Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-26T18:06:22.290Z Has data issue: false hasContentIssue false
  • English
  • Français

Conformational Effects of Adsorbed Polymer on the Swelling Behavior of Engineered Clay Minerals

Published online by Cambridge University Press:  01 January 2024

Sungho Kim ,
Michael A. Motyka ,
Angelica M. Palomino  and
Nikolas J. Podraza
Sungho Kim
Affiliation:
Department of Civil and Environmental Engineering, University of Tennessee, Knoxville, TN 37996, USA
Michael A. Motyka
Affiliation:
Department of Engineering Science and Mechanics, Pennsylvania State University, University Park, PA 16802, USA
Angelica M. Palomino*
Affiliation:
Department of Civil and Environmental Engineering, University of Tennessee, Knoxville, TN 37996, USA
Nikolas J. Podraza
Affiliation:
Department of Physics and Astronomy, University of Toledo, 2801 W. Bancroft St. Mailstop 111, Toledo, OH 43606, USA
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The conformational behavior of polymers in clay-polymer nanocomposites (CPN) is not fully understood because of the many factors involved. The purpose of the present study was to investigate the conformational behavior of a polymer at the micro- and meso-scales in order to predict the behavior of tunable CPN. The study used a pH-responsive polymer, polyacrylamide, which has time-dependent hydrolysis response properties, to examine micro-scale conformational behavior of the polymer adsorbed on representative clay-mineral surfaces, SiO2 and Al2O3. A nanocomposite and a microcomposite were used to link meso-scale CPN behavior to micro-scale polymer conformation. The conformational behavior was characterized using in situ, real-time spectroscopic ellipsometry. The contracted coil conformation of polyacrylamide was observed at pH = 3, while extended conformation was observed at pH = 11.5 on both SiO2 and Al2O3 surfaces. At pH = 11.5, the polymer conformation changed from expanded coil to extended conformation over time. The polymer conformation changed more rapidly with the Al2O3 surface due to mineral dissolution at pH = 3 and 11.5. Swelling tests were conducted as functions of pH and time to link the micro-scale phenomena to meso-scale CPN behavior. The results indicated that the swelling potential of CPN corresponded to the conformation of adsorbed polyacrylamide, which varied with pH and time. The swelling potential of CPN was maximized at pH = 11.5 and decreased with decreasing pH, corresponding to the observed micro-scale conformational behavior.

Keywords

KaoliniteMontmorillonitepH-responsive PolymerPolyacrylamideSpectroscopic EllipsometrySwelling PotentialTunable Clay-polymer Nanocomposites
Type
Article
Information
Clays and Clay Minerals , Volume 60 , Issue 4 , August 2012 , pp. 363 - 373
Copyright
Copyright © Clay Minerals Society 2012

References

Abdullah, W.S. Alshibli, K.A. and Al-Zou’bi, M.S., 1999 Influence of pore water chemistry on the swelling behavior of compacted clays Applied Clay Science 15 447–462.CrossRefGoogle Scholar
Al-Anazi, H.A. and Sharma, M.M., 2002 Use of a pH sensitive polymer for conformance control International Symposium and Exhibition on Formation Damage Control Louisiana Lafayette.Google Scholar
Alexandre, M. and Dubois, P., 2000 Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials Materials Science and Engineering: R: Reports 28 1–63.CrossRefGoogle Scholar
