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Experimental Study on the Formation of Zeolites from Obsidian by Interaction with NaOH and KOH Solutions at 150 and 200 °C

Published online by Cambridge University Press:  28 February 2024

Motoharu Kawano  and
Katsutoshi Tomita
Motoharu Kawano
Affiliation:
Department of Environmental Sciences and Technology, Faculty of Agriculture, Kagoshima University, 1-21-24 Korimoto, Kagoshima 890, Japan
Katsutoshi Tomita
Affiliation:
Institute of Earth Sciences, Faculty of Science, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890, Japan
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Abstract

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Experimental alteration of obsidian was performed in 0.001 to 0.5 N NaOH and KOH solutions at 150 and 200 °C for 1 to 30 d. The products were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive X-ray analysis (EDX). Changes in chemical composition and pH value of solutions during the reactions were also measured. As the pH of reacting solutions was increased, smectite, phillipsite and rhodesite crystallized progressively in NaOH solutions, while smectite, merlinoite and sanidine grew successively in KOH solutions. In addition, a small amount of less-soluble, poorly ordered boehmite was present as products of all the experiments. Smectite mainly appeared at slightly high pH, Si/Al and Na/K conditions, whereas rhodesite should be produced in extremely high pH, Na/K and Si/Al conditions. Sanidine was also formed in conditions of very high pH and Si/Al and very low Na/K. In intermediate conditions of pH and Si/Al, crystallization of phillipsite was stimulated in solutions of Na/K > 10, while formation of merlinoite was favored in conditions of Na/K < 1.

Keywords

KOH solutionMerlinoiteNaOH SolutionObsidianPhillipsiteRhodesiteSanidineSmectite
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 3 , June 1997 , pp. 365 - 377
Copyright
Copyright © 1997, The Clay Minerals Society

