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Desorption Behavior of Cd, Zn and Pb Sorbed on Hydroxyaluminum- and Hydroxyaluminosilicate-Montmorillonite Complexes

Published online by Cambridge University Press:  01 January 2024

Uttam Kumar Saha ,
Kōzō Iwasaki  and
Katsutoshi Sakurai
Uttam Kumar Saha*
Affiliation:
Department of Soil Science, University of Saskatchewan, 51 Campus Drive, Saskatoon, SK S7N 5A8, Canada
Kōzō Iwasaki
Affiliation:
Faculty of Agriculture, Kochi University, B 200 Monobe, Nankoku 783-8502, Kochi, Japan
Katsutoshi Sakurai
Affiliation:
Faculty of Agriculture, Kochi University, B 200 Monobe, Nankoku 783-8502, Kochi, Japan
*
*E-mail address of corresponding author: [email protected]
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Abstract

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There is a clear gap in the understanding of the desorption patterns of metals sorbed on soils and clays, despite their importance in the mobility, transport and fate of metals in natural environments. In this study, we investigated the desorption behavior of Cd, Zn and Pb sorbed on montmorillonite (Mt) and on hydroxyaluminum (HyA)- and hydroxyaluminosilicate (HAS)-Mt complexes. At pH 6.5, 2.5 g L–1 of HyA-Mt and HAS-Mt sorbed almost all of the 10–6 M Cd, Zn or Pb, while Mt under the same condition sorbed ~48, 49 and 55% of the added Cd, Zn and Pb, respectively. Based on pH50 values, the selectivity of metal sorption on Mt was Pb > Zn > Cd, and on the complexes, it was Pb ≫ Zn = Cd. In general, larger fractions of sorbed metals were remobilized from Mt than from the complexes. Again, in comparison with Pb, larger fractions of sorbed Cd and Zn were remobilized from different clays. Reducing the pHs of the equilibrium sorption systems from a fixed point (6.5) to different points (6.0, 5.5, 5.0, 4.5, and 4.0) and from different points (6.5, 6.0, 5.5, 5.0, and 4.5) to a fixed point (4.0) both yielded hysteretic metal desorption patterns. The fractions of Cd and Zn desorbed through Na and Cu exchange from the clays, especially from the complexes, were very different, indicating the existence of cation exchangeable metal sorption sites of weak and strong affinities on the complexes. Based on the EDTA-extractable fractions of Cd and Zn from HAS–Mt and HyA-Mt, it appeared that HyA–metal bonds are stronger than the HAS–metal bonds. Compared with other agents, acetic acid remobilized the highest fractions of all metals irrespective of the type of clays, with a concomitant release of Al or Al + Si. The Pb-HyA/HAS-Mt bonds were, however, still much too strong to be broken substantially by this mechanism. The results accomplished in this study suggest further attention to the fundamental understanding of the mobility, fate, bioavailability and toxicity of the concerned metals in soils and related environments.

Keywords

CadmiumDesorptionHydroxyaluminumHydroxyaluminosilicateInterlayeringLeadMontmorilloniteSorptionZinc
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 5 , October 2003 , pp. 481 - 492
Copyright
Copyright © 2003, The Clay Minerals Society

