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Customized Spectral Libraries for Effective Mineral Exploration: Mining National Mineral Collections

Published online by Cambridge University Press:  01 January 2024

Jeanne B. Percival ,
Sean A. Bosman ,
Eric G. Potter ,
Jan M. Peter ,
Alexandra B. Laudadio ,
Ashley C. Abraham ,
Daniel A. Shiley  and
Chris Sherry
Jeanne B. Percival*
Affiliation:
Geological Survey of Canada, Ottawa, Ontario, Canada K1A 0E8
Sean A. Bosman
Affiliation:
Saskatchewan Geological Survey, Regina, Saskatchewan, Canada S4P 3Z8
Eric G. Potter
Affiliation:
Geological Survey of Canada, Ottawa, Ontario, Canada K1A 0E8
Jan M. Peter
Affiliation:
Geological Survey of Canada, Ottawa, Ontario, Canada K1A 0E8
Alexandra B. Laudadio
Affiliation:
Department of Earth Sciences, Carleton University, Ottawa, Ontario, Canada K1S 5B6
Ashley C. Abraham
Affiliation:
Department of Earth Sciences, Carleton University, Ottawa, Ontario, Canada K1S 5B6
Daniel A. Shiley
Affiliation:
ASD Inc.-Malvern Panalytical, Longmont, Colorado, USA 80503
Chris Sherry
Affiliation:
Consultant Geologist, Morrison, Colorado, USA 80465
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Infrared (Visible-Near Infrared-Shortwave Infrared (VNIR-SWIR)) spectroscopy is a cost-effective technique for mineral identification in the field. Modern hand-held spectrometers are equipped with on-board spectral libraries that enable rapid, qualitative analysis of most minerals and facilitate recognition of key alteration minerals for exploration. Spectral libraries can be general or customized for specific mineral deposit environments. To this end, careful collection of spectra in a controlled environment on pure specimens of key minerals was completed using the National Mineral Reference Collection (NMC) of the Geological Survey of Canada. The spectra collected from specimens in the ‘Kodama Clay Collection’ were processed using spectral plotting software and each new example was validated before being added to a group of spectra considered for incorporation into the on-board library of the handheld ASD-TerraSpec Halo near-infrared (NIR) mineral identification instrument. Spectra from an additional suite of mineral samples of the NMC containing REE, U, Th, and/or Nb are being prepared for a new, publicly available spectral library. These minerals commonly occur in carbonatite or alkali intrusive deposits, and as such will assist in the exploration for critical metals.

Keywords

ASD-TerraSpecClay MineralsInfrared SpectroscopyNational Mineral Reference CollectionNear InfraredOptical Reflectance SpectroscopyREE-bearing MineralsShortwave Infrared
Type
Article
Information
Clays and Clay Minerals , Volume 66 , Issue 3 , June 2018 , pp. 297 - 314
Copyright
Copyright © Clay Minerals Society 2018

References

Agar, B. Coulter, D., Milkereit, B., 2007 Remote sensing for mineral exploration — A decade perspective 1997–2007 Exploration in the New Millennium, Proceedings of the Fifth Decennial International Conference on Mineral Exploration 109–136.Google Scholar
ASD Inc., 2013 TerraSpec Mineral Analyzer opens new uranium exploration potential in the Athabasca Basin .Google Scholar
Bedini, E. (2017) The use of hyperspectral remote sensing for mineral exploration: A review. Journal of Hyperspectral Remote Sensing, 7, .CrossRefGoogle Scholar
Berger, B.R., Cox, D.P. and Singer, D.A., 1986 Descriptive model of epithermal quartzalunite Au Mineral Deposit Models Reston, Virginia, USA S. Geological Survey Bulletin 1693 158.Google Scholar
