Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-23T16:50:02.510Z Has data issue: false hasContentIssue false
  • English
  • Français

Effects of Reaction Conditions on the Formation of Todorokite at Atmospheric Pressure

Published online by Cambridge University Press:  01 January 2024

Hao-Jie Cui ,
Xiong-Han Feng ,
Ji-Zheng He ,
Wen-Feng Tan  and
Fan Liu
Hao-Jie Cui
Affiliation:
College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China
Xiong-Han Feng
Affiliation:
College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China
Ji-Zheng He
Affiliation:
Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Wen-Feng Tan*
Affiliation:
College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China
Fan Liu
Affiliation:
College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Todorokite is a common Mn oxide (with a tunnel structure) in the Earth surface environment, and can be obtained by hydrothermal treatment or refluxing process from precursor buserite with a layered structure. Several chemical reaction conditions for the phase transformation from Na-buserite to todorokite at atmospheric pressure were investigated, including temperature, pH, crystallinity of precursor Na-buserite, the amount of the interlayer Mg2+ of the Mg-buserite and clay minerals. The results showed that the conversion rate and crystallinity of todorokite decreased with falling temperature, and Mg-buserite could not be completely transformed to todorokite at lower temperatures (40°C). The poorly crystalline Na-buserite could be converted into todorokite more easily than highly crystalline Na-buserite. Todorokite can be prepared at pH 5–9, but the rate of conversion and crystallinity of todorokite did vary with pH in the order: neutral ≈ alkali > acidic. The conversion rate of todorokite decreased with decreasing interlayer Mg2+ content of the Mg-buserite. The presence of montmorillonite or goethite slowed the formation reaction of todorokite in the refluxing process, and the reaction time was prolonged when the amounts of those minerals were increased.

Keywords

BirnessiteClay MineralMn OxideTodorokiteTransformation
Type
Research Article
Information
Clays and Clay Minerals , Volume 54 , Issue 5 , October 2006 , pp. 605 - 615
Copyright
Copyright © 2006, The Clay Minerals Society

