Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-24T13:12:52.914Z Has data issue: false hasContentIssue false
  • English
  • Français

Dielectric Relaxation of Water in Clay Minerals

Published online by Cambridge University Press:  01 January 2024

Maria A. Vasilyeva ,
Yuri A. Gusev ,
Valery G. Shtyrlin ,
Anna Greenbaum (Gutina) ,
Alexander Puzenko ,
Paul Ben Ishai  and
Yuri Feldman
Maria A. Vasilyeva
Affiliation:
The Kazan Federal University, Institute of Physics, Kremlevskaya st. 18, 420008, Kazan, Russian Federation
Yuri A. Gusev*
Affiliation:
The Kazan Federal University, Institute of Physics, Kremlevskaya st. 18, 420008, Kazan, Russian Federation
Valery G. Shtyrlin
Affiliation:
The Kazan Federal University, A.M. Butlerov Chemistry Institute, Kremlevskaya st. 18, 420008, Kazan, Russian Federation
Anna Greenbaum (Gutina)
Affiliation:
Department of Applied Physics, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Givat Ram, 91904, Jerusalem, Israel
Alexander Puzenko
Affiliation:
Department of Applied Physics, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Givat Ram, 91904, Jerusalem, Israel
Paul Ben Ishai
Affiliation:
Department of Applied Physics, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Givat Ram, 91904, Jerusalem, Israel
Yuri Feldman
Affiliation:
Department of Applied Physics, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Givat Ram, 91904, Jerusalem, Israel
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The study of confined water dynamics in clay minerals is a very important topic in aluminosilicate-surface chemistry. Aluminosilicates are among the most technologically versatile materials in industry today. Dielectric spectroscopy is a very useful method for investigating the structure and dynamics of water adsorbed on solid matrix surfaces and water in the vicinity of ions in solutions. Use of this method for the study of clay minerals has been underutilized to date, however. The main goal of the present research was to understand the relaxation mechanisms of water molecules interacting with different hydration centers in clay minerals, with a view to eventually control this interaction. Two types of natural layered aluminosilicates (clay minerals) — montmorillonite with exchangeable K+, Co2+, and Ni2+ cations and kaolinite with exchangeable K+ and Ba2+ cations — were examined by means of dielectric spectroscopy over wide ranges of temperature (from -121°C to +300°C) and frequency (1 Hz–1 MHz). An analysis of the experimental data is provided in terms of four distributed relaxation processes. The low-temperature relaxation was observed only in montmorillonites and could be subdivided into two processes, each related to a specific hydration center. The cooperative behavior of water at the interface was observed in the intermediate temperature region, together with a proton percolation. The dielectric properties of ice-like and confined water structures in the layered clay minerals were compared with the dielectric response observed in porous glasses. The spatial fractal dimensions of the porous aluminosilicates were calculated by two separate methods — from an analysis of the fractality found in photomicrographs and from the dielectric response.

Keywords

Adsorbed WaterDielectric SpectroscopyExchangeable CationsFractal DimensionKaoliniteMontmorillonite
Type
Article
Information
Clays and Clay Minerals , Volume 62 , Issue 1 , February 2014 , pp. 62 - 73
Copyright
Copyright © Clay Minerals Society 2014

