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Condensation of Olefins on Clays. Gas-Solid Systems. Part I: Gravimetric Methods

Published online by Cambridge University Press:  28 February 2024

Eduardo Choren ,
Alexander Moronta ,
Gustavo Varela ,
Arnedo Arteaga  and
Jorge Sánchez
Eduardo Choren
Affiliation:
Centro de Superficies y Catálisis, Facultad de Ingeniería, Universidad del Zulia, Apartado 15251, Maracaibo 4003A, Venezuela
Alexander Moronta
Affiliation:
Centro de Superficies y Catálisis, Facultad de Ingeniería, Universidad del Zulia, Apartado 15251, Maracaibo 4003A, Venezuela
Gustavo Varela
Affiliation:
Centro de Superficies y Catálisis, Facultad de Ingeniería, Universidad del Zulia, Apartado 15251, Maracaibo 4003A, Venezuela
Arnedo Arteaga
Affiliation:
Centro de Superficies y Catálisis, Facultad de Ingeniería, Universidad del Zulia, Apartado 15251, Maracaibo 4003A, Venezuela
Jorge Sánchez
Affiliation:
Centro de Superficies y Catálisis, Facultad de Ingeniería, Universidad del Zulia, Apartado 15251, Maracaibo 4003A, Venezuela
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Abstract

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The adsorption-condensation of olefins was studied on 