for a selection of dickites and halloysites. The San Juan Dickite and the Eureka Halloysite show further resolution of the low frequency 3620 cm−1 hydroxyl band. This splitting is attributed to variation in the position of the inner hydroxyls. Variation in band intensity and position was found to be sample dependent.

Keywords

DickiteFT Raman spectroscopyHalloysiteInfrared spectroscopyKandite clayKaolinite
Type
Research Article
Information
Clays and Clay Minerals , Volume 43 , Issue 2 , April 1995 , pp. 191 - 195
Copyright
Copyright © 1995, The Clay Minerals Society

References

Balachandran, U., and Eror, N. G. 1982 . Raman spectrum of titanium dioxide. Journal of Solid State Chemistry 42: 276–282.CrossRefGoogle Scholar
Chase, D. B., 1986. Fourier Raman transform spectroscopy. J. Am. Chem. Soc. 108: 7485–7488.CrossRefGoogle Scholar
Cutler, D. J., 1990. Fourier Transform raman instrumentation. Spectrochimica Acta 46A: 131–151.CrossRefGoogle Scholar
Farmer, V. C., 1974. The layer silicates: Ch 15. In Infrared Spectra of Minerals. Farmer, V. C., ed. London: Mineralogical Society, 331–363.CrossRefGoogle Scholar
Frost, R. L., Bartlett, J. R., and Fredericks, P. M. 1993 . Fourier transform Raman spectra of kandite clays. Spectrochimica Acta 49A: 667–674.CrossRefGoogle Scholar
Frost, R. L., Fredericks, P. M., Collins, B. M., Vassallo, A. J., and Finnie, K. A. . Infrared emission spectroscopy of clay minerals and their thermal transformations. The Proceedings of the 10th International Clay Conference. Fitzpatrick, R. W., Churchman, G. J., and Eggleton, T., 1994 eds. Adelaide, Australia (in press).Google Scholar
Frost, R. L., and Vassallo, A. J. 1994 . Dehydroxylation of the kandite and imogolite clay minerals. 14th Australian Clay Minerals Conference, Kalgoorie, Australia.Google Scholar
Ishii, M., Shimanouchi, T., and Nakahira, M. 1967 . Far infrared absorption of layer silicates. Inorg. Chim. Acta 1: 387–392.CrossRefGoogle Scholar
Johnston, C. T., Sposito, G., and Birge, R. R. 1985 . Raman spectroscopic study of kaolinite in aqueous suspension. Clays & Clay Miner. 33: 483–489.CrossRefGoogle Scholar
Johnston, C. T., Agnew, S. F., and Bish, D. L. 1990 . Polarised single crystal Fourier Transform infrared microscopy of Ouray dickite and Keokuk kaolinite. Clays & Clay Miner. 38: 573–583.CrossRefGoogle Scholar
Lazarev, A. N., 1972. Vibrational Spectra and Structure of Silicates. New York: Plenum Press, 123–124.Google Scholar
Ledoux, R. L., and White, J. L. 1964 . Infrared study of selective deuteration of kaolinite and halloysite at room temperature. Science 145: 47–49.CrossRefGoogle ScholarPubMed
Ohsaka, T., Izumu, F., and Fujiki, Y. 1978 . Raman spectrum of anatase, TiO2. J. Raman Spec. 7: 321–324.CrossRefGoogle Scholar
Pajcini, V., and Dhamelincourt, P. 1994 . Raman study of OH-stretching vibrations in kaolinite at low temperature. App. Spec. 48: 638–641.CrossRefGoogle Scholar
Prost, R., Damene, A. S., Huard, E., Driard, J., and Leydecker, J. P. 1989 . Infrared study of structural OH in kaolinite, dickite and nacrite and poorly crystalline kaolinite at 5 to 600K. Clays & Clay Miner. 37: 464–468.CrossRefGoogle Scholar
Rouxhet, P. G., Samudacheata, N., Jacobs, H., and Anton, O. 1977 . Attribution of the OH stretching bands of kaolinite. Clay Miner. 12: 171–178.CrossRefGoogle Scholar
Wada, K., 1967. A study of hydroxyl groups in kaolin minerals utilising selective deuteration and infrared spectroscopy. Clay Miner. 7: 51–61.CrossRefGoogle Scholar
White, J. L., Laycock, A., and Cruz, M. 1970 . Infrared studies of proton delocalisation in kaolinite. Bull Groupe Franc. Argiles 22: 157–165.CrossRefGoogle Scholar
Wiewiora, A., Wieckowski, T., and Sokolowska, A. 1979 . The Raman spectra of kaolinite subgroup minerals and of pyrophyllite. Arch. Mineral. 135: 5–14.Google Scholar
Vassallo, A. M., Cole-Clarke, P. A., Pang, L. S. K., and Palmisano, A. 1992 . Infrared emission spectroscopy of coal minerals and their thermal transformations. J. Appl. Spectrosc. 46: 73–78.CrossRefGoogle Scholar