Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-22T08:11:39.733Z Has data issue: false hasContentIssue false
  • English
  • Français

Dielectric-Relaxation Spectroscopy of Kaolinite, Montmorillonite, Allophane, and Imogolite under Moist Conditions

Published online by Cambridge University Press:  28 February 2024

Tomoyuki Ishida ,
Tomoyuki Marino  and
Changjun Wang
Tomoyuki Ishida
Affiliation:
Department of Agricultural Engineering, Kagawa University, Miki, Kagawa 761-0795, Japan
Tomoyuki Marino
Affiliation:
Soil Chemistry Laboratory, National Institute of Agro-Environmental Sciences of Japan, Tsukuba, Ibaraki 305-8604, Japan
Changjun Wang
Affiliation:
Department of Agricultural Engineering, Kagawa University, Miki, Kagawa 761-0795, Japan
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The dielectric behavior of kaolinite, montmorillonite, allophane, and imogolite samples adjusted to a water potential of 33 kPa was examined using a time-domain reflectometry method over a wide frequency range of 103-1010 Hz. A dielectric relaxation peak owing to bound H2O was observed. The observation of this peak required the precise determination of the contributions of dc conductivity. The peak is located at 10 MHz, indicating that the relaxation time of the bound H2O is approximately ten times longer than the relaxation time of bound H2O with organic polymers, such as an aqueous globular-protein solution. The structure of bound H2O differs between phyllosilicates and amorphous phases, based on differences in relaxation strength and the pattern of distribution of the relaxation times. The dielectric process involving rotation of bulk H2O molecules was also observed at 20 GHz. The relaxation strength of bulk H2O increased with an increase in the water content. The interfacial polarization in the diffuse double layer occurred only in montmorillonite and kaolinite, indicating that mechanisms involving the Maxwell-Wagner and surface-polarization effects cannot be extended to include allophane and imogolite. Although these results suggest that additional work is required, a tentative conclusion is that a tangential migration of counter-ions along clay surfaces may be important.

Keywords

AllophaneBound WaterComplex PermittivityDielectric-Relaxation SpectroscopyImogoliteInterfacial PolarizationKaoliniteMontmorilloniteTime-Domain Reflectometry
Type
Research Article
Information
Clays and Clay Minerals , Volume 48 , Issue 1 , February 2000 , pp. 75 - 84
Copyright
Copyright © 2000, The Clay Minerals Society