References

Barnhisel, R.I. Bertsch, P.M., Dixon, J.B. and Weed, S.B., (1989) Chlorites and hydroxy-interlayered vermiculite and smectite Minerals in Soil Environments 2nd Madison, wisconsin Soil Science Society of America 729 788.Google Scholar
Bautista-Tulin, A.T. and Inoue, K., (1997) Hydroxy-inter-layered minerals in Japanese soils influenced by eolian deposition Soil Science Society of America Journal 61 631–640 10.2136/sssaj1997.03615995006100020037x.Google Scholar
Clark, C.J. and McBride, M.B., (1984) Chemisorption of Cu(II) and Co(II) on allophane and imogolite Clays and Clay Minerals 4 300–310 10.1346/CCMN.1984.0320408.Google Scholar
Coughlin, B.R. and Stone, A.T., (1995) Nonreversible adsorption of divalent metal ions (MnII, CoII, NiII, CuII, and PbII) onto goethite: effects of acidification, FeII addition, and picolinic acid addition Environmental Science and Technology 29 2445–2455 10.1021/es00009a042.Google Scholar
Davenport, W.H., (1949) Determination of aluminum in presence of iron — spectrophotometric method using ferron Analytical Chemistry 21 710–711 10.1021/ac60030a020.Google Scholar
Eltantawy, I.M. and Arnold, P.M., (1973) Reappraisal of ethylene glycol mono-ethyl ether (EGME) method for surface area estimation of clays Journal of Soil Science 24 232–238 10.1111/j.1365-2389.1973.tb00759.x.Google Scholar
Farmer, V.C. Fraser, A.R. and Tait, J.M., (1979) Characterization of chemical structures of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy Geochimica et Cosmochimica Acta 43 1417–1420 10.1016/0016-7037(79)90135-2.Google Scholar
Forbes, E.A. Posner, A.M. and Quirk, J.P., (1976) The specific adsorption of divalent Cd, Co, Pb, and Zn on goethite Journal of Soil Science 27 154–166 10.1111/j.1365-2389.1976.tb01986.x.Google Scholar
Harsh, J.B. and Doner, H.E., (1984) Specific adsorption of copper on a hydroxy-aluminum-montmorillonite complex Soil Science Society of America Journal 48 1034–1039 10.2136/sssaj1984.03615995004800050017x.Google Scholar
Huang, P.M. Wang, M.K. Kämpf, N. Schulze, D.G., Dixon, J.B. and Schulze, D., (2002) Aluminum hydroxides Soil Mineralogy with Environmental Applications Madison, Wisconsin Soil Science Society of America 261 289.Google Scholar
Jackson, M.L., (1963) Soil Chemical Analysis — Advanced Course Madison, Wisconsin, USA Published by the author 895 pp.Google Scholar
James, R.O. and Healy, T.W., (1972) Adsorption of hydrolysable metal ions at the oxide-water interface Journal of Colloid Interface Science 40 42–52 10.1016/0021-9797(72)90172-5.Google Scholar
Jarvis, S.C., (1981) Copper sorption by soils at low concentration and relation to uptake by plants Journal of Soil Science 32 257–269 10.1111/j.1365-2389.1981.tb01705.x.Google Scholar
Kinniburgh, D.G. Jackson, M.L., Anderson, M.A. and Rubin, A.J., (1981) Cation adsorption by hydrous metal oxide and clays Adsorption of Inorganics at Solid-Liquid Interfaces Ann Arbor, Michigan Ann Arbor Science 91 160.Google Scholar
Kinniburgh, D.G. Syers, J.K. and Jackson, M.L., (1975) Specific adsorption of trace amounts of calcium and strontium by hydrous oxides of iron and aluminum Soil Science Society of America Journal 39 464–470 10.2136/sssaj1975.03615995003900030027x.Google Scholar
Kinniburgh, D.G. Jackson, M.L. and Syers, J.K., (1976) Adsorption of alkaline earth, transition, and heavy metal cations by hydrous oxide jels of iron and aluminum Soil Science Society ofAmerica Journal 40 796–799 10.2136/sssaj1976.03615995004000050047x.Google Scholar
Matsue, N. and Wada, K., (1988) Interlayer materials of partially interlayered vermiculite in Dystrochrepts derived from Tertiary sediments Journal of Soil Science 39 155–162 10.1111/j.1365-2389.1988.tb01202.x.Google Scholar
Margerum, D.W., Cayley, G.R., Weatherburn, D.C. and Pagenkopf, G.K. (1978) In: Coordination Chemistry (Martell, A.E., editor). Monograph 174, American Chemical Society.Google Scholar
McBride, M.B. and Bolt, G.H., (1991) Processes of heavy and transition metal sorption by soil minerals Interactions at the Soil Colloid-Soil Solution Interface Dordrecht, The Netherlands Kluwer Academic Publishers 149–175 10.1007/978-94-017-1909-4_5.Google Scholar
Mehra, O.P. and Jackson, M.L., (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Proceedings of 7th Annual Conference of the Clay Minerals Society London Pergamon Press 317 327.Google Scholar
