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Effect of Clay Mineralogy and Aluminum and Iron Oxides on the Hydraulic Conductivity of Clay-Sand Mixtures

Published online by Cambridge University Press:  02 April 2024

N. Alperovitch ,
I. Shainberg ,
R. Keren  and
M. J. Singer
N. Alperovitch
Affiliation:
Institute of Soils and Water, Agricultural Research Organization, The Volcani Center, P.O. Box 6, Bet-Dagan, Israel
I. Shainberg
Affiliation:
Institute of Soils and Water, Agricultural Research Organization, The Volcani Center, P.O. Box 6, Bet-Dagan, Israel
R. Keren
Affiliation:
Institute of Soils and Water, Agricultural Research Organization, The Volcani Center, P.O. Box 6, Bet-Dagan, Israel
M. J. Singer
Affiliation:
Department of Land, Air, and Water Resources, University of California, Davis, California 95616
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Abstract

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Changes in hydraulic conductivity and clay dispersivity of clay-sand mixtures (four reference smectites and Fithian illite) as a function of concentration (0.01 M Cl− and distilled water) and sodium adsorption ratio (SAR ≤ 30) of the percolating solution were measured. In addition, the effect of sand percentage, sand particle size, and addition of AlCl3 and FeCl3 on the hydraulic conductivity of the mixtures were measured.

Clay dispersion and migration out of the 3% clay columns was substantial. The clay dispersed only in the distilled water system; dispersion increased with an increase in the percentage of exchangeable Na and was about the same for the Wyoming montmorillonite and Fithian illite. Conversely, the clay swelled in the 0.01 M Cl− solution. The swelling of the montmorillonites increased in the order: Upton, Wyoming = Belle Fourche, South Dakota > Polkville, Mississippi > Otay, California, and was higher than that of the Fithian illite. The swelling and dispersion of the clay accounted for the changes in hydraulic conductivity.

Mixtures treated with FeCl3 and AlCl3 were leached with NaCl-CaCl2 solutions until the pH of the effluent exceeded 6.5. The composition of the exchangeable phase was then determined by the SAR of the leach solutions. At pH > 6.5, the polycations hydrolyzed and were present as the hydroxy-polymer species. The hydraulic conductivity of the mixtures decreased as exchangeable Na increased, but the decrease was less than in untreated mixtures, AlCl3 was more effective in maintaining hydraulic conductivity than FeCl3. In montmorillonite clay with an ESP of 20, less than 5% of a complete Al-interlayer was enough to prevent a reduction in hydraulic conductivity. Packets in the day systems tested explain the high efficiency of the Fe and Al polycations.

Keywords

Aluminum oxideExchangeable sodium percentageHydraulic conductivityIlliteIron oxideMontmorilloniteSalinitySand
Type
Research Article
Information
Clays and Clay Minerals , Volume 33 , Issue 5 , October 1985 , pp. 443 - 450
Copyright
Copyright © 1985, The Clay Minerals Society

Footnotes

1

Contribution No. 1274-E 1984 series from the Agricultural Research Organization, The Volcani Center, Bet-Dagan, Israel.