References

Al-Sagheer, F.A. and Zaki, M.L., (2004) Synthesis and surface characterization of todorokite-type microporous manganese oxides: implications for shape-selective oxidation catalysts Microporous and Mesoporous Materials 67 43–52 10.1016/j.micromeso.2003.10.005.CrossRefGoogle Scholar
Atkinson, R.J. Posner, A.M. and Quirk, J.P., (1967) Adsorption of potential determining ion on the ferric oxide-aqueous electrolyte interface Journal of Physical Chemistry B 71 550–558 10.1021/j100862a014.CrossRefGoogle Scholar
Ching, S. Krukowska, K.S. and Suib, S.L., (1999) A new synthetic route to todorokite-type manganese oxides Inorganica Chimica Acta 294 123–132 10.1016/S0020-1693(99)00208-X.CrossRefGoogle Scholar
Cui, H.J. Feng, X.H. Liu, F. Tan, W.F. and He, J.Z., (2005) Factors governing formation of todorokite at atmospheric pressure Science in China Series D Earth Sciences 48 1678–1689 10.1360/01YD0550.CrossRefGoogle Scholar
Feng, Q. Honbu, C. Yanagisawa, K. and Yamasaki, N., (1999) Hydrothermal soft chemical reaction for formation of sandwich layered manganese oxide Chemistry of. Materials 11 2444–2450 10.1021/cm990133n.CrossRefGoogle Scholar
Feng, X.H. Tan, W.F. Liu, F. Wang, J.B. and Ruan, H.D., (2004) Synthesis of todorokite at atmospheric pressure Chemistry of Materials 16 4330–4336 10.1021/cm0499545.CrossRefGoogle Scholar
Feng, X.H. Liu, F. Tan, W.F. Liu, X.W. and Hu, H.Q., (2004) Synthesis of todorokite by refluxing process and its primary characteristics Science in China Series D Earth Sciences 47 760–768 10.1360/03yd0511.CrossRefGoogle Scholar
Feng, X.H. Liu, F. Tan, W.F. and Liu, X.W., (2004) Synthesis of birnessite from the oxidation of Mn2+ by O2 in alkali medium: Effects of synthesis conditions Clays and Clay Minerals 52 240–250 10.1346/CCMN.2004.0520210.CrossRefGoogle Scholar
Feng, X.H. Tan, W.F. Liu, F. Wang, Y.J. and Xu, Y.S., (2005) Hydrothermal synthesis of todorokite and its influencing factors Earth Science Journal China University of Geosciences 30 347–352.Google Scholar
Giovanoli, R. Burki, P. Giuffredi, M. and Stumm, W., (1975) Layer structured manganese oxide hydroxides IV. The buserite group: structure stabilization by transition elements Chimia 29 517–520.Google Scholar
Golden, D.C. Chen, C.C. and Dixon, J.B., (1986) Synthesis of todorokite Science 231 717–719 10.1126/science.231.4739.717.CrossRefGoogle ScholarPubMed
Golden, D.C. Chen, C.C. and Dixon, J.B., (1987) Transformation of birnessite to buserite, todorokite and manganite under mild hydrothermal treatment Clays and Clay Minerals 35 271–280 10.1346/CCMN.1987.0350404.CrossRefGoogle Scholar
Kuma, K. Usui, A. Paplawsky, W. Gedulin, B. and Arrhenius, G., (1994) Crystal structures of synthetic 7 Å and 10 Å manganates substituted by mono- and divalent cations Mineralogical Magazine 58 425–447 10.1180/minmag.1994.058.392.08.CrossRefGoogle ScholarPubMed
Lanson, B. Drits, V.A. Silvester, E. and Manceau, A., (2000) Structure of H-exchanged hexagonal birnessite and its mechanism of formation from Na-rich monoclinic buserite at low pH American Mineralogist 85 826–838 10.2138/am-2000-5-625.CrossRefGoogle Scholar
Liu, J. Cai, J. Son, Y.C. Gao, Q. Suib, S.L. and Aindow, M., (2002) Magnesium manganese oxide nanoribbons: Synthesis, characterization, and catalytic application Journal of Physical Chemistry B 106 9761–9768 10.1021/jp0208586.CrossRefGoogle Scholar
Liu, Z.H. Kang, L. Ooi, K. Makita, Y. and Feng, Q., (2005) Studies on the formation of todorokite-type manganese oxide with different crystalline birnessites by Mg2+-templating reaction Journal of Colloid and Interface Science 285 239–246 10.1016/j.jcis.2004.11.021.CrossRefGoogle ScholarPubMed
Luo, J. Zhang, Q. Huang, A. Giraldo, O. and Suib, S.L., (1999) Double-aging method for preparation of stabilized Na-buserite and transformations to todorokites incorporated with various metals Inorganic Chemistry 38 6106–6113 10.1021/ic980675r.CrossRefGoogle ScholarPubMed
Malinger, K.A. Laubernds, K. Son, Y.C. and Suib, S.L., (2004) Effects of microwave processing on chemical, physical and catalytic properties of todorokite-type manganese oxide Chemistry of Materials 16 4296–4303 10.1021/cm049149q.CrossRefGoogle Scholar
Mellin, T.A. and Lei, G., (1993) Stabilization of 10 Å-manganates by interlayer cations and hydrothermal treatment: Implication for the mineralogy of marine manganese concretions Marine Geology 115 67–83 10.1016/0025-3227(93)90075-7.CrossRefGoogle Scholar
Naoaki, K. Shinichi, K. Hiroiki, S. and Nobuko, K., (2001) Preparation of todorokite-type manganese-based oxide and its application as lithium and magnesium rechargeable battery cathode Journal of Power Sources 97–98 515–517.Google Scholar
Post, J.E. Heaney, P.J. and Hanson, J., (2003) Synchrotron X-ray diffraction study of the structure and dehydration behavior of todorokite American Mineralogist 88 142–150 10.2138/am-2003-0117.CrossRefGoogle Scholar
Shen, Y.F. Zerger, R.P. DeGuzman, R.N. Suib, S.L. McCurdy, L. Potter, D.I. and O’Young, C.L., (1993) Manganese oxide octahedral molecular sieves: preparation, characterization and application Science 260 511–515 10.1126/science.260.5107.511.CrossRefGoogle Scholar
Shen, Y.F. Suib, S.L. and O’Young, C.L., (1994) Effects of inorganic cation templates on octahedral molecular sieves of manganese oxide Journal of American Chemical Society 116 11020–11029 10.1021/ja00103a018.CrossRefGoogle Scholar
Shen, Y.F. Suib, S.L. and O’Young, C.L., (1996) Cu containing octahedral molecular sieves and octahedral layered materials Journal of Catalysis 161 115–122 10.1006/jcat.1996.0168.CrossRefGoogle Scholar
Silvester, E. Manceau, A. and Drits, V.A., (1997) Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite: II. Results from chemical studies and EXAFS spectroscopy American Mineralogist 82 962–978 10.2138/am-1997-9-1013.CrossRefGoogle Scholar
Tan, W.F. Liu, F. Li, Y.H. He, J.Z. and Li, X.Y., (2000) Mineralogy of manganese in iron-manganese nodules of several soils in China Acta Pedologica Sinica 37 192–201.Google Scholar
Turner, S. Siegel, M.D. and Buseck, P.R., (1982) Structure features of tordorokite intergrowths in manganese nodules Nature 296 841–842 10.1038/296841a0.CrossRefGoogle Scholar
Vileno, E. Zhou, H. Zhang, Q. Suib, S.L. Corbin, D.R. and Koch, T.A., (1999) Synthetic todorokite produced by microwave heating: An active oxidation catalyst Journal of Catalysis 187 285–297 10.1006/jcat.1999.2639.CrossRefGoogle Scholar