References

Alberti, A. Hentschel, G. and Vezzalini, G., (1979) Amicite, a new natural zeolite Neues Jahrb Mineral Monatsh 481–488.Google Scholar
Barrer, R.M., (1982) Hydrothermal chemistry of zeolites London Academic Pr..Google Scholar
Barrer, R.M. and Baynham, J.W., (1956) Hydrothermal chemistry of the silicates. Part VII. Synthetic potassium aluminosilicates J Chem Soc (London) 2882–2892.Google Scholar
Barrer, R.M. Baynham, J.W. Bultitude, F.W. and Meier, W.M., (1959) Hydrothermal chemistry of the silicates. Part VIII. Lowtemperature crystal growth of aluminosilicates, and of some gallium and germanium analogues J Chem Soc (London) 195–208.Google Scholar
Barth-Wirsching, U. and Höller, H., (1989) Experimental studies on zeolite formation conditions Eur J Mineral 1 1–506 10.1127/ejm/1/4/0489.CrossRefGoogle Scholar
Boles, J.R., Kallo, D. and Sherry, H.S., (1988) Occurrences of natural zeolites—Present status and future research Occurrence, properties and utilization of natural zeolites Budapest Akademiai Kiado 3–18.Google Scholar
Burnham, C.W., (1991) LCLSQ: Lattice parameter refinment using correction terms for systematic errors Am Mineral 76 76–664.Google Scholar
Burriesci, N. Crisafulli, M.L. Giordano, N. Bart, J.C.J. and Polizzotti, G., (1984) Hydrothermal synthesis of zeolites from low-cost natural silica-alumina sources Zeolites 4 4–388.CrossRefGoogle Scholar
Chermak, J.A., (1992) Low temperature experimental investigation of the effect of high pH NaOH solutions on the opalinus shale, Switzerland Clays Clay Miner 40 650–658 10.1346/CCMN.1992.0400604.CrossRefGoogle Scholar
Chermak, J.A., (1993) Low temperature experimental investigation of the effect of high pH KOH solutions on the opalinus shale, Switzerland Clays Clay Miner 41 365–372 10.1346/CCMN.1993.0410313.CrossRefGoogle Scholar
Colella, C. and Aiello, R., (1975) Sintesi idrotermale di zeoliti da vetro riolitico in presenza di basi miste sodico-potassiche Rend Soc Ital Miner Petrol 31 31–652.Google Scholar
Colella, C. Aiello, R. and DiLudovico, V., (1977) Sulla merlinoite sintetica Rend Soc Ital Miner Petrol 33 33–518.Google Scholar
Coombs, D.S. Ellis, A.J. Fyfe, W.S. and Taylor, A.M., (1959) The zeolite facies, with comments on the interpretation of hydrothermal syntheses Geochim Cosmochim Acta 17 53–107 10.1016/0016-7037(59)90079-1.CrossRefGoogle Scholar
De Kimpe, C.R., (1976) Formation of phyllosilicates and zeolites from pure silica-alumina gels Clays Clay Miner 24 24–207 10.1346/CCMN.1976.0240408.CrossRefGoogle Scholar
Donahoe, R.J. Hemingway, B.S. and Liou, J.G., (1990) Thermochem-ical data for merlinoite: 1. Low-temperature heat capacities, entropies, and enthalpies of formation at 298.15 K of six synthetic samples having various Si/Al and Na/(NaK) ratios Am Mineral 75 188–200.Google Scholar
Donahoe, R.L. and Liou, J.G., (1985) An experimental study on the process of zeolite formation Geochim Cosmochim Acta 49 49–2360 10.1016/0016-7037(85)90235-2.CrossRefGoogle Scholar
Donahoe, R.J. Liou, J.G. and Guldman, S., (1984) Synthesis and characterization of zeolites in the system Na2O-K2O-Al2O,-SiO2-H2O Clays Clay Miner 32 32–443 10.1346/CCMN.1984.0320601.CrossRefGoogle Scholar
Donahoe, R.J. Liou, J.G. and Hemingway, B.S., (1990) Thermochemical data for merlinoite: 2. Free energies of formation at 298.15 K of six synthetic samples having various Si/Al and Na/(NaK) ratios and application to saline, alkaline lakes Am Mineral 75 201–208.Google Scholar
Eugster, H.P. Jones, B.F. and Sheppard, R.A., (1967) New hydrous sodium silicates from Kenya, Oregon, and California: Possible precursors of chert [abstract] Prog Annu Meet Geol Soc Am 1967 60.Google Scholar
Gard, J.A. and Taylor, H.F.W., (1957) An investigation of two new minerals: Rhodesite and mountainite Mineral Mag 31 31–623.Google Scholar
Gottardi, G. and Galli, E., (1985) Natural zeolites New York Springer-Verlag 10.1007/978-3-642-46518-5.CrossRefGoogle Scholar
Hawkins, D.B., (1981) Kinetics of glass dissolution and zeolite formation under hydrothermal conditions Clays Clay Miner 29 29–340 10.1346/CCMN.1981.0290503.CrossRefGoogle Scholar
Hawkins, D.B. Sheppard, R.A. Gude, A.J. 3rd, Sand, L.B. and Mumpton, F.A., (1978) Hydrothermal synthesis of clinoptilonite and comments on the assemblage phillipsite-clinoptilolite-mordenite Natural zeolites: Occurrence, properties, use New York Pergamon Pr. 337–343.Google Scholar
Hay, R.L., (1963) Stratigraphy and zeolitic diagenesis of the John Day Formation of Oregon Univ Calif Pubs Sci 42 42–262.Google Scholar
Hay, R.L.. 1966. Zeolites and zeolite reactions in sedimentary rocks. Geol Soc Am Spec Paper 85. 130 p.Google Scholar
