Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-23T03:46:24.488Z Has data issue: false hasContentIssue false
  • English
  • Français

Crystal-Chemical Regularities and Identification Criteria in Fe-Bearing, K-Dioctahedral 1M Micas from X-ray Diffraction and Infrared Spectroscopy Data

Published online by Cambridge University Press:  01 January 2024

Bella B. Zviagina ,
Victor A. Drits ,
Boris A. Sakharov ,
Tatiana A. Ivanovskaya ,
Olga V. Dorzhieva  and
Douglas K. McCarty
Bella B. Zviagina*
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky per. 7, 119017, Moscow, Russia
Victor A. Drits
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky per. 7, 119017, Moscow, Russia
Boris A. Sakharov
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky per. 7, 119017, Moscow, Russia
Tatiana A. Ivanovskaya
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky per. 7, 119017, Moscow, Russia
Olga V. Dorzhieva
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky per. 7, 119017, Moscow, Russia Institute of Ore Deposits, Petrography, Mineralogy, and Geochemistry of the Russian Academy of Science, Staromonetny per. 35, 7, 119017, Moscow, Russia
Douglas K. McCarty
Affiliation:
Institute of Geological Sciences, Polish Academy of Sciences - Research Centre in Krakow, ul. Senacka 1, 31-002, Krakow, Poland
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Iron-bearing K-dioctahedral 1M and 1Md micas are abundant in diverse geological environments and vary in composition from illite to celadonite through Fe-illite, Al-glauconite, and glauconite. The chemistry and structural features of these micas are complex and heterogeneous, reliable diagnostic criteria are lacking, and the conventional mineralogical nomenclature is ambiguous, which complicate the identification of these mica varieties. The objectives of the present study were to reveal the structural and crystal-chemical variability in Fe-bearing, K-dioctahedral 1M micas and to define composition ranges and identification criteria for the mica varieties in the series. A collection of samples of various compositions was studied using X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) spectroscopy. Analysis of the relationships between unit-cell parameters and cation composition showed that the series included four groups, namely, Fe-bearing illites, Al-glauconites, glauconites, and celadonites and each group was characterized by a specific combination of unit-cell parameters and variation ranges. The illite group contained two distinct subgroups; Fe-bearing, Mg-rich illites and Feillites; which differ in the range of cation compositions and in FTIR characteristics. The boundary between Fe-illites and Al-glauconites occurs at a unit cell b value of ~9.05 Å and at ratios of octahedral Al to total trivalent octahedral cations that range between 0.60 and 0.65. The partially overlapping cation composition and cell parameter ranges may complicate the distinction between Al-glauconites and glauconites, which can still be unambiguously differentiated using FTIR data. The dramatically different XRD and FTIR characteristics confirmed that glauconite and celadonite should be treated as separate mineral species. The distinctive features of celadonite are relatively low csinβ values and reduced |ccosβ/a| values combined with b parameters lower than glauconites, but similar to Fe-illites. Celadonites also have distinct and sharp FTIR absorption bands at specific positions in the Si-O and OH stretching regions.

Keywords

CeladoniteDioctahedral MicaFTIR SpectroscopyGlauconiteIlliteUnit-cell ParametersX-ray Diffraction
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 4 , August 2017 , pp. 234 - 251
Copyright
Copyright © Clay Minerals Society 2017

