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Effect of Surface Charge and Elemental Composition on the Swelling and Delamination of Montmorillonite Nanoclays Using Sedimentation Field-flow Fractionation and Mass Spectroscopy

Published online by Cambridge University Press:  01 January 2024

Shoeleh Assemi ,
Sugandha Sharma ,
Soheyl Tadjiki ,
Keith Prisbrey ,
James Ranville  and
Jan D. Miller
Shoeleh Assemi*
Affiliation:
Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah, USA
Sugandha Sharma
Affiliation:
Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah, USA
Soheyl Tadjiki
Affiliation:
Postnova Analytics USA, Salt Lake City, Utah, USA
Keith Prisbrey
Affiliation:
Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah, USA
James Ranville
Affiliation:
Department of Chemistry, Colorado School of Mines, Golden, Colorado, USA
Jan D. Miller
Affiliation:
Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah, USA
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The swelling properties of smectite-type clay particles (including montmorillonite) are of interest in various industries. A fundamental understanding of the surface properties of smectite particles at the sub-micron level would facilitate investigation of the effect of distributed properties such as charge and elemental composition. Swelling and delamination of SWy-2 Na-montmorillonite (Na-Mnt) nano-clay particles were studied here using size distributions obtained by sedimentation field-flow fractionation (SdFFF). Fractions were examined by electron microscopy and inductively-coupled optical emission spectroscopy (ICP-OES). Two distinct populations were observed in the size distribution of SWy-2 Na-Mnt particles (bimodal size distribution), with mean equivalent spherical diameters of ~60 nm and 250 nm, respectively. In contrast, the size distribution of STx-1 Ca-montmorillonite (Ca-Mnt) particles showed only one peak with a mean equivalent spherical diameter of ~410 nm, which changed to 440 nm after 4 days of hydration. Analyses of the fractions by ICP-OES obtained along the size distribution of Na-Mnt showed an abundance of Ca and Mg in the fractions below 250 nm, and confirmed the presence of Fe and Mg as isomorphous substituents. Electron micrographs of the fractions obtained from Na-Mnt size distributions were used to calculate the thickness of the clay particles. Bridging forces between pure orMgsubstituted montmorillonite and either Ca2+ or Na+ were calculated using semi-empirical methods. The results demonstrated that swelling and delamination of Na-Mnt clay particles are dictated by properties such as elemental composition and surface charge which are distributed along the size distribution.

Keywords

Ca-montmorilloniteDelaminationMolecular dynamics SimulationNa-montmorilloniteOptical Emission SpectroscopyParticle ThicknessSedimentation Field-flow FractionationSwelling
Type
Article
Information
Clays and Clay Minerals , Volume 63 , Issue 6 , December 2015 , pp. 457 - 468
Copyright
Copyright © The Clay Minerals Society 2015

