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Firing Tests on Clay-Rich Raw Materials from the Algarve Basin (Southern Portugal): Study of Mineral Transformations with Temperature

Published online by Cambridge University Press:  01 January 2024

Maria José Trindade ,
Maria Isabel Dias ,
João Coroado  and
Fernando Rocha
Maria José Trindade*
Affiliation:
Institute Tecnológico e Nuclear EN 10, 2686-953 Sacavém, Portugal GeoBioTec — GeoBiociências, Geotecnologias e GeoEngenharias, Universidade de Aveiro, Portugal
Maria Isabel Dias
Affiliation:
Institute Tecnológico e Nuclear EN 10, 2686-953 Sacavém, Portugal GeoBioTec — GeoBiociências, Geotecnologias e GeoEngenharias, Universidade de Aveiro, Portugal
João Coroado
Affiliation:
Departamento Arte, Conservação e Restaura, Institute Politécnico de Tornar, 2300-313 Tornar, Portugal GeoBioTec — GeoBiociências, Geotecnologias e GeoEngenharias, Universidade de Aveiro, Portugal
Fernando Rocha
Affiliation:
Departamento de Geociências, Universidade de Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal GeoBioTec — GeoBiociências, Geotecnologias e GeoEngenharias, Universidade de Aveiro, Portugal
*
* E-mail address of corresponding author: [email protected]
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Abstract

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In cases where the provenance of raw materials used in the manufacture of local archeological ceramics is of interest, a detailed study of thermal transformations of minerals may be useful. The purpose of this study was to measure mineralogical transformations of different types of clays obtained during experimental firing runs, carried out at different temperatures, with the main goal of establishing Algarve reference groups based on the composition of raw material and high-temperature mineralogy, which may be compared with ceramics in studies of provenance. Eleven samples of clay-rich raw materials from the Algarve Basin (southern Portugal) were fired to temperatures ranging from 300 to 1100°C in increments of 100°C under oxidizing conditions. These were chosen to have variable chemical and mineralogical compositions, representing the main compositional range of the clay deposits from the region. Mineralogical and geochemical characterizations of the original clays were carried out by X-ray diffraction (XRD) and X-ray fluorescence (XRF), respectively. Mineral transformations on the fired products were also studied by XRD.

Three groups of clays were distinguished according to the type of neoformed high-temperature minerals: (1) non-calcareous clays; (2) clays containing calcite as the only carbonate; and (3) clays with dolomite or dolomite + calcite. Firing of non-calcareous clays produced mullite at 1100–1200°C. Gehlenite and wollastonite formed by firing calcite-rich clays above 900°C, accompanied by anorthite or larnite in samples with small or large calcite contents, respectively. Firing of dolomite-rich clays at temperatures >900°C yielded a member of the gehlenite-åkermanite group and diopside. Anorthite, enstatite, periclase, forsterite, and monticellite may also form in the firing products.

Keywords

Algarve BasinClaysFiring TestsHigh-temperature MineralsMineral TransformationsX-ray Diffraction
Type
Article
Information
Clays and Clay Minerals , Volume 58 , Issue 2 , April 2010 , pp. 188 - 204
Copyright
Copyright © Clays and Clay Minerals 2010

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