Ashmawy, A.K. El-Hajji, D. Sotelo, N. and Muhammad, N., 2002 Hydraulic performance of untreated and polymertreated bentonite in inorganic landfill leachates Clays and Clay Minerals 50 546–552.CrossRefGoogle Scholar
Askadskii, A.A., 1990 Influence of crosslinking density on the properties of polymer networks Polymer Science U.S.S.R. 32 2061–2069.CrossRefGoogle Scholar
ASTM, 2006 D5890: Standard test method for swell index of clay mineral component of geosynthetic clay liners .Google Scholar
Aulich, D. Hoy, O. Luzinov, I. Brucher, M. Hergenroder, R. Bittrich, E. Eichhorn, K.-J. Uhlmann, P. Stamm, M. Esser, N. and Hinrichs, K., 2010 In situ studies on the switching behavior of ultrathin poly(acrylic acid) polyelectrolyte brushes in different aqueous environments Langmuir 26 12926–12932.CrossRefGoogle ScholarPubMed
Bajpai, A.K. and Giri, A., 2003 Water sorption behaviour of highly swelling (carboxy methylcellulose-g-polyacrylamide) hydrogels and release of potassium nitrate as agrochemical Carbohydrate Polymers 53 271–279.CrossRefGoogle Scholar
Barvenik, F.W., 1994 Polyacrylamide characteristics related to soil applications Soil Science 158 235–243.CrossRefGoogle Scholar
Besra, L. Sengupta, D.K. Roy, S.K. and Ay, P., 2004 Influence of polymer adsorption and conformation on flocculation and dewatering of kaolin suspension Separation and Purification Technology 37 231–246.CrossRefGoogle Scholar
Bittrich, E. Kuntzsch, M. Eichhorn, K.-J. and Uhlmann, P., 2010 Complex pH- and temperature-sensitive swelling behavior of mixed polymer brushes Journal of Polymer Science Part B: Polymer Physics 48 1606–1615.CrossRefGoogle Scholar
Borchardt, G., Dixon, J.B. Weed, S.B. and Dinauer, R.C., 1989 Smectites Minerals in Soil Environments Madison, Wisconsin, USA Soil Science Society of America 675–727.Google Scholar
Caskey, J.A. and Primus, R.J., 1986 The effect of anionic polyacrylamide molecular conformation and configuration on flocculation effectiveness Environmental Progress 5 98–103.CrossRefGoogle Scholar
Castel, D. Ricard, A. and Audebert, R., 1990 Swelling of anionic and cationic starch-based superabsorbents in water and saline solution Journal of Applied Polymer Science 39 11–29.CrossRefGoogle Scholar
Chen, C. An, I. Ferreira, G.M. Podraza, N.J. Zapien, J.A. and Collins, R.W., 2004 Multichannel Mueller matrix ellipsometer based on the dual rotating compensator principle Thin Solid Films 455-456 14–23.CrossRefGoogle Scholar
Cohen Stuart, M.A. Cosgrove, T. and Vincent, B., 1986 Experimental aspects of polymer adsorption at solid/solution interfaces Advances in Colloid and Interface Science 24 143–239.CrossRefGoogle Scholar
Collins, R.W. Ferlauto, A.S., Tompkins, H.G. and Irene, E.A., 2005 Optical properties of materials Handbook of Ellipsometry Norwich, New York, USA William Andrew Publisers, Springer 125–129.Google Scholar
Cong, Y. An, I. Vedam, K. and Collins, R.W., 1991 Optical characterization of a four-medium thin film structure by real time spectroscopic ellipsometry: amorphous carbon on tantalum Applied Optics 30 2692–2703.CrossRefGoogle ScholarPubMed
Fan, X. and Advincula, R.C., 2002 Nanostructured ultrathin films of silicate clay and polyelectrolytes: deposition parameters and mechanical properties by nanoindentation Materials Research Society Symposium Proceedings 335–340.CrossRefGoogle Scholar