References

Bailey, S.W., 1980 Summary of recommendations of AIPEA nomenclature committee on clay minerals American Mineralogist 65 1–7.Google Scholar
Besson, G. and Drits, V.A., 1997a Refined relationships between chemical composition of dioctahedral fine-dispersed mica minerals and their infrared spectra in the OH stretching region Part I. Identification of the stretching bands. Clays and Clay Minerals 45 158–169.CrossRefGoogle Scholar
Besson, G. and Drits, V.A., 1997b Refined relationship between chemical composition of dioctahedral fine-dispersed mica minerals and their infrared spectra in the OH stretching region Part II. The main factors affecting OH vibration and quantitative analysis. Clays and Clay Minerals 45 170–183.Google Scholar
Besson, G. Drits, V.A. Dayniak, L.G. and Smoliar, B.B., 1987 Analysis of cation distribution in dioctahedral micaceous minerals on the basis of IR spectroscopy data Clays and Clay Minerals 22 465–478.CrossRefGoogle Scholar
Brigatti, M.F. and Guggenheim, S., 2002 Mica crystal chemistry and the influence of pressure, temperature and solid solution on atomistic models Micas: Crystal Chemistry and Metamorphic Petrology 46 1–97.Google Scholar
Buckley, H.A. Bevan, J.C. Brown, K.M. Johnson, L.R. and Farmer, V.C., 1978 Glauconite and celadonite: two separate mineral species Mineralogical Magazine 42 373–382.CrossRefGoogle Scholar
Dainyak, L.G. Rusakov, V.S. Sukhorukov, I.A. Zviagina, B.B. and Drits, V.A., 2009 An improved model for the interpretation of Mössbauer spectra of dioctahedral 2:1 trans-vacant Fe-rich micas: refinement of parameters European Journal of Mineralogy 21 995–1008.CrossRefGoogle Scholar
Drits, V.A., 1987 Electron Diffraction and High-Resolution Electron Microscopy of Mineral Structures Berlin Springer Verlag.CrossRefGoogle Scholar
Drits, V.A., 2003 Structural and chemical heterogeneity of layer silicates and clay minerals Clay Minerals 38 403–432.CrossRefGoogle Scholar
Drits, V.A. and Kossovskaya, A.G., 1991 Clay Minerals: Micas and Chlorites Moscow Nauka 175p.Google Scholar
Drits, V.A. and Zviagina, B.B., 2009 Trans-vacant and cisvacant 2:1 layer silicates: structural features, identification and occurrence Clays and Clay Minerals 57 405–415.CrossRefGoogle Scholar
Drits, V.A. Kameneva, M. Yu, Sakharov, B.A. Dainyak, L.G. Smoliar, B.B. Bookin, A.S. and Salyn, A.L., 1993b Problems in Determination of the Actual Crystal Structure of Glauconites and Related Phyllosilicates Novosibirsk Nauka 198p.Google Scholar
Drits, V.A. McCarty, D.K. and Zviagina, B.B., 2006 Crystal-chemical factors responsible for the distribution of octahedral cations over trans- and cis-sites in dioctahedral 2:1 layer silicates Clays and Clay Minerals 54 131–153.CrossRefGoogle Scholar
Drits, V.A. Sakharov, B.A. Ivanovskaya, T.A. and Pokrovskaya, E.V., 2013 Crystal-chemical microheterogeneity of Precambrian globular dioctahedral mica minerals Lithology and Mineral Resources 48 503–528.CrossRefGoogle Scholar
Drits, V.A. Weber, F. Salyn, A. and Tsipursky, S.I., 1993a X-ray identification of 1M illite varieties Clays and Clay Minerals 28 185–207.CrossRefGoogle Scholar
Drits, V.A. Zviagina, B.B. McCarty, D.K. and Salyn, A.L., 2010 Factors responsible for crystal-chemical variations in the solid solutions from illite to aluminoceladonite and from glauconite to celadonite American Mineralogist 95 348–361.CrossRefGoogle Scholar
Duplay, J. and Buatier, M., 1997 The problem of differentiating glauconite and celadonite Chemical Geology 84 264–266.CrossRefGoogle Scholar
Farmer, V.C., Farmer, V.C., 1974 The layer silicates Infrared Spectra of Minerals London Monograph 4, Mineralogical Society 331–363.CrossRefGoogle Scholar
Ivanovskaya, T.A., 1994 Globular glauconite-illite layer silicates in Middle Riphean Debengdinsk Formation of the Olenek Uplift Lithology and Mineral Resources 29 595–605.Google Scholar
