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Effects of Synthesis Conditions on the Thermal Stability of a Texas Montmorillonite Expanded with [Al13O4(OH)24(H2O)12]7+ Cations

Published online by Cambridge University Press:  28 February 2024

S. M. Thomas  and
M. L. Occelli
S. M. Thomas
Affiliation:
Georgia Institute of Technology, Chemistry and Biochemistry Department, Atlanta, Georgia 30332, USA
M. L. Occelli
Affiliation:
MLO Consultants, 6105 Black Water Trail, Atlanta, Georgia 30328, USA
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Abstract

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Keywords

Keggin IonsMontmorillonitesPillared ClaysPillar DensityThermal Stability
Type
Notes
Information
Clays and Clay Minerals , Volume 48 , Issue 2 , April 2000 , pp. 304 - 308
Copyright
Copyright © 2000, The Clay Minerals Society

References

Baes, C.E. and Mesmer, R.E., 1976 The Hydrolysis of Cations pmNew York, New York J.W. Wiley 112–123.Google Scholar
Bailar, J.C., 1956 The Chemistry of the Coordination Compounds New York, New York Reinhold 24–62.Google Scholar
Bottero, J.Y. Cases, J.M. Fiessinger, F. and Poirier, J.E., 1980 Studies of hydrolized aluminum chloride solutions. I. Nature of the aluminum specie and composition of aqueous solutions Journal of Physical Chemistry 84 2933–2939 10.1021/j100459a021.CrossRefGoogle Scholar
Bottero, J.Y. Tchoubar, D. Cases, J.M. and Fiessinger, F., 1982 Investigation of the hydrolysis of aqueous solution of aluminum chloride. 2. Nature and structure by small X-ray scattering Journal of Physical Chemistry 86 3667–3673 10.1021/j100215a034.CrossRefGoogle Scholar
Brossett, C. Biedermann, G. and Sillen, G., 1954 Studies on the hydrolysis of metal ions Acta Chimica Scandinavia 8 1917 10.3891/acta.chem.scand.08-1917.CrossRefGoogle Scholar
De Boer, J.H. Lippens, B.C. Linsen, B.G. Broekhoff, J.C.P. Van den Heuvel, A. and Osinga, Th J, 1966 The t-curve of multimolecular N2-adsorption Journal of Colloidal and Interface Science 21 405–414 10.1016/0095-8522(66)90006-7.CrossRefGoogle Scholar
Figueras, J., 1988 Pillared clays as catalysts Catalysis Reviews, Science and Engineering 30 457–499 10.1080/01614948808080811.CrossRefGoogle Scholar
Fitzgerald, J.J., Laden, K. and Felger, C.B., 1988 Chemistry of basic commercial aluminum hydrolysis complexes Antiperspirants and Deodorants New York Marcel Dekker Inc. 119–292.Google Scholar
Fu, G. Nazar, L.F. and Bain, A.D., 1991 Aging processes of alumina sol-gel: Characterization of new aluminum polyoxycations by Al NMR spectroscopy Chemistry of Materials 3 602–610 10.1021/cm00016a009.CrossRefGoogle Scholar
Hartman, H. Sposito, G. Yang, A. Manne, S. Gould, S.A.C. and Hansma, P., 1990 Molecular scale imaging of clay mineral surfaces with the atomic force microscope Clays and Clay Minerals 38 337–342 10.1346/CCMN.1990.0380401.CrossRefGoogle Scholar
Hsu, P. and Bates, T., 1964 Fixation of hydroxy-aluminum polymers by vermiculite Soil Science 28 763 10.2136/sssaj1964.03615995002800060025x.CrossRefGoogle Scholar
Johansson, G., 1960 On the crystal structure of some basic aluminum salts Acta Chimica Scandinavia 16 403 10.3891/acta.chem.scand.16-0403.CrossRefGoogle Scholar
Lindgreen, H. Garnaes, J. Hansen, P.L. Besenbacher, F. Laegsgaard, E S P Gould, S.A.C. and Hansma, P., 1991 Ultrafine particles of North Sea illite/smectite clay minerals investigated by STM and AFM American Mineralogist 76 1218–1222.Google Scholar
Maes, N. Zhu, H. and Vansant, E., 1995 The use of the logarithmic adsorption isotherm for the determination of the micropore size distribution Journal of Porous Materials 2 97–105 10.1007/BF00486576.CrossRefGoogle Scholar
Occelli, M.L. and Kaliaguin, S., 1989 Physicochemical properties of pillared clay catalysts Keynotes in Energy Related Catalysis Amsterdam Elsevier 101–137.Google Scholar
Occelli, M.L. Drake, B. and Gould, S.A.C., 1993 Characterization of pillared montmorillonites with the atomic force microscope Journal of Catalysis 142 337–348 10.1006/jcat.1993.1212.CrossRefGoogle Scholar
Pinnavaia, T.J., 1983 Intercalated clay catalysts Science 220 365–371 10.1126/science.220.4595.365.CrossRefGoogle ScholarPubMed
Plee, D. Borg, E. Gatineau, L. and Fripiat, J.J., 1985 Highresolution solid state Al and Si NMR study of pillared clays Journal of the American Chemical Society 107 23 10.1021/ja00294a028.CrossRefGoogle Scholar
Schoonheydt, R. Leeman, H. Scorpion, A. Lenotte, I. and Grobet, P., 1994 The Al pillaring of clays. Part II. Pillaring with [Al13O4(OH)24(H2O)12]7+ Clays and Clay Minerals 42 518–525 10.1346/CCMN.1994.0420502.CrossRefGoogle Scholar
Schutz, A. Stone, W.E.E. Poncelet, G. and Fripiat, J.J., 1987 Preparation and characterization of bidimensional zeolitic structures obtained from synthetic beidellite and hydroxy-aluminum solutions Clays and Clay Minerals 35 251–261 10.1346/CCMN.1987.0350402.CrossRefGoogle Scholar