Fan, X. Park, M.-k. Xia, C. and Advincula, R., 2002 Surface structural characterization and mechanical testing by nanoindentation measurements of hybrid polymer/clay nanostructured multilayer films Journal of Materials Research 17 1622–1633.CrossRefGoogle Scholar
Filippova, N.L., 1998 Adsorption and desorption kinetics of polyelectrolytes on planar surfaces Langmuir 14 1162–1176.CrossRefGoogle Scholar
Fleer, G.J., 1993 Polymers at Interfaces 1 London, New York Chapman & Hall.Google Scholar
Flory, P.J., 1953 Principles of Polymer Chemistry Ithaca, New York Cornell University Press.Google Scholar
Furusawa, K. Shou, Z. and Nagahashi, N., 1992 Polymer adsorption on fine particles; the effects of particle size and its stability Colloid and Polymer Science 270 212–218.CrossRefGoogle Scholar
Giannelis, E.P. Krishnamoorti, R. and Manias, E., 1999 Polymer-silicate nanocomposites: Model systems for confined polymers and polymer brushes Advances in Polymer Science 138 107–147.CrossRefGoogle Scholar
Gupta, P. Vermani, K. and Garg, S., 2002 Hydrogels: from controlled release to pH-responsive drug delivery Drug Discovery Today 7 569–579.CrossRefGoogle ScholarPubMed
Herbert, H.-J. Kasbohm, J. Sprenger, H. Fernandez, A.M. and Reichelt, C., 2008 Swelling pressures of MX-80 bentonite in solutions of different ionic strength Physics and Chemistry of the Earth 33 S327–S342.CrossRefGoogle Scholar
Herzinger, C.M. Johs, B. McGahan, W.A. Woollam, J.A. and Paulson, W., 1998 Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation Journal of Applied Physics 83 3323–3336.CrossRefGoogle Scholar
Huang, S.-Y. Lipp, D.W. Farinato, R.S., Seidel, A., 2001 Acrylamide polymers Kirk-Othmer Encyclopedia of Chemical Technology New Jersey, USA John Wiley & Sons 304–342.Google Scholar
Ikegami, A. and Imai, N., 1962 Precipitation of polyelectrolytes by salts Journal of Polymer Science 56 133–152.CrossRefGoogle Scholar
Inyang, H.I. Bae, S. Mbamalu, G. and Park, S.-W., 2007 Aqueous polymer effects on volumetric swelling of Namontmorillonite Journal of Materials in Civil Engineering 19 84–90.CrossRefGoogle Scholar
Irene, E.A., 1993 Applications of spectroscopic ellipsometry to microelectronics Thin Solid Films 233 96–111.CrossRefGoogle Scholar
Jaffe, H.W., 1956 Application of the rule of gladstone and dale to minerals American Mineralogist 41 757.Google Scholar
Karnland, O. Olsson, S. Nilsson, U. and Sellin, P., 2007 Experimentally determined swelling pressures and geochemical interactions of compacted Wyoming bentonite with highly alkaline solutions Physics and Chemistry of the Earth 32 275–286.CrossRefGoogle Scholar
Kheradmand, H. Francois, J. and Plazanet, V., 1988 Hydrolysis of polyacrylamide and acrylic acid-acrylamide copolymers at neutral pH and high temperature Polymer 29 860–870.CrossRefGoogle Scholar
Kim, S., 2011 An engineered clay soil system using functional polymers Pennsylvania, USA Pennsylvania State University, University Park.Google Scholar
Kim, S. and Palomino, A.M., 2009 Polyacrylamide-treated kaolin: A fabric study Applied Clay Science 45 270–279.CrossRefGoogle Scholar
Kim, S. and Palomino, A. M., 2011 Factors influencing the synthesis of tunable clay-polymer nanocomposites using bentonite and polyacrylamide Applied Clay Science 51 491–498.CrossRefGoogle Scholar
Kim, S. Palomino, A.M. and Colina, C.M., 2012 Responsive polymer conformation and resulting permeability of claypolymer nanocomposites Molecular Simulation 38 723–734.CrossRefGoogle Scholar