Boesche, N.K. Rogas, C. Lubitz, C. Brell, M. Herrmann, S. Mielke, C. Tonn, S. Appelt, O. Altenberger, U. and Kaufmann, H., 2015 Hyperspectral REE (rare earth element) mapping of outcrops — applications for neodymium detection Remote Sensing 7 5160–5186.CrossRefGoogle Scholar
Bosman, S.A. and Percival, J.B., 2014.Spectral reflectance data and interpretation of Athabasca Basin drillholes, Saskatchewan (NTS 64L, 74F to 74K, and 74N to 74P)Google Scholar
Chang, Z.S. Hedenquist, J.W. White, N.C. Cooke, D.R. Roach, M. Deyell, C.L. Garcia, J Jr Gemmell, J.B. McKnight, S. and Cuison, A.L., 2011 Exploration tools for linked porphyry and epithermal deposits: Example from the Mankayan intrusion-centered Cu-Au district, Luzon, Philippines Economic Geology 106 1365–1398.CrossRefGoogle Scholar
Clark, R.N., 2004 Spectroscopy of rocks and minerals, and principles of spectroscopy Infrared Spectroscopy in Geochemistry, Exploration Geochemistry, and Remote Sensing 33 17–55.Google Scholar
Clark, R.N. King, T.V.V. Klejwa, M. and Swayze, G.A., 1990 High spectral resolution reflectance spectroscopy of minerals Journal of Geophysical Research 95B8 12,653–12,680.CrossRefGoogle Scholar
Coblentz, W.W., 1906 Radiometric investigations of infrared absorption and reflection spectra National Bureau of Standards (U.S.) Bulletin 2 457–462.CrossRefGoogle Scholar
Cooke, D.R. Hollings, P. Wilkinson, J.J. and Tosdal, R., 2014 Geochemistry of porphry deposits Treatise on Geochemistry 13 357–381.CrossRefGoogle Scholar
Corriveau, L. Williams, P.J. and Mumin, A.H., 2010 Alteration vectors to IOCG mineralization — from uncharted terranes to deposits 20 89–110.Google Scholar
Corriveau, L. Montreuil, J.-F. and Potter, E.G., 2016 Alteration facies linkages amongst IOCG, IOA and affiliated deposits from the Great Bear Magmatic Zone, Canada Economic Geology 111 2045–2072.CrossRefGoogle Scholar
Date, J. Watanabe, Y. and Saeki, Y., 1983 Zonal alteration around the Fukazawa Kuroko deposits, Akita Prefecture, northern Japan Economic Geology Monograph 5 365–386.Google Scholar
Ducart, D.F. Crósta, A.P. Filho, C.R.S. and Coniglio, J., 2006 Alteration mineralogy at the Cerro La Mina epithermal prospect, Patagonia, Argentina: Field mapping, short-wave infrared spectroscopy, and ASTER images Economic Geology 101 981–996.CrossRefGoogle Scholar
Duke, E.F., 1994 Near infrared spectra of muscovite, Tschermak substitution and metamorphic reaction progress: implications for remote sensing Geology 22 621–624.2.3.CO;2>CrossRefGoogle Scholar
Earle, S., 1994 Application of reflectance spectrometry to analysis of Manitou Falls Formation samples Saskatchewan, Canada Cameco Corp., Saskatoon.Google Scholar
Earle, S., 1995 Quantitative reflectance spectrometry for analysis of the clay mineralogy of the Athabasca Basin rock samples Saskatchewan, Canada Cameco Corp., Saskatoon.Google Scholar
Earle, S., 1996 Evaluation of the reliability of mineral proportion estimates from PIMA-II reflectance spectrometer and MINSPEC1 program Saskatchewan, Canada Cameco Corp., Saskatoon.Google Scholar
Earle, S. Wheatley, K. Wasyliuk, K., Ashton, K.E. and Harper, C.T., 1996 Application of reflectance spectroscopy to the assessment of alteration mineralogy in the Key Lake area Proceedings of Minexpo’ 96 Symposium, Advances in Saskatchewan Geology and Mineral Exploration Saskatoon Special Publication No. 14 109–123.Google Scholar
Farmer, V.C. (editor) (1974) The Infrared Spectra of Minerals. Monograph 4, Mineralogical Society, London.CrossRefGoogle Scholar
Gaines, R.V. Skinner, C.W. Foord, E.E. Mason, B. Rosenzweig, A. and King, V.T., 1997 Dana’s New Mineralogy — The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Eighth New York John Wiley & Sons.Google Scholar