References

Calvet, R., 1975 Dielectric properties of montmorillonites saturated by bivalent cations. Clays and Clay Minerals 23 257–265 10.1346/CCMN.1975.0230401.CrossRefGoogle Scholar
Carrington, A. and McLachlan, A.D., 1967 Introduction to Magnetic Resonance. New York Harper & Row.Google Scholar
Cole, R.H., 1975 Evaluation of dielectric behavior by time domain spectroscopy. 1. Dielectric response by real time analysis. Journal of Physical Chemistry 79 1459–1468 10.1021/j100581a022.CrossRefGoogle Scholar
Cole, R.H., 1975 Evaluation of dielectric behavior by time domain spectroscopy. 2. Complex permittivity. Journal of Physical Chemistry 19 1469–1474 10.1021/j100581a023.CrossRefGoogle Scholar
Cole, R.H. Mashimo, S. and Winsor, P IV, 1980 Evaluation of dielectric behavior by time domain spectroscopy. 3. Precision difference methods. Journal of Physical Chemistry 84 786–793 10.1021/j100444a017.CrossRefGoogle Scholar
Dukhin, S.S. and Matijevic, E., 1973 Dielectric properties of disperse systems Surface and Colloid Science, Volume 3 New York Academic Press 83–165.Google Scholar
Dukhin, S.S., 1993 Non-equilibrium electric surface phenomena. Advances in Colloid and Interface Science 44 1–134 10.1016/0001-8686(93)80021-3.CrossRefGoogle Scholar
Fripiat, J.J. Jelli, A. Poncelet, G. and Andre, J., 1965 Thermodynamic properties of adsorbed water molecules and electrical conduction in montmorillonites and silicas. Journal of Physical Chemistry 69 2185–2197 10.1021/j100891a007.CrossRefGoogle Scholar
Fukuzaki, M. Umehara, T. Kurita, D. Shioya, S. Haida, M. and Mashimo, M., 1992 Measurement of bound water in an aqueous DNA solution using nuclear magnetic resonance and time domain reflectometry. Journal of Physical Chemistry 96 10087–10089 10.1021/j100204a001.CrossRefGoogle Scholar
Fukuzaki, M. Miura, N. Shinyashiki, N. Kurita, D. Shioya, S. Haida, M. and Mashimo, M., 1995 Comparison of water relaxation time in serum albumin solution using nuclear magnetic resonance and time domain reflectometry. Journal of Physical Chemistry 99 431–435 10.1021/j100001a064.CrossRefGoogle Scholar
Goldsmith, B.J. and Muir, J., 1960 Surface ion effects in the dielectric properties of adsorbed water films. Journal of Chemical Society, Faraday Transactions 1 56 1656–1661 10.1039/tf9605601656.CrossRefGoogle Scholar
Hall, P.G. and Rose, M.A., 1978 Dielectric properties of water adsorbed by kaolinite clays. Journal of Chemical Society, Faraday Transactions 1 74 1221–1233 10.1039/f19787401221.CrossRefGoogle Scholar
Havriliak, S. and Negami, S., 1967 A complex plane representation of dielectric and mechanical relaxation processes in some polymers. Polymer 8 161–210 10.1016/0032-3861(67)90021-3.CrossRefGoogle Scholar
Helmy, A.K. Santamaria, R.M. and Garcia, N.J., 1988 Dielectric behavior of montmorillonite discs. Colloids and Surfaces 34 13–21 10.1016/0166-6622(88)80078-7.CrossRefGoogle Scholar
Henmi, T., 1991 Idea and methodology on the study of amorphous clays. Journal of Clay Science Society of Japan 31 75–81.Google Scholar
Hertz, H.G. and Frank, F., 1973 Nuclear magnetic relaxation spectroscopy Water, A Comprehensive Treatise, Volume 3 New York Plenum Press 301–400.Google Scholar
Hill, N.E. Vaughan, W.E. Price, A.H. and Davies, M., 1969 Dielectric Properties and Molecular Behaviour. London Van Nostrand Reinhold.Google Scholar
Hoekstra, P. and Doyle, W.T., 1971 Dielectric relaxation of surface adsorbed water. Journal of Colloid and Interface Science 36 513–521 10.1016/0021-9797(71)90386-9.CrossRefGoogle Scholar
Ishida, T. and Makino, T., 1999 Microwave dielectric relaxation of bound water to silica, alumina, and silica-alumina gel suspensions. Journal of Colloid and Interface Science 211 144–151 10.1006/jcis.1998.6029.CrossRefGoogle Scholar
Ishida, T. and Makino, T., 1999 Effects of pH on dielectric relaxation of montmorillonite, allophane, and imogolite suspensions. Journal of Colloid and Interface Science 211 152–161 10.1006/jcis.1998.6030.CrossRefGoogle Scholar
Iwata, S. Izumi, F. and Tsukamoto, A., 1989 Differential heat of water adsorption for montmorillonite, kaolinite and allophane. Clay Minerals 24 505–512 10.1180/claymin.1989.024.3.04.CrossRefGoogle Scholar
Jackson, M.L. (1979). Soil Chemical Analysis-Advanced Course, 2nd edition. M. L. Jackson, Madison, Wisconsin, 895 pp.Google Scholar
Lockhart, N.C., 1980 Electrical properties and the surface characteristics and structure of clays. I. Swelling clays. Journal of Colloid and Interface Science 74 509–519 10.1016/0021-9797(80)90220-9.CrossRefGoogle Scholar