Ivanovskaya, T.A., 2009 Glauconitites in terrigenous rocks of the Khaipakh Formation (Middle Riphean, Olenek Uplift) Lithology and Mineral Resources 44 348–366.CrossRefGoogle Scholar
Ivanovskaya, T.A. and Tsipursky, S.I., 1990 First find of globular glauconite in the Lower Riphean, Anabar Uplift Litologia i Poleznye Iskopaemye 25 110–121.Google Scholar
Ivanovskaya, T.A. Tsipursky, S.I. and Yakovleva, O.V., 1989 Mineralogy of globular Riphean and Vendian layer silicates in Siberia and the Ural Lithology and Mineral Resources 24 271–284.Google Scholar
Ivanovskaya, T.A. Kats, A.G. Florova, Z.B. Tsipursky, S.I. and Yakovleva, O.V., 1993 Structure and lithomineralogical peculiarities of the Basal Lower Riphean in the Olenek Uplift (Osorkhayata Formation) Stratigrafiya Geologicheskaya Korrelyatsiya 1 84–92.Google Scholar
Ivanovskaya, T.A. Gor’kova, N.V. Karpova, G.V. and Pokrovskaya, E.V., 2006 Layer silicates (glauconite, illite, chlorite) in terrigenous rocks of the Arymassi Formation (Olenek Uplift) Lithology and Mineral Resources 41 601–623.CrossRefGoogle Scholar
Ivanovskaya, T. A. Zaitseva, T. S. Zviagina, B. B. and Sakharov, B. A., 2012 Crystal-chemical peculiarities of globular layer silicates of the glauconite-illite composition (Upper Proterozoic, Northern Siberia) Lithology and Mineral Resources 47 491–512.CrossRefGoogle Scholar
Ivanovskaya, T. A. Zviagina, B. B. Sakharov, B. A. Zaitseva, T. S. Pokrovskaya, E. V. and Dorzhieva, O. V., 2015 Globular layer silicates of the glauconite-illite composition in Upper Proterozoic and Lower Cambrian rocks Lithology and Mineral Resources 50 452–477.CrossRefGoogle Scholar
Kimbara, K. and Shimoda, S., 1973 A ferric celadonite in amygdales of dolerite at Taiheizan, Akita prefecture, Japan Clay Science 4 143–150.Google Scholar
Lazarenko, E.K. and Pavlishin, V.I., 1976 Relationship of celadonite and svitalskite Mineralogy of Sedimentary Rocks Dumka, Kiev Naukova.Google Scholar
Longuépée, H. and Cousineau, P.A., 2006 Constraints on the genesis of ferrian illite and aluminum-rich glauconite: potential impact on sedimentology and isotopic studies The Canadian Mineralogist 44 967–980.CrossRefGoogle Scholar
Madejova, J., 2003 FTIR techniques in clay mineral studies Vibrational Spectroscopy 31 1–10.CrossRefGoogle Scholar
Madejova, J. and Komadel, P., 2001 Baseline studies of The Clay Minerals Society Source Clays: Infrared methods Clays and Clay Minerals 49 410–432.CrossRefGoogle Scholar
Malkova, K.M., 1956 On the celadonite of Pobuzhye Collected Papers on Mineralogy 10 305–318.Google Scholar
Meunier, A. and El-Albani, A., 2006 The glauconite-Fe-illite-Fe-smectite problem: A critical review Terra Nova 19 95–104.CrossRefGoogle Scholar
Muller, F. Drits, V.A. Plançon, A. and Besson, G., 2000 Dehydroxylation of Fe3+, Mg-rich dioctahedral micas: (I) structural transformation Clay Minerals 35 491–504.CrossRefGoogle Scholar
Murav’ev, V.I., 1983 Mineral Parageneses of Glauconie-Siliceous Formations Moscow Nauka 208.Google Scholar
Nikolaeva, I.V., 1977 Minerals of the Glauconite Group in Sedimentary Formations Novosibirsk Nauka 319.Google Scholar
Odom, I.E., 1984 Glauconite and celadonite minerals Micas 13 545–572.CrossRefGoogle Scholar
Parron, C. and Amouric, M., 1990 Crystallochemical heterogeneity of glauconite and the related problem of glauconiteceladonite distinction Chemical Geology 84 286–289.CrossRefGoogle Scholar
Rieder, M. Cavazzini, G. D’yakonov, Y.S. Frank-Kamenetskii, V.A. Gottardi, G. Guggenheim, S. Koval, P.V. Muller, G. Neiva, A.M.R. Radoslovich, E.W. Robert, J.-L. Sassi, F.P. Takeda, H. Weiss, Z. and Wones, D.R., 1998 Nomenclature of the micas Clays and Clay Minerals 46 586–595.CrossRefGoogle Scholar
Russell, J.D. Fraser, A.R., Wilson, editor, M.J., 1994 Infrared methods Clay Mineralogy: Spectroscopic and Chemical Determinative Methods London Chapman & Hall 11–67.CrossRefGoogle Scholar