Klenina, O.V. and Lebedeva, L.G., 1983 Viscometric properties of dilute solutions of hydrolyzed polyacrylamide Polymer Science U.S.S.R. 25 2380–2389.CrossRefGoogle Scholar
Kurenkov, V.F., Cheremisinoff, N.P., 1997 Acrylamide polymers Handbook of Engineering Polymeric Materials New York Marcel Dekker 61–72.Google Scholar
Lee, J.J. and Fuller, G.G., 1984 Ellipsometry studies of adsorbed polymer chains subjected to flow Macromolecules 17 375–380.CrossRefGoogle Scholar
Lee, J.W. Kim, S.Y. Kim, S.S. Lee, Y.M. Lee, K.H. and Kim, S.J., 1999 Synthesis and characteristics of interpenetrating polymer network hydrogel composed of chitosan and poly(acrylic acid) Journal of Applied Polymer Science 73 113–120.3.0.CO;2-D>CrossRefGoogle Scholar
Lee, W.-F. and Lin, G.-H., 2001 Superabsorbent polymeric materials VIII: Swelling behavior of crosslinked poly[sodium acrylate-co-trimethyl methacryloyloxyethyl ammonium iodide] in aqueous salt solutions Journal of Applied Polymer Science 79 1665–1674.3.0.CO;2-P>CrossRefGoogle Scholar
Leermakers, F.A.M. Atkinson, P.J. Dickinson, E. and Horne, D.S., 1996 Self-consistent-field modeling of adsorbed [beta]-casein: effects of pH and ionic strength on surface coverage and density profile Journal of Colloid and Interface Science 178 681–693.CrossRefGoogle Scholar
Mahdavinia, G.R. Pourjavadi, A. Hosseinzadeh, H. and Zohuriaan, M. J., 2004 Modified chitosan 4. Superabsorbent hydrogels from poly(acrylic acid-co-acrylamide) grafted chitosan with salt- and pH-responsiveness properties European Polymer Journal 40 1399–1407.CrossRefGoogle Scholar
Michaels, A.S., 1954 Aggregation of suspensions by polyelectrolytes Industrial & Engineering Chemistry 46 1485–1490.CrossRefGoogle Scholar
Myagchenkov, V.A. and Proskurina, V.E., 2004 Flocculation activity (with respect to ocher) of anionic copolymers of acrylamide in the mode of restricted sedimentation as influenced by their chemical heterogeneity Russian Journal of Applied Chemistry 77 463–466.CrossRefGoogle Scholar
Pefferkorn, E., 1999 Polyacrylamide at solid/liquid interfaces Journal of Colloid and Interface Science 216 197–220.CrossRefGoogle ScholarPubMed
Ray, S.S. and Okamoto, M., 2003 Polymer/layered silicate nanocomposites: a review from preparation to processing Progress in Polymer Science 28 1539–1641.Google Scholar
Ringenbach, E. Chauveteau, G. and Pefferkorn, E., 1993 Adsorption of polyelectrolytes on soluble oxides induced by polyion complexation with dissolution species Journal of Colloid and Interface Science 161 223–231.CrossRefGoogle Scholar
Ringenbach, E. Chauveteau, G. and Pefferkorn, E., 1995 Effect of soluble aluminum ions on polyelectrolyte-alumina interaction Kinetics of polymer adsorption and colloid stabilization. Colloids and Surfaces A: Physicochemical and Engineering Aspects 99 161–173.Google Scholar
Ruiz-Hitzky, E. van Meerbeek, A., Bergaya, F. Theng, B.K.G. and Lagaly, G., 2006 Clay mineraland organoclay-polymer nanocomposite Handbook of Clay Science Amsterdam Elsevier 141–245.Google Scholar
Russev, S.C. Arguirov, T.V. and Gurkov, T.D., 2000 [beta]-Casein adsorption kinetics on air-water and oil-water interfaces studied by ellipsometry Colloids and Surfaces B: Biointerfaces 19 89–100.CrossRefGoogle Scholar