Goodfellow, W.D. and Lydon, J.W., 2007 Sedimentaryexhalative (SEDEX) deposits Mineral Deposits of Canada: A Synthesis of Major Deposit types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods 5 163–183.Google Scholar
Halley, S. Dilles, J.H. and Tosdal, R.M., 2015 Footprints: Hydrothermal alteration and geochemical dispersion around porphyry copper deposits Society of Economic Geologists Newsletter 100 12–17.Google Scholar
Harraden, C.L. McNulty, B.A. Gregory, M.J. and Lang, J.R., 2013 Shortwave infrared spectral analysis of hydrothermal alteration associated with the Pebble porphyry copper-goldmolybdenum deposit, Iliamna, Alaska Economic Geology 108 483–494.CrossRefGoogle Scholar
Hauff, P.L., 2005 Applied Reflectance Spectroscopy Arvada, Colorado, USA Spectral International, Inc..Google Scholar
Hauff, P. and Percival, J.B., 2006.Rapid in situ mineral analyses using field-portable SWIR spectrometers: Uranium and diamond examplesGoogle Scholar
Herrmann, W. Blake, M. Doyle, M. Huston, D. Kamprad, J. Merry, N. and Pontual, S., 2001 Short wavelength infrared (SWIR) spectral analysis of hydrothermal alteration zones associated with base metal sulfide deposits at Rosebery and Western Tharsis, Tasmania, and Highway-Reward, Queensland Economic Geology 96 939–955.Google Scholar
Hirschmugl, C., 2004 An introduction to infrared spectroscopy for geochemistry and remote sensing Infrared Spectroscopy in Geochemistry, Exploration Geochemistry, and Remote Sensing 33 1–16.Google Scholar
Hoeve, J. and Quirt, D. (1984) Mineralization and host rock alteration in relation to clay mineral diagenesis and evolution of the Middle-Proterozoic, Athabasca basin, northern Saskatchewan, Canada. Saskatchewan Research Council, Technical Report 187, 187 pp.Google Scholar
Hoeve, J. and Quirt, D., 1987 A stationary redox front as a critical factor in the formation of high-grade, unconformitytype uranium ores in the Athabasca basin, Saskatchewan, Canada Bulletin de Minéralogie 110 157–171.CrossRefGoogle Scholar
Hunt, G.R. and Ashley, R.P., 1979 Spectra of altered rocks in the visible and near infrared Economic Geology 74 1613–1629.CrossRefGoogle Scholar
Hunt, G.R. and Salisbury, J.W., 1970 Visible and nearinfrared spectra of minerals and rocks: I. Silicate minerals Modern Geology 1 283–300.Google Scholar
Hunt, G.R. and Salisbury, J.W., 1971 Visible and nearinfrared spectra of minerals and rocks: II. Carbonates Modern Geology 2 23–30.Google Scholar
Hunt, G.R. Salisbury, J.W. and Lenhoff, C.J., 1971a Visible and near-infrared spectra of minerals and rocks: III. Oxides and hydroxides Modern Geology 2 195–205.Google Scholar
Hunt, G.R. Salisbury, J.W. and Lenhoff, C.J., 1971b Visible and near-infrared spectra of minerals and rocks: IV. Sulphides and sulphates Modern Geology 3 1–14.Google Scholar
Hunt, G.R. Salisbury, J.W. and Lenhoff, C.J., 1971c Visible and near-infrared spectra of minerals and rocks: V. Halides, phosphates, arsenates, vanadates and borates Modern Geology 3 121–132.Google Scholar
Hunt, G.R. Salisbury, J.W. and Lenhoff, C.J., 1973 Visible and near infrared spectra of minerals and rocks: VI Additional silicates. Modern Geology 4 85–106.Google Scholar
Huntington, J. and Laukamp, C., 2015 Drill core reflectance spectroscopy applied to the carbonatite hosted REE deposit at Cummins Range (Australia) SGA (Society for Geology Applied to Mineral Deposits) 2015 France Nancy 1017–1019.Google Scholar
Jefferson, C.W. Thomas, D. Quirt, D. Mwenifumbo, CJ ^D, Milkereit, B., 2007a Empirical models for Canadian unconformity-associated uranium deposits Proceedings of Exploration 07: Fifth Decennial International Conference on Mineral Exploration 741–769.Google Scholar