Lockhart, N.C., 1980 Electrical properties and the surface characteristics and structure of clays. II. Kaolinite-a non-swelling clay. Journal of Colloid and Interface Science 74 520–529 10.1016/0021-9797(80)90221-0.CrossRefGoogle Scholar
Mamy, J., 1968 Recherches sur l’hydration de la montmorillonite: proprietes dielectriques et structure du film d’eau. Annales Agronomiques 19 175–246.Google Scholar
Mashimo, S. Umehara, T. Ota, X. Kuwabara, S. Shinyashiki, N. and Yagihara, S., 1987 Evaluation of complex permittivity of aqueous solution by time domain reflectometry. Journal of Molecular Liquids 36 135–151 10.1016/0167-7322(87)80036-3.CrossRefGoogle Scholar
Mashimo, S. Kuwabara, S. Yagihara, S. and Higasi, K., 1987 Dielectric relaxation time and structure of bound water in biological materials. Journal of Physical Chemistry 91 6337–6338 10.1021/j100309a005.CrossRefGoogle Scholar
Mashimo, S. Umehara, T. and Kuwabara, S., 1989 Dielectric study on dynamics and structure of water bound to DNA using a frequency range 107-1010 Hz. Journal of Physical Chemistry 93 4963–4967 10.1021/j100349a057.CrossRefGoogle Scholar
Mehra, O.R. and Jackson, M.L., 1960 Iron oxide removal from soils and clays by a dithionite citrate system buffered with sodium bicarbonates. Clays and Clay Minerals 7 317–327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Miura, N. Asaka, N. Shinyashiki, N. and Mashimo, S., 1994 Microwave dielectric study on bound water of globule proteins in aqueous solution. Biopolymers 34 357–364 10.1002/bip.360340307.CrossRefGoogle Scholar
Miyauchi, N. and Aomine, S., 1966 Mineralogy of gel-like substance in the pumice bed in Kanuma and Kitakami districts. Soil Science and Plant Nutrition 12 187–190.CrossRefGoogle Scholar
Muraoka, M., 1951 Reports on Ibusuki clay produced from Kagoshima Prefectures. Bulletin of the Geological Survey of Japan 2 74–84.Google Scholar
Raythatha, R. and Sen, P.N., 1986 Dielectric properties of clay suspensions in MHz to GHz range. Journal of Colloid and Interface Science 109 301–309 10.1016/0021-9797(86)90308-5.CrossRefGoogle Scholar
Schwarz, G., 1962 A theory of the low-frequency dielectric dispersion of colloidal particles in electrolyte solution. Journal of Physical Chemistry 66 2636–2642 10.1021/j100818a067.CrossRefGoogle Scholar
Sen, P.N., 1981 Relation of certain geometrical features to the dielectric anomaly of rocks. Geophysics 46 1714–1720 10.1190/1.1441178.CrossRefGoogle Scholar
Shinyashiki, N. Asaka, N. Mashimo, S. Yagihara, S. and Sasaki, N., 1990 Microwave dielectric study on hydration of moist collagen. Biopolymers 29 1185–1191 10.1002/bip.360290809.CrossRefGoogle Scholar
Sillars, R.W., 1936 The properties of a dielectric containing semiconducting particles of various shapes. Proceedings of Royal Society of London A 166 378–394.Google Scholar
Sposito, G., 1981 Single-particle motions in liquid water. II. The hydrodynamic model. Journal of Chemical Physics 74 6943–6949 10.1063/1.441057.CrossRefGoogle Scholar
Sposito, G. and Prost, R., 1982 Structure of water adsorbed on smectites. Chemical Reviews 82 553–573 10.1021/cr00052a001.CrossRefGoogle Scholar
Sueno, J. and Nakaishi, K., 1992 Thixotropic behaviors of sodium and calcium montmorillonites at salt concentrations in the vicinity of 0.3 N. Clay Science 8 349–353.Google Scholar
Umehara, T. Kuwabara, S. Mashimo, S. and Yagihara, S., 1990 Dielectric study on hydration of B-, A-, and Z-DNA. Biopolymers 30 649–656 10.1002/bip.360300702.CrossRefGoogle Scholar
Weiler, R.A. and Chaussidon, J., 1968 Surface conductivity and dielectrical properties of montmorillonite gels. Clays and Clay Minerals 16 147–155 10.1346/CCMN.1968.0160205.CrossRefGoogle Scholar
Winsor, P. I. and Cole, R.H., 1982 Dielectric properties of electrolyte solutions. 1. Sodium iodide in seven solvents at various temperatures. Journal of Physical Chemistry 86 2486–2490 10.1021/j100210a049.CrossRefGoogle Scholar
Winsor, P. I. and Cole, R.H., 1982 Dielectric properties of electrolyte solutions. 2. Alkali halides in methanol. Journal of Physical Chemistry 86 2491–2494 10.1021/j100210a050.CrossRefGoogle Scholar
Yoshinaga, N., 1966 Chemical composition and some thermal data of eighteen allophanes from Ando soils and weathered pumices. Soil Science and Plant Nutrition 12 47–54 10.1080/00380768.1966.10431182.CrossRefGoogle Scholar