Hay, R.L., (1986) Geologic occurrence of zeolites and some associated minerals Pure Appl Chem 58 58–1342 10.1351/pac198658101339.CrossRefGoogle Scholar
Hay, R.L. and Moiola, R.J., (1963) Authigenic silicate minerals in Searler Lake, California Sedimentology 2 312–332 10.1111/j.1365-3091.1963.tb01222.x.CrossRefGoogle Scholar
Höller, H. Wirsching, U., Sand, L.B. and Mumpton, F.A., (1978) Experiments on the formation of zeolites by hydrothermal alteration of volcanic glass Natural zeolites: Occurrence, properties, use New York Pergamon Pr. 329–336.Google Scholar
Iijima, A., Ishihara, S. Kanehira, K. Sasaki, A. Sato, T. and Shimazaki, Y., (1974) Clay and zeolitic alteration zones surrounding Kuroko deposits in the Hokuriku District, northern Akita, as submarine hydrothermal-diagenetic alteration products Geology of Kuroko deposits Tokyo Soc Mining Geol Jpn. 267–289.Google Scholar
Jansen, J.C., (1991) Synthesis of zeolites Introduction to zeolite science and practice, Studies in surface science and catalysis 58 77–136 10.1016/S0167-2991(08)63601-0.CrossRefGoogle Scholar
Kawano, M. and Tomita, K., (1992) Formation of allophane and beidellite during hydrothermal alteration of volcanic glass below 200 °C Clays Clay Miner 40 40–674 10.1346/CCMN.1992.0400106.CrossRefGoogle Scholar
Kawano, M. and Tomita, K., (1995) Experimental study on the formation of clay minerals from obsidian by interaction with acid solution at 150° and 200 °C Clays Clay Miner 43 43–222.CrossRefGoogle Scholar
Kawano, M. Tomita, K. and Kamino, Y., (1993) Formation of clay minerals during low temperature experimental alteration of obsidian Clays Clay Miner 41 41–441 10.1346/CCMN.1993.0410404.CrossRefGoogle Scholar
Khomyakov, A.P. Kurova, T.A. and Muravishkaya, G.I., (1981) Merlinoite, the first discovery in the USSR Dokl Akad Nauk SSSR 256 172–174.Google Scholar
Kühl, G.H., (1969) Synthetic phillipsite Am Mineral 54 54–1612.Google Scholar
Mariner, R.H. and Surdam, R.C., (1970) Alkaninity and formation of zeolites in saline, alkaline lakes Science 170 977–980 10.1126/science.170.3961.977.CrossRefGoogle ScholarPubMed
Mountain, E.D., (1957) Rhodesite, a new mineral from the Bultfontein mine, Kimberley Mineral Mag 31 607–610.Google Scholar
Mumpton, F.A.. 1977. Mineralogy and geology of natural zeolite, Short course notes, vol. 4. Virginia: Mineral Soc Am. 233 p.CrossRefGoogle Scholar
Park, M. and Choi, J., (1995) Synthesis of phillipsite from fly ash. Clay Sci 9 219–229.Google Scholar
Passaglia, E. Pongiluppi, D. and Rinaldi, R., (1977) Merlinoite, a new mineral of the zeolite group Neues Jahrb Mineral Monatsh 355–364.Google Scholar
Sand, L.B. and Rees, L.V.C., (1980) Zeolite synthesis and crystallization Proc 5th Int Conf/Zeolites 1–9.CrossRefGoogle Scholar
Sheppard RA, Gude, A.J. 3rd. 1968. Distribution and genesis of authigenic silicate minerals in tuffs of Pleistocene Lake Tecopa, Inyo County, Californis. US Geol Surv Prof Paper 597. 38 p.Google Scholar
Sheppard, R.A. and Gude, A.J. 19693rd, Rhodesite from Trinity County, California Am Mineral 54 54–255.Google Scholar
Sheppard RA, Gude, A.J. 3rd. 1973. Zeolites and associated authigenic minerals in tuffaceous rocks of the Big Sandy Formation, Mohave County, California. US Geol Surv Prof Paper 830. 36 p.Google Scholar
Souza-Santos, P. Valleijo-Freire, A. and Souza-Santos, H.L., (1953) Electron microscope studies on the aging of amorphous colloid aluminum hydroxide Kolloid Z 133 133 107 10.1007/BF01513446.Google Scholar
Stumm, W. and Morgan, J., (1981) Aquatic chemistry: An introduction emphasizing chemical equilibria in natural waters 2nd ed. New York J Wiley.Google Scholar
Tettenhorst, R. and Hofmann, D.A., (1980) Crystal chemistry of boehmite Clays Clay Miner 28 28–380 10.1346/CCMN.1980.0280507.CrossRefGoogle Scholar
Violante, A. Gianfreda, L. and Violante, P., (1993) Effect of prolonged aging on the transformation of short-range ordered aluminum precipitation products formed in the presence of organic and inorganic ligands Clays Clay Miner 41 41–359.CrossRefGoogle Scholar
Violante, A. and Huang, P.M., (1985) Influence of inorganic and organic ligands on the formation of aluminum hydroxides and oxyhydroxides Clays Clay Miner 33 33–192 10.1346/CCMN.1985.0330303.CrossRefGoogle Scholar
Wirsching, U., (1976) Experiments on hydrothermal alteration processes of rhyolitic glass in closed and “open” system Neues Jahrb Mineral Monatsh 1976 1976 213.Google Scholar
Wirsching, U., (1981) Experiments on the hydrothermal formation of calcium zeolites Clays Clay Miner 29 29–183 10.1346/CCMN.1981.0290302.CrossRefGoogle Scholar