References

Behnsen, J. and Faulkner, D.R., 2011 Water and argon permeability of phyllosilicate powders under medium to high pressure Journal of Geophysical Research 116 B12203.CrossRefGoogle Scholar
Bunde, A. and Havlin, S., 1995 Fractals in Science Berlin, Heidelberg, New York Springer-Verlag.Google Scholar
Calvet, R., 1975 Dielectric properties of montmorillonites saturated by bivalent cations Clays and Clay Minerals 23 257–265.CrossRefGoogle Scholar
Cole, K.S. and Cole, R.H., 1941 Dispersion and absorption in dielectrics. I. Alternating current characteristics Journal of Chemical Physics 9 341–351.CrossRefGoogle Scholar
Feldman, Y. Puzenko, A. and Ryabov, Y.a., 2006 Dielectric relaxation phenomena in complex materials Fractals, Diffusion, and Relaxation in Disordered Complex Systems: a Special Volume of Advances in Chemical Physics 133 1–125.CrossRefGoogle Scholar
Greg, S.J. and Sing, K.S.W., 1967 Adsorption, Specific Area and Porosity London, New York Academic Press 303 pp..Google Scholar
Gupta, S.S. and Bhattacharyya, K.G., 2012 Adsorption of heavy metals on kaolinite and montmorillonite: a review Physical Chemistry Chemical Physics 14 6698–6723.CrossRefGoogle ScholarPubMed
Gutina, A. Antropova, T. Rysiakiewicz-Pasek, E. Virnik, K. and Feldman, Y.u., 2003 Dielectric relaxation in porous glasses Microporous and Mesoporous Materials 58 237–254.CrossRefGoogle Scholar
Hall, P.G. and Rose, M.A., 1978 Dielectric properties of water adsorbed by kaolinite clays Journal of Chemical Society, Faraday Transactions 1 74 1221–1233.CrossRefGoogle Scholar
Hoekstra, P. and Doyle, W.T., 1971 Dielectric relaxation of surface adsorbed water Journal of Colloid and Interface Science 36 513–521.CrossRefGoogle Scholar
Ishida, T. Makino, T. and Wang, C., 2000 Dielectricrelaxation spectroscopy of kaolinite, montmorillonite, allophane, and imogolite under moist conditions Clays and Clay Minerals 48 75–84.CrossRefGoogle Scholar
Jonscher, A.K., 1996 Universal Relaxation Law London Chelsea Dielectrics Press 415 pp..Google Scholar
Kaviratna, P.D. Pinnavaia, T.J. and Schroeder, P.A., 1996 Dielectric properties of smectite clays Journal of Physics and Chemistry of Solids 57 1897–1906.CrossRefGoogle Scholar
Kiselev, A.V., 1986 Intermolecular Interactions in Adsorption and Chromatography Moscow Vyshzhaya shkola 360 pp..Google Scholar
Kozlowski, T., 2011 Low temperature exothermic effects on cooling of homoionic clays Cold Regions Science and Technology 68 139–149.CrossRefGoogle Scholar
Kozlowski, T., 2012 Modulated Differential Scanning Calorimetry (MDSC) studies on low-temperature freezing of water adsorbed on clays, apparent specific heat of soil water and specific heat of dry soil Cold Regions Science and Technology 78 89–96.CrossRefGoogle Scholar
Kremer, F. and Schoenhals, A., 2002 Broadband Dielectric Spectroscopy Berlin, Heidelberg, New York Springer-Verlag 729 pp..Google Scholar
Krestov, G.A., 1991 Thermodynamics of Solvation: Solution and Dissolution, Ions and Solvents, Structure and Energetics New York Horwood 570 pp..Google Scholar
Levy, E. Puzenko, A. Kaatze, U. Ben Ishai, P. and Feldman, Y.u., 2012 Dielectric spectra broadening as the signature of dipole-matrix interaction. II. Water in ionic solutions Journal of Chemical Physics 136 114503.CrossRefGoogle ScholarPubMed
Libster, D. Ben Ishai, P. Aserin, A. Shoham, G. and Garti, N., 2008 Microscopic to mesoscopic properties of lyotropic reverse hexagonal liquid crystals Langmuir 24 2118–2127.CrossRefGoogle ScholarPubMed
Lockhart, N.C., 1980 Electrical properties and the surface characteristics and structure of clays. I. Swelling clays Journal of Colloid and Interface Science 74 509–519.CrossRefGoogle Scholar
Lockhart, N.C., 1980 Electrical properties and the surface characteristics and structure of clays. II. Kaolinite — a nonswelling clay Journal of Colloid and Interface Science 74 520–529.CrossRefGoogle Scholar
Logsdon, S.D. and Laird, D.A., 2002 Dielectric spectra of bound water in hydrated Ca-smectite Journal of Non-Crystalline Solids 305 243–246.CrossRefGoogle Scholar
Logsdon, S.D. and Laird, D.A., 2004 Electrical conductivity spectra of smectites as influenced by saturating cation and humidity Clays and Clay Minerals 52 411–420.CrossRefGoogle Scholar
Low, P.F. Anderson, D.M. and Hoekstra, P., 1968 Thermodynamic relationships for soils at or below the freezing point. I. Freezing point depression and heat capacity Water Resources Research 4 379–394.CrossRefGoogle Scholar
Low, P.F. Hoekstra, P. and Anderson, D.M., 1968 Thermodynamic relationships for soils at or below the freezing point. II. Effects of temperature and pressure on unfrozen soil water Water Resources Research 4 541–544.CrossRefGoogle Scholar
Mamy, J., 1968 Recherches sur l’hydration de la montmorillonite: propriétés diélectriques et structure du film d’eau Annales Agronomiques 19 175–246.Google Scholar