References

Alperovitch, N., Shainberg, I. and Keren, R., 1981 Specific effect of magnesium on the hydraulic conductivity of sodic soils J. Soil Sei. 32 543–554.CrossRefGoogle Scholar
Bamhisel, R. I., Dixon, J. B. and Weed, S. B., 1977 Chlorites and hydroxy interlayered vermiculite and smectite Minerals in Soil Environment Wisconsin Soil Sei. Soc. Amer., Madison 331–356.Google Scholar
Carstea, D. D., Harward, M. E. and Knox, E. G., 1970 Comparison of Fe and Al hydroxy interlayers in mont- morillonite and vermiculite: I. Formation Soil Sei. Soc. Amer. Proc. 34 517–521.CrossRefGoogle Scholar
Deshpande, T. L., Greenland, D. J. and Quirk, J. P., 1968 Changes in soil properties associated with the removal of iron and aluminum oxides J. Soil Sei. 19 108–122.CrossRefGoogle Scholar
El Rayah, H. M. E. and Rowell, D. L., 1973 The influence of Fe and Al hydroxides on the swelling of montmorillonite and the permeability of a Na-soil J. Soil Sci. 24 137–144.CrossRefGoogle Scholar
Felhendler, R., Shainberg, I. and Frenkel, H., 1974 Dispersion and hydraulic conductivity of soils in mixed solution Trans. 10th Int. Congr. Soil Sci., 1974, Moscow Moscow Nauka Publ. House 103–112.Google Scholar
Frenkel, H., Goertzen, J. O. and Rhoades, J. D., 1978 Effects of clay type and content, exchangeable sodium percentage, and electrolyte concentration on clay dispersion and soil hydraulic conductivity Soil Sci. Soc. Amer. J. 42 32–39.CrossRefGoogle Scholar
Frenkel, H. and Shainberg, I., 1980 The effect of hydroxy Al and Fe polymers on montmorillonite particle size Soil Sci. Soc. Amer. 44 624–628.CrossRefGoogle Scholar
Keren, R., 1980 Effects of titration rate, pH and drying process on cation exchange capacity reduction and aggregate size distribution of montmorillonite hydroxy-Al complexes Soil Sci. Soc. Amer. J. 44 1209–1212.CrossRefGoogle Scholar
Low, P. F., 1980 The swelling of clay: II. Montmorillonites Soil Sci. Soc. Amer. J. 44 667–676.CrossRefGoogle Scholar
Low, P. F. and Margheim, J. F., 1979 The swelling of clay: basic concepts and empirical equations Soil Sci. Soc. Amer. J. 43 473–481.CrossRefGoogle Scholar
McNeal, B. L. and Coleman, N. T., 1966 Effect of solution composition on soil hydraulic conductivity Soil Sci. Soc. Amer. Proc. 30 308–312.CrossRefGoogle Scholar
McNeal, B. L., Layfield, D. A., Norvell, W. A. and Rhoades, J. D., 1968 Factors influencing hydraulic conductivity of soils in the presence of mixed-salt solutions Soil Sci. Soc. Amer. Proc. 32 187–190.CrossRefGoogle Scholar
Oades, J. M., 1984 Interactions of polycations of Al and Fe with clays Clays & Clay Minerals 32 49–57.CrossRefGoogle Scholar
Oster, J. D., Shainberg, I. and Wood, J. D., 1980 Flocculation value and gel structure of Na/Ca montmorillonite and illite suspension Soil Sci. Soc. Amer. J. 44 955–959.CrossRefGoogle Scholar
Pupisky, H. and Shainberg, I., 1979 Salt effects on the hydraulic conductivity of a sandy soil Soil Sci. Soc. Amer. J. 43 429–433.CrossRefGoogle Scholar
Quirk, J. P. and Schofield, R. K., 1955 The effect of electrolyte concentration on soil permeability J. Soil Sci. 6 163–178.CrossRefGoogle Scholar
Rhoades, J. D., 1972 Quality of water for irrigation Soil Sci. 113 277–284.CrossRefGoogle Scholar
Shainberg, I. and Letey, J., 1984 Response of soils to sodic and saline conditions Hilgardia 52 1–57.CrossRefGoogle Scholar
Shainberg, I., Rhoades, J. D. and Prather, R.J., 1981 Effect of low electrolyte concentration on clay dispersion and hydraulic conductivity of a sodic soil Soil Sci. Soc. Amer. J. 45 273–277.CrossRefGoogle Scholar
U.S. Salinity Laboratory Staff (1954) Diagnosis and improvement of saline and alkali soils: U.S. Dept. Agric. Handbk. 60, 160 pp.Google Scholar
Velasco-Molina, H. A., Swoboda, R. and Godfrey, C. L., 1971 Dispersion of soils of different mineralogy in relation to sodium adsorption ratio and electrolyte concentration Soil Sci. 111 282–287.CrossRefGoogle Scholar
Yaron, B. and Thomas, G. W., 1968 Soil hydraulic conductivity as affected by sodic water Water Resources Res. 4 545–552.CrossRefGoogle Scholar