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The Effect of Smectite on the Corrosion of Iron Metal

Published online by Cambridge University Press:  01 January 2024

Barbara A. Balko ,
Stephanie A. Bossé ,
Anne E. Cade ,
Elise F. Jones-Landry ,
James E. Amonette  and
John L. Daschbach
Barbara A. Balko*
Affiliation:
Chemistry Department, Lewis & Clark College, Portland, OR 97219 USA
Stephanie A. Bossé
Affiliation:
Chemistry Department, Lewis & Clark College, Portland, OR 97219 USA
Anne E. Cade
Affiliation:
Chemistry Department, Lewis & Clark College, Portland, OR 97219 USA
Elise F. Jones-Landry
Affiliation:
Chemistry Department, Lewis & Clark College, Portland, OR 97219 USA
James E. Amonette
Affiliation:
Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352 USA
John L. Daschbach
Affiliation:
Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352 USA Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352 USA
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The combination of zero-valent iron (ZVI) and a clay-type amendment is often observed to have a synergistic effect on the rate of reduction reactions. In the present study, electrochemical techniques were used to determine the mechanism of interaction between the iron (Fe) and smectite clay minerals. Iron electrodes coated with an evaporated smectite suspension (clay-modified iron electrodes, CMIEs) were prepared using five different smectites: SAz-1, SWa-1, STx-1, SWy-1, and SHCa-1. All the smectites were exchanged with Na+ and one sample of SWy-1 was also exchanged with Mg2+. Potentiodynamic polarization scans and cyclic voltammograms were taken using the CMIEs and uncoated but passivated Fe electrodes. These electrochemical experiments, along with measurements of the amount of Fe2+ and Fe3+ sorbed in the smectite coating, suggested that the smectite removed the passive layer of the underlying Fe electrode during the evaporation process. Cyclic voltammograms taken after the CMIEs were biased at the active-passive transition potential for varying amounts of time suggested that the smectite limited growth of a passive layer, preventing passivation. These results are attributed to the Brønsted acidity of the smectite as well as to its ability to sorb Fe cations. Oxides that did form on the surface of the Fe in the presence of the smectite when it was biased anodically were reduced at a different electrochemical potential from those that form on the surface of an uncoated Fe electrode under otherwise similar conditions; this difference suggested that the smectite reacted with the Fe2+ formed from the oxidation of the underlying Fe. No significant correlation could be found between the ability of the smectite to remove the Fe passive film and the smectite type. The results have implications for the mixing of sediments and Fe particles in permeable reactive barriers, underground storage of radioactive waste in steel canisters, and the use of smectite supports in preventing aggregation of nano-sized zero-valent iron.

Keywords

Clay BarrierFe-Clay InteractionsFe CorrosionMontmorillonitePermeable Reactive BarrierSmectiteZero-Valent Iron
Type
Article
Information
Clays and Clay Minerals , Volume 60 , Issue 2 , April 2012 , pp. 136 - 152
Copyright
Copyright © Clay Minerals Society 2012

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