Narine, S.S. and Marangoni, A.G., 1999 Fractal nature of fat crystal networks Physical Review E 59 1908–1920.CrossRefGoogle Scholar
Puzenko, A. Kozlovich, N. Gutina, A. and Feldman, Y.u., 1999 Determination of dimensions of pore fractals and porosity of silica glasses from the dielectric dispersion at percolation Physical Review B 60 14348–14359.CrossRefGoogle Scholar
Puzenko, A. Ben Ishai, P. and Feldman, Y., 2010 Cole-Cole broadening and strange kinetics Physical Review Letters 105 037601–4.CrossRefGoogle ScholarPubMed
Puzenko, A. Levy, E. Shendrik, A. Talary, M. S. Caduff, A. and Feldman, Y., 2012 Dielectric spectra broadening as a signature for dipole-matrix interaction. III. Water in adenosine monophosphate/adenosine-5-triphosphate solutions Journal of Chemical Physics 137 194502.CrossRefGoogle ScholarPubMed
Raythatha, R. and Sen, P.N., 1986 Dielectric properties of clay suspensions in MHz to GHz range Journal of Colloid and Interface Science 109 301–309.CrossRefGoogle Scholar
Rotenberg, B. Cadéne, A. Dufrêche, J.-F. Durand-Vidal, S. Badot, J.-C. and Turq, P., 2005 An analytical model for probing ion dynamics in clays with broadband dielectric spectroscopy Journal of Physical Chemistry B 109 15548–15557.CrossRefGoogle ScholarPubMed
Ryabov, Y. Gutina, A. Arkhipov, V. and Feldman, Y.u., 2001 Dielectric relaxation phenomena of water absorbed in porous glasses Journal of Physical Chemistry B 105 1845–1850.CrossRefGoogle Scholar
Salles, F. Devautour-Vinot, S. Bildstein, O. Jullien, M. Maurin, G. Giuntini, J.-C. Douillard, J.-M. and Van Damme, H., 2008 Ionic mobility and hydration energies in montmorillonite clay Journal of Physical Chemistry C 112 14001–14009.CrossRefGoogle Scholar
Saltas, V. Vallianatos, F. Soupios, P. Makris, J.P. and Triantisc, D., 2007 Dielectric and conductivity measurements as proxy method to monitor contamination in sandstone Journal of Hazardous Materials 142 520–525.CrossRefGoogle ScholarPubMed
Samoilov, O.Y.a., 1957 The Structure of Aqueous Electrolyte Solutions and the Ion Hydration Moscow Akademie Nauk SSSR 192 pp..Google Scholar
Schaumburg, G., 1994 Overview: Modern measurement techniques in Broadband Dielectric Spectroscopy Dielectrics Newsletter 4–7.Google Scholar
Schoonheydt, R. Johnston, C., Bergaya, F. Theng, B. and Lagaly, G., 2006 Surface and interface chemistry of clay minerals Handbook of Clay Science New York Elsevier 87–114.CrossRefGoogle Scholar
Spanoudaki, A. Albela, B. Bonneviot, L. and Peyrard, M., 2005 The dynamics of water in nanoporous silica studied by dielectric spectroscopy The European Physical Journal E: Soft Matter and Biological Physics 17 21–27.CrossRefGoogle ScholarPubMed
Sposito, G. and Prost, R., 1982 Structure of water adsorbed on smectites Chemical Reviews 82 553–573.CrossRefGoogle Scholar
Tang, D. and Marangoni, A.G., 2006 3D fractal dimension of fat crystal networks Chemical Physics Letters 433 248–252.CrossRefGoogle Scholar
Tang, D. and Marangoni, A.G., 2006 Microstructure and fractal analysis of fat crystal networks Journal of the American Oil Chemists’ Society 83 377–388.CrossRefGoogle Scholar
Tarasevich, Y.u.I., 1988 Structure and Surface Chemistry of Layer Silicates Kiev Naukova Dumka 248 pp..Google Scholar
Tarasevich, Y.u.I. and Ovcharenko, F.D., 1975 Adsorption on Clayey Minerals Kiev Naukova Dumka 351 pp..Google Scholar
Tarasevich, Y.u.I. and Ovcharenko, F.D., 1978 A study of the nature of the active centers on the surface of layer silicates Adsorbents, their Preparation, Properties, and Applications Leningrad Nauka 138–141.Google Scholar
Tarasevich, Y.u.I. and Ovcharenko, F.D., 1980 Adsorption sur des Minéreaux Argileux Paris Institut Français du Pétrole, Rueil Malmaison 449 pp..Google Scholar
Vasilyeva, M.A. Gusev, Y.u.A. and Shtyrlin, V.G., 2012 Two types of adsorbed water in natural montmorillonites at low temperatures by dielectric spectroscopy Journal of Physics: Conference Series 394 012027.Google Scholar
Vasilyeva, M.A. Gusev, Y.u.A. and Shtyrlin, V.G., 2012 Differences in behaviour of adsorbed water in kaolinites and montmorillonites in temperature range from -90°C to +140°C by dielectric spectroscopy Journal of Physics: Conference Series 394 012028.Google Scholar
Volzone, C. Thompson, J.G. Melnitchenko, A. Ortiga, J. and Palethorpe, S.R., 1999 Selective gas adsorption by amorphous clay-mineral derivatives Clays and Clay Minerals 47 647–657.CrossRefGoogle Scholar
Wander, M.C.F. and Clark, A.E., 2008 Structural and dielectric properties of quartz-water interfaces Journal of Physical Chemistry C 112 19986–19994.CrossRefGoogle Scholar
Wong, P. and Cao, Q., 1992 Correlation function and structure factor for a mass fractal bounded by a surface fractal Physical Review B 45 7627–7632.CrossRefGoogle ScholarPubMed