Jefferson, C.W. Thomas, D.J. Gandhi, S.S. Ramaekers, P. Delaney, G. Brisbin, D. Cutts, C. Quirt, D. Portella, P. and Olson, R.A., 2007b Unconformity-associated uranium deposits of the Athabasca Basin, Saskatchewan and Alberta Mineral Deposits of Canada: A Synthesis of Major Deposit-types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods 5 273–305.Google Scholar
Kerr, A. Rafuse, H. Sparkes, G. Hinchey, J. and Sandeman, H., 2011 Visible/infrared spectroscopy (VIRS) as a research tool in economic geology: Background and pilot studies from Newfoundland and Labrador 145–166.Google Scholar
Kodama, H., 1985.Infrared spectra of minerals; reference guide to identification and characterization of minerals for the study of soils Research Branch Agriculture Canada, Technical BulletinGoogle Scholar
Kyser, K. Hiatt, E. Renac, C. Durocher, K. Holk, G. and Deckart, K., 2000 Diagenetic fluids in paleo- and meso- Proterozoic sedimentary basins and their implications for long protracted fluid histories Fluids and Basin Evolution 28 225–262.Google Scholar
Laakso, K. Rivard, B. Peter, J.M. White, H.P. Maloley, M. Harris, J. and Rogge, D., 2015 Application of airborne, laboratory, and field hyperspectral methods to mineral exploration in the Canadian arctic: recognition and characterization of volcanogenic massive sulfide-associated hydrothermal alteration in the Izok Lake deposit area, Nunavut, Canada Economic Geology 110 925–941.CrossRefGoogle Scholar
Laakso, K. Peter, J.M. Rivard, B. and White, H.P., 2016 Short-wave infrared spectral and geochemical characteristics of hydrothermal alteration at the Archean Izok Lake Zn- Cu-Pb-Ag volcanogenic massive sulfide deposit, Nunavut, Canada: Application in exploration target vectoring Economic Geology 111 1223–1239.CrossRefGoogle Scholar
Lau, I.C. Cudahy, T.J. Heinson, G. Mauger, A.J. James, P.R., Roach, I.C., 2003 Practical applications of hyperspectral remote sensing in regolith research Advances in Regolith: Proceedings of the CRC LEME Regional Regolith Symposia Australia Cooperative Research Centre for Landscape Environments and Mineral Exploration (CRC LEME) 249–253.Google Scholar
Leach, D.L. Sangster, D.F. Kelley, K.D. Large, R.R. Garven, G. Allen, C.R. Gutzmer, J. and Walters, S., 2005 Sediment-hosted lead zinc deposits: A global perspective Economic Geology 100 561–607.Google Scholar
Leach, D.L. Taylor, R.D. Fey, D.L. Diehl, S.F. and Saltus, R.W., 2010 A deposit model for Mississippi Valley-Type lead-zinc ores, Chapter A of mineral deposit models for resource assessment Virginia, USA Reston 1–52.Google Scholar
Lemière, B. and Uvarova, Y., 2017.Status and new developments in field portable geochemical techniques and on-site technologies for mineral explorationGoogle Scholar
Lyon, R.J.P. and Burns, E.A., 1963 Analysis of rocks and minerals by reflected infrared radiation Economic Geology 58 274–284.CrossRefGoogle Scholar
Marel, H.W. and Beutelspacher, H., 1976 Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures Amsterdam Elsevier.Google Scholar
Mauger, A.J. Ehrig, K. Kontonikas-Charos, A. Ciobanu, C.L. Cook, N.J. and Kamenetsky, V.S., 2016 Alteration at the Olympic Dam IOCG-U deposit: insights into distal to proximal feldspar and phyllosilicate chemistry from infrared reflectance spectroscopy Australian Journal of Earth Sciences 638 959–972.Google Scholar
Neal, L.C. Wilkinson, J.J. Mason, P.J. and Chang, Z., 2018 Spectral characteristics of propylitic alteration minerals as a vectoring tool for porphyry copper deposits Journal of Geochemical Exploration 184 179–198.CrossRefGoogle Scholar