References

Anderson, R.L. Ratcliffe, I. Greenwell, H.C. Williams, P.A. Cliffe, S. and Coveney, P.V., 2010 Clay swelling — A challenge in the oil field Earth Science Reviews 98 201–216.CrossRefGoogle Scholar
Beckett, R. and Giddings, J.C., 1997 Entropic contribution to the retention of nonspherical particles in field-flow fractionation Journal of Colloid and Interface Science 186 53–59.CrossRefGoogle Scholar
Beckett, R. Hart, B.T., Buffle, J. and van Leeuwen, H.P., 1993 Use of field-flow fractionation techniques to characterize aquatic particles, colloids, and macromolecules Environmental Particles, Volume 2 Boca Raton, Florida, USA CRC Press.Google Scholar
Beckett, R. Nicholson, G. Hotchin, D. and Hart, B., 1992 The use of sedimentation field-flow fractionation to study suspended particulate matter Hydrobiologia 235/236 697–710.CrossRefGoogle Scholar
Boek, E.S. Coveney, P.V. and Skipper, N.T., 1995 Monte Carlo modeling studies of hydrated Li-, Na-, K-smectites: understanding the role of potassium as a clay swelling inhibitor Journal of the American Chemical Society 117 12608–12617.CrossRefGoogle Scholar
Borden, D. and Giese, R.F., 2001 Baseline studies of The Clay Minerals Society Source Clays: Cation exchange capacity measurements by the ammonia-electrode method Clays and Clay Minerals 49 444–445.CrossRefGoogle Scholar
Bouby, M. Geckeis, H. and Geyer, F.W., 2008 Application of asymmetric flow field-flow fractionation (AsFlFFF) coupled to inductively coupled plasma mass spectrometry (ICPMS) to the quantitative characterization of natural colloids and synthetic nanoparticles Analytical and Bioanalytical Chemistry 392 1447–1457.CrossRefGoogle Scholar
Cadene, A. Durand-Vidal, S. Turq, P. and Brendlé, J., 2005 Study of individual Na-montmorillonite particle size, morphology, and apparent charge Journal of Colloid and Interface Science 285 719–730.CrossRefGoogle Scholar
Chiou, C.T. and Rutherford, D.W., 1997 Effects of exchanged cation and layer charge on the sorption of water and EGME vapors on montmorillonite clays Clays and Clay Minerals 45 867–880.CrossRefGoogle Scholar
Giddings, J.C., 1993 Field-flow fractionation: analysis of macromolecular, colloidal, and particulate materials Science 260 1456–1465.CrossRefGoogle ScholarPubMed
Gotz, A.W. Williamson, M.J. Xu, D. Poole, D. LeGrand, S. and Walker, R.C., 2012 Routine microsecond molecular dynamic simulations with AMBER on GPUs. 1. Generalized Born Journal of Chemical Theory Computation 8 1542–1555.CrossRefGoogle Scholar
Hanwell, M.D. Curtis, D.E. Lonie, D.C. Vendermeersch, T. Zurek, E. and Hutchinson, G.R., 2012 Avogadro, an advanced semantic chemical editor, visualization and analysis platform Journal of Cheminformatics 4 17.CrossRefGoogle ScholarPubMed
Hendricks, S.B. Nelson, R.A. and Alexander, L.T., 1940 Hydration mechanism of the clay mineral montmorillonite saturated with various cations Journal of the American Chemical Society 62 12608–12617.CrossRefGoogle Scholar
Johnston, C.T. Tombácz, E., Dixon, J.B. and Schulze, D.G., 2002 Surface chemistry of soil minerals Soil Mineralogy with Environmental Applications Madison, Wisconsin, USA Soil Science Society of America.Google Scholar
Katti, D. and Shanmugasundaram, V., 2001 Influence of swelling on the microstructure of expansive clays Canadian Geotechnology Journal 38 175–182.Google Scholar
Laird, D.A., 1999 Layer charge influences on the hydration of expandable 2:1 phylosilicates Clay and Clay Minerals 46 630–636.CrossRefGoogle Scholar
Laird, D.A., 2006 Influence of layer charge on the swelling of smectites Applied Clay Science 34 74–87.CrossRefGoogle Scholar
Liu, J. Sandaklie-Nikolova, L. Wang, X. and Miller, J.D., 2014 Surface force measurements at kaolinite edge surfaces using atomic force microscopy Journal of Colloid and Interface Science 420 35–40.CrossRefGoogle ScholarPubMed
Low, P.F., 1980 The swelling of clay: II. Montmorillonites Soil Science Society of America Journal 44 667–676.CrossRefGoogle Scholar
Low, P.F., Güven, N. and Pollastro, R.M., 1992 Interparticle forces in clay suspensions: Flocculation, viscous flow and swelling Clay-Water Interface and its Rheological Implications Boulder, Colorado, USA CMS Workshop Lectures, The Clay Minerals Society.CrossRefGoogle Scholar
Mermut, A.R. and Cano, A.F., 2001 Baseline studies of The Clay Minerals Society Source Clays: chemical analyses of major elements Clays and Clay Minerals 49 381–386.CrossRefGoogle Scholar
Michot, L.J. Bihannic, I. Porsch, K. Maddi, S. Baravian, C. Mougel, J. and Levitz, P., 2004 Phase diagrams of Wyoming Na-montmorillonite clay. Influence of particle anisotropy Langmuir 20 10829–10837.CrossRefGoogle ScholarPubMed
Norrish, K., 1954 The swelling of montmorillonite Discussions of the Faraday Society 18 120–134.CrossRefGoogle Scholar
Novik, K.E. (2000) Amber2lammps.py: convert Amber files to lammps files.Google Scholar
Plaschke, M. Schafer, T. Bundschuh, T. Ngo Manh, T. Knopp, R. Geckeis, H. and Kim, J.I., 2001 Size characterization of bentonite colloids by different methods Analytical Chemistry 73 4338–4347.CrossRefGoogle ScholarPubMed
Plimpton, S., 1995 Fast parallel algorithms for short-range molecular dynamics Journal of Computational Physics 117 1–19.CrossRefGoogle Scholar
Ranville, J.F. Chittleborough, D.J. and Beckett, R., 2005 Particle-size and element distributions of soil colloids Soil Science Society of America Journal 69 1173–1184.CrossRefGoogle Scholar
Roberson, H.E. Weir, A.H. and Woods, R.D., 1968 Morphology of particles in size-fractionated Na-montmorillonites Clays and Clay Minerals 16 239–247.CrossRefGoogle Scholar
Schneider, C.A. Rasband, W.S. and Eliceiri, K.W., 2012 NIH Image to ImageJ: 25 years of image analysis Nature Methods 9 7 671–675.CrossRefGoogle ScholarPubMed
Stewart, J.J.P., 2012 MOPAC2012 Colorado Springs, Colorado, USA Stewart Computational Chemistry.Google Scholar
Tadjiki, S. Assemi, S. Deering, C. Veranth, J.M. and Miller, J.D., 2009 Detection, separation, and quantification of unlabeled silica nanoparticles in biological media using sedimentation field-flow fractionation Journal of Nanoparticle Research 11 981–988.CrossRefGoogle Scholar
Taylor, H.E. Garbarino, J.R. Murphy, D.M. and Beckett, R., 1992 Inductively coupled plasma-mass spectrometry as an element-specific detector for field-flow fractionation particle separation Analytical Chemistry 64 2036–2041.CrossRefGoogle ScholarPubMed
v.d. Kammer, F. Baborowski, F.M. Tadjiki, S. Tümpling, W.V. Jr., 2004 Colloidal particles in sediment pore waters: Particle-size distributions and associated element size distribution in anoxic and re-oxidized samples, obtained by FFF-ICP-MS coupling Acta Hydrochimica et Hydrobiologica 31 400–410.CrossRefGoogle Scholar
van Olphen, H., 1963 An Introduction to Clay Colloid Chemistry New York Interscience Publishers.Google Scholar
Viani, B.E. Low, P.F. and Roth, C.B., 1983 Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite Journal of Colloid and Interface Science 96 229–239.CrossRefGoogle Scholar
Williams, P.S. Giddings, M.C. and Giddings, J.C., 2001 A data analysis algorithm for programmed Field-Flow Fractionation Analytical Chemistry 73 4204–4211.CrossRefGoogle ScholarPubMed
Zhang, Z.Z. and Low, P.F., 1989 Relation between the heat of immersion and the initial water content of Li-, Na-, and Kmontmorillonite Journal of Colloid and Interface Science 133 461–472.CrossRefGoogle Scholar