Samoshina, Y. Nylander, T. Shubin, V. Bauer, R. and Eskilsson, K., 2005 Equilibrium aspects of polycation adsorption on silica surface: How the adsorbed layer responds to changes in bulk solution Langmuir 21 5872–5881.CrossRefGoogle ScholarPubMed
Schmidt, D.J. Cebeci, F.C. Kalcioglu, Z.I. Wyman, S.G. Ortiz, C. Van Vliet, K.J. and Hammond, P.T., 2009 Electrochemically controlled swelling and mechanical properties of a polymer nanocomposite ACS Nano 3 2207–2216.CrossRefGoogle ScholarPubMed
Schwarz, S. Eichhorn, K.J. Wischerhoff, E. and Laschewsky, A., 1999 Polyelectrolyte adsorption onto planar surfaces: a study by streaming potential and ellipsometry measurements Colloids and Surfaces A: Physicochemical and Engineering Aspects 159 491–501.CrossRefGoogle Scholar
Shackelford, C.D. Benson, C.H. Katsumi, T. Edil, T.B. and Lin, L., 2000 Evaluating the hydraulic conductivity of GCLs permeated with non-standard liquids Geotextiles and Geomembranes 18 133–161.CrossRefGoogle Scholar
Shubin, V. and Linse, P., 1995 Effect of electrolytes on adsorption of cationic polyacrylamide on silica: Ellipsometric study and theoretical modeling The Journal of Physical Chemistry 99 1285–1291.CrossRefGoogle Scholar
Snoeyink, V.L. and Jenkins, D., 1980 Water Chemistry New York, Singapore John Wiley & Sons.Google Scholar
Spencer, H.G., 1962 A note on dissociation constants of polycarboxylic acids Journal of Polymer Science 56 S25–S28.CrossRefGoogle Scholar
Stemme, S. Odberg, L. and Malmsten, M., 1999 Effect of colloidal silica and electrolyte on the structure of an adsorbed cationic polyelectrolyte layer Colloids and Surfaces A: Physicochemical and Engineering Aspects 155 145–154.CrossRefGoogle Scholar
Strawhecker, K.E. Manias, E., Mai, Y.W. and Yu, Z.-Z., 2006 Nanocomposites based on water soluble polymers and unmodified smectite clays Polymer nanocomposites Florida, USA CRC Press, Boca Raton 206–233.CrossRefGoogle Scholar
Stumm, W., 1992 Chemistry of the Solid-Water Interface: Processes at the Mineral-Water and Particle-Water Interface in Natural Systems New York Wiley.Google Scholar
Synowicki, R.A. Pribil, G.K. Cooney, G. Herzinger, C.M. Green, S.E. French, R.H. Yang, M.K. Burnett, J.H. and Kaplan, S., 2004 Fluid refractive index measurements using rough surface and prism minimum deviation techniques Journal of Vacuum Science & Technology B 22 3450–3453.CrossRefGoogle Scholar
van Olphen, H., 1977 An Introduction to Clay Colloid Chemistry: For Clay Technologists, Geologists, and Soil Scientists New York Wiley.Google Scholar
Vazquez, B. Roman, J.S. Peniche, C. and Cohen, M.E., 1997 Polymeric hydrophilic hydrogels with flexible hydrophobic chains Control of the hydration and interact ions with water molecules. Macromolecules 30 8440–8446.Google Scholar
Wang, J. Wang, D.Y. Li, F. Tang, X.G. Chan, H.L.W. Mo, D. and Choy, C.L., 2004 Simple transmission ellipsometry method for measuring the electric-field-induced birefringence in PLZT thin films Journal of Materials Science 39 1805–1807.CrossRefGoogle Scholar
Wehrli, B. Wieland, E. and Furrer, G., 1990 Chemical mechanisms in the dissolution kinetics of minerals; the aspect of active sites Aquatic Sciences 52 3–31.CrossRefGoogle Scholar
Wu, J. Lin, J. Li, G. and Wei, C., 2001 Influence of the COOH and COONa groups and crosslink density of poly(acrylic acid)/montmorillonite superabsorbent composite on water absorbency Polymer International 50 1050–1053.CrossRefGoogle Scholar