Sakharov, B.A. and Drits, V.A. (2018) Determination of small quantities of smectite layers in dioctahedral K-bearing micaceous minerals of illite, aluminoceladonite, and glauconite compositions. Lithology and Mineral Resources, 54 (in press).Google Scholar
Sakharov, B.A. Besson, G. Drits, V.A. Kameneva, M Yu Salyn, A.L. and Smoliar, B.B., 1990 X-ray study of the nature of stacking faults in the structure of glauconites Clay Minerals 25 419–435.CrossRefGoogle Scholar
Shutov, V.D. Katz, M.Y. Drits, V.A. Sokolova, A.L. Kazakov, G.A., Kossovskaya, A.G., 1975 Crystal chemistry of glauconites as an indicator of facial condition of their formation and postsedimentary transformation Crystal Chemistry of Minerals and Geological Problems Moscow Nauka 74–81.Google Scholar
Slonimskaya, M.V. Besson, G. Dainyak, L.G. Tchoubar, C. and Drits, V.A., 1986 Interpretation of the IR spectra of celadonites and glauconites in the region of OH-stretching frequencies Clay Minerals 21 377–388.CrossRefGoogle Scholar
Środoń, J. and Eberl, D.D., 1984 Illite Micas 13 495–544.CrossRefGoogle Scholar
Thompson, J.R. and Hower, J., 1975 The mineralogy of glauconite Clays and Clay Minerals 23 289–300.CrossRefGoogle Scholar
Tóth, E. Weiszburg, T., Vlahović, I. Tibljaš, D. Durn, G. and Biševac, V., 2006 Two in one: Two different glauconite series from the same rock, Sümeg Marl Formation, Lower Cretaceous, Bakony Mountains, Hungary Abstract Book/ 3rd Mid-European Clay Conference - MECC 06, Opatija, September 18–23, 2006 116.Google Scholar
Tsipursky, S.I. and Ivanovskaya, T.A., 1988 Crystal chemistry of globular layer silicates Litologiya i Poleznye Iskopayemye 23 41–49.Google Scholar
Velde, B., 1978 Infrared spectra of synthetic micas in the series muscovite-MgAl celadonite American Mineralogist 63 343–349.Google Scholar
Velde, B. (1985) Clay Minerals: A Physico-chemical Explanation of Their Occurrence. Developments in Sedimentology, 40, Elsevier, Amsterdam.Google Scholar
Weiszburg, T. Tóth, E. and Beran, A., 2004 Celadonite, the 10-Å green clay mineral of the manganese carbonate ore, rkút, Hungary Acta Mineralogica-Petrographica 45/1 65–80.Google Scholar
Weiszburg, T. Tóth, E. Pop, D., Vlahović, I. Tibljaš, D. Durn, G. and Biševac, V., 2006 Continuous crystal-chemical space for the dioctahedral iron-rich micas and related phases (celadonite, glauconite, Fe-illite) Abstract Book/ 3rd Mid-European Clay Conference - MECC 06, Opatija, September 18–23, 2006 122.Google Scholar
Wilson, M.D., 2013 Rock-Forming Minerals, Volume 3C, Sheet Silicates: Clay Minerals London The Geological Society.Google Scholar
Zaitseva, T.S. Gorokhov, I.M. Ivanovskaya, T.A. Semikhatov, M.A. Kuznetsov, A.B. Mel’nikov, N.N. Arakelyants, M.M. and Yakovleva, O.V., 2008 Mössbauer characteristics, mineralogy and isotopic age (Rb-Sr, K-Ar) of Upper Riphean glauconites from the Uk Formation, the southern Urals Stratigraphy and Geological Correlation 14 227–247.CrossRefGoogle Scholar
Zhukhlistov, A.P., 2005 Crystal structure of celadonite from the electron diffraction data Crystallography Reports 50 902–906.CrossRefGoogle Scholar
Zviagina, B.B. and Drits, V.A., 2012 Structural regularities in 2M 1 dioctahedral micas: The structure modeling approach American Mineralogist 97 1939–1954.CrossRefGoogle Scholar
Zviagina, B.B. McCarty, D.K. Środoń, J. and Drits, V.A., 2004 Interpretation of infrared spectra of dioctahedral smectites in the region of OH-stretching vibrations Clays and Clay Minerals 52 399–410.CrossRefGoogle Scholar
Zviagina, B.B. Sakharov, B. A. and Drits, V. A., 2007 X-ray diffraction criteria for the identification of trans- and cis-vacant varieties of dioctahedral micas Clays and Clay Minerals 55 467–480.CrossRefGoogle Scholar
Zviagina, B.B. Drits, V.A. Środoń, J. McCarty, D.K. and Dorzhieva, O.V., 2015 The illite-aluminoceladonite series: Distinguishing features and identification criteria from X-ray diffraction and infrared spectroscopy data Clays and Clay Minerals 63 378–394.CrossRefGoogle Scholar