Neave, D.A. Black, M. Riley, T.R. Gibson, S.A. Ferrier, G. Wall, F. and Broom-Fendley, S., 2016 On the feasibility of imaging carbonatite-hosted rare earth element deposits using remote sensing Economic Geology 111 641–665.CrossRefGoogle Scholar
Percival, J.B. Bell, K. and Torrance, J.K., 1993 Clay mineralogy and isotopic geochemistry of the alteration halo at the Cigar lake uranium deposit Canadian Journal of Earth Sciences 30 689–704.CrossRefGoogle Scholar
Percival, J.B. Wasyliuk, K. Reif, T. Bernier, S. Drever, G. and Perkins, C.T., 2002.Mineralogical aspects of three drill cores along the McArthur River transect using a portable infrared spectrometer Summary of Investigations 2002, Volume 2Google Scholar
Percival, J.B. Bosman, S.A. Potter, E.G. Ramaekers, P. Venance, K.E. Hunt, P.A. Davis, W. and Jefferson, C.W., 2013 Hydrothermal alteration in hydro-fractured Athabasca sandstone: distal expression of uranium mineralization? Exploration & Mining Geology (CIM) 21 63–77.Google Scholar
Percival, J.B. Olejarz, A.D. English, M.L.R. Belley, P.M. Flynn, T. Laudadio, A.B. and Stirling, J.A.R., 2016a.Spectral Library: The Kodama Clay CollectionGoogle Scholar
Percival, J.B. Potter, E.G. Lauzière, K. Ijewliw, O. Bilot, I. Hunt, P. English, M.L.R. Olejarz, A.D. Laudadio, A.B. Enright, A. Robillard, K.-L. and Corriveau, L., 2016b.Mineralogy, petrography and autoradiography of selected samples from the Contact Lake and NICO areas, Great Bear Magmatic Zone, Northwest Territories (IOCG-GEM Project)CrossRefGoogle Scholar
Percival, J.B. Venance, K.E. Desbarats, A.J. Parsons, M.B. Bilot, I. Abraham, A. and Laudadio, A., 2017 Mineralogical signature of the St. Lawrence Columbium Mine at Oka, Québec 40 304.Google Scholar
Perry, S.L., 2004 Spaceborne and airborne remote sensing systems for mineral exploration — Case histories using infrared (IR) spectroscopy Infrared Spectroscopy in Geochemistry, Exploration Geochemistry, and Remote Sensing 33 227–240.Google Scholar
Peter, J.M. Layton-Matthews, D. Gadd, M.G. Gill, S. Baker, S. Plett, S. Paradis, S., Paradis, S., 2015 Application of visiblenear infrared and short wave infrared spectroscopy to sediment-hosted Zn-Pb deposit exploration in the Selwyn Basin, Yukon Targeted Geoscience Initiative 4: Sediment-hosted Zn-Pb deposits: processes and implications for exploration 152–172.CrossRefGoogle Scholar
Potter, E.G. Montreuil, J.-F. Corriveau, L. and DeToni, A., 2013 Geology and hydrothermal alteration of the Fab Lake region, Northwest Territories.CrossRefGoogle Scholar
Quirt, D.H., 2010.Is illite still a pathfinder mineral for the geological environment of Athabasca unconformity-type uranium deposits? Program with AbstractsGoogle Scholar
Riegler, T. Lescuyer, J.-L. Wollenberg, P. Quirt, D. and Beaufort, D., 2014 Alteration related to uranium deposits in the Kiggavik-Andrew Lake structural trend, Nunavut, Canada: New insights from petrography and clay mineralogy The Canadian Mineralogist 52 27–45.CrossRefGoogle Scholar
Rowan, L.C. Kingston, M.J. and Crowley, J.K., 1986 Spectral reflectance of carbonatites and related alkali igneous rocks: selected samples from four North American localities Economic Geology 81 857–871.CrossRefGoogle Scholar
Ruitenbeek, F.J.A. Cudahy, T. van der Meer, F.D. and Hale, M., 2012 Characterization of the hydrothermal systems associated with Archean VMS-mineralization at Panorama, Western Australia, using hyperspectral, geochemical and geothermometric data Ore Geology Reviews 45 33–46.CrossRefGoogle Scholar
Sarrazin, P. Blake, D. Feldman, S. Chipera, S. Vaniman, D. and Bish, D., 2005 Field deployment of a portable X-ray diffraction/X-ray fluorescence instrument on Mars analog terrain Powder Diffraction 20 128–133.CrossRefGoogle Scholar
Schneider, S. Murphy, R.J. Monteiro, S.T. and Nettleton, E., 2009.On the development of a hyperspectral library for autonomous mining systems Proceedings of the Australasian Conference on Robotics and Automation (ACRA)Google Scholar
Shanks, W.C. III, 2012 Hydrothermal alteration-volcanogenic massive sulfide occurrence model 167–180.Google Scholar
Sherry, C., 2017.Advancements in portable NIR mineral spectroscopy (2007-2017)Google Scholar
Simmons, S.F. White, N.C. and John, D.A., 2005 Geological characteristics of epithermal precious and base metal deposits Economic Geology 1905–2005 485–522.Google Scholar
Somers, A. and Sholtz, N., 2017.The application of hand held laser induced breakdown spectroscopy to lithium exploration: A case studyGoogle Scholar
Steacy, H.R. and Williams, R., 1976.Canada’s Mineral Collection: the origins, display aspects and research significance of the National Mineral CollectionCrossRefGoogle Scholar
Stirling, J.A.R. Jonasson, I.R. Herd, R.K. Dougherty, J. Belley, P. and Therriault, A., 2011 The National Mineral Collection of Canada celebrates its golden anniversary Geological Association of Canada-Mineralogical Association of Canada Annual Meeting 34 212.Google Scholar
Tappert, M.C. Rivard, B. Giles, D. Tappert, R. and Mauger, A., 2013 The mineral chemistry, near-infrared, and midinfrared reflectance spectroscopy of phengite from the Olympic Dam IOCG deposit, South Australia Ore Geology Reviews 53 26–38.CrossRefGoogle Scholar
Taylor, B.E., 2007 Epithermal gold deposits Mineral Deposits of Canada: A Synthesis of Major Deposit types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods 5 113–139.Google Scholar
Thompson, A.J.B. and Thompson, JFH e, 1996.Atlas of Alteration: A Field and Petrographic Guide to Hydrothermal Alteration MineralsGoogle Scholar
Thompson, A.J.B. Hauff, P.L. and Robitaille, A.J., 1999 Alteration mapping in exploration: application of shortwave infrared (SWIR) spectroscopy Society Of Economic Geologists Newsletter 39 1 16–27.Google Scholar
Turner, D.J., 2015 Reflectance spectroscopy and imaging spectroscopy of rare earth element-bearing mineral and rock samples University of British Columbia Department of Geological Sciences.Google Scholar
Turner, D.J. Rivard, B. and Groat, L.A., 2014 Visible and short-wave infrared reflectance spectroscopy of REE fluorocarbonates American Mineralogist 99 1335–1346.CrossRefGoogle Scholar
Turner, D. Rivard, B. Groat, L., Simandl, G.J. and Neetz, M., 2015 Visible to shortwave infrared reflectance spectroscopy of rare earth element minerals Proceedings of the Symposium on Strategic and Critical Materials British Columbia Geological Survey British Columbia Ministry of Energy and Mines 219–229.Google Scholar
White, N.C. and Hedenquist, J.F., 1995 Epithermal gold deposits: Styles, characteristics, and exploration. Society of Economic Geologists Newsletter, 23 1, 9–13.Google Scholar
Yang, K. Huntington, J.F. Gemmell, J.B. and Scott, K.M., 2011 Variations in composition and abundance of white mica in the hydrothermal alteration system at Hellyer, Tasmania, as revealed by infrared reflectance spectroscopy Journal of Geochemical Exploration 108 143–156.CrossRefGoogle Scholar
Zhang, G. Wasyliuk, K. and Pan, Y., 2001 The characterization and quantitative analysis of clay minerals in the Athabasca Basin, Saskatchewan: Application of shortwave infrared reflectance spectroscopy The Canadian Mineralogist 39 1347–1363.CrossRefGoogle Scholar