Misono, M. Ochiai, E. Saito, Y. and Yoneda, Y., (1967) A new parameter scale for the strength of Lewis acids and bases with the evaluation of their softness Journal of Inorganic and Nuclear Chemistry 29 2685–2691 10.1016/0022-1902(67)80006-X.Google Scholar
Nowack, B. Kari, F.G. and Krüger, H.G., (2001) The remobilization of metals from iron oxides and sediments by metal-EDTA complexes Water Air and Soil Pollution 125 243–257 10.1023/A:1005296312509.Google Scholar
Parfitt, R.L. Fraser, A.R. Russell, J.D. and Farmer, V.C., (1977) Adsorption of hydrous oxides. II. Oxalate, benzoate, and phosphate on gibbsite Journal of Soil Science 28 40–47 10.1111/j.1365-2389.1977.tb02294.x.Google Scholar
Parks, G.A., (1965) The isoelectric points of solid oxides, solid hydroxides and aqueous hydroxy complex system Chemical Review 65 177–198 10.1021/cr60234a002.Google Scholar
Perrin, D.D., (1969) Dissociation constants of inorganic acids and bases in aqueous solution Pure and Applied Chemistry 20 133–236 10.1351/pac196920020133.Google Scholar
Saha, U.K. and Inoue, K., (1998) Hydroxy-interlayers in expansible layer silicates and their relation to potassium fixation Clays and Clay Minerals 46 556–566 10.1346/CCMN.1998.0460509.Google Scholar
Saha, U.K. Hiradate, S. and Inoue, K., (1998) Retention of phosphate by hydroxyaluminum- and hydroxyaluminosilicate-montmorillonite complexes Soil Science Society of America Journal 62 922–929 10.2136/sssaj1998.03615995006200040011x.Google Scholar
Saha, U.K. Takachi, C.Y. Kawai, S. and Inoue, K., (1999) Effect of HyA-interlayering on NH4/Ca selectivity of expandable layer silicates Clay Science 10 477 496.Google Scholar
Saha, U.K. Taniguchi, S. and Sakurai, K., (2001) Adsorption behavior of cadmium, zinc, and lead on hydroxyaluminum-and hydroxyaluminosilicate-montmorillonite complexes Soil Science Society of America Journal 65 694–703 10.2136/sssaj2001.653694x.Google Scholar
Saha, U.K. Taniguchi, S. and Sakurai, K., (2002) Simultaneous adsorption of cadmium, zinc, and lead on hydroxyaluminum- and hydroxyaluminosilicate-montmorillonite complexes Soil Science Society of America Journal 66 117–128 10.2136/sssaj2002.1170.Google Scholar
Sakurai, K. and Huang, P.M., (1998) Intercalation of hydroxy-aluminosilicate and hydroxyaluminum in montmorillonite and resultant physicochemical properties Soil Science Society of America Journal 62 362–368 10.2136/sssaj1998.03615995006200020011x.Google Scholar
Sakurai, K. Ohdate, Y. and Kyuma, K., (1988) Comparison of salt titration and potentiometric titration methods for the determination of zero point of charge (ZPC) Soil Science and Plant Nutrition 34 171–182 10.1080/00380768.1988.10415671.Google Scholar
Scheidegger, A.M. and Sparks, D.L., (1996) A critical assessment of sorption-desorption mechanisms at the soil mineral/water interface Soil Science 161 814–831 10.1097/00010694-199612000-00002.Google Scholar
Schulthess, C.P. and Huang, C.P., (1990) Adsorption of heavy metals by silicon and aluminum oxide surfaces on clay minerals Soil Science Society of America Journal 54 679–688 10.2136/sssaj1990.03615995005400030008x.Google Scholar
Schulthess, C.P. and Sparks, D.L., (1989) Competitive ion exchange behavior on oxides Soil Science Society of America Journal 53 366–373 10.2136/sssaj1989.03615995005300020009x.Google Scholar
Schultz, M.F. Benjamin, M.M. and Ferguson, J.F., (1987) Adsorption and desorption of metals on ferrihydrite: reversibility of the reaction and sorption properties of the regenerated solid Environmental Science and Technology 21 863–869 10.1021/es00163a003.Google Scholar
Taniguchi, S. Yamagata, N. and Sakurai, K., (2000) Cadmium adsorption on hydroxyaluminosilicate-montmorillonite complex as influenced by oxalate and citrate Soil Science and Plant Nutrition 46 315 324.Google Scholar
Ueno, K., (1988) Chelate Chemistry, an Introduction 2nd Tokyo Nankodo Publishers 290 pp.Google Scholar
Verburg, K. and Baveye, P., (1994) Hysteresis in the binary exchange of cations on 2:1 clays: a critical review Clays and Clay Minerals 42 207–220 10.1346/CCMN.1994.0420211.Google Scholar
Wada, K. and Okamura, Y., (1980) Electric charge characteristics of Ando A1 and buried A1 horizon soils Journal of Soil Science 31 307–314 10.1111/j.1365-2389.1980.tb02083.x.Google Scholar
Weaver, R.M. Syers, J.K. and Jackson, M.L., (1968) Determination of silica in citrate-bicarbonate extracts of soils Soil Science Society of America Proceedings 32 497–501 10.2136/sssaj1968.03615995003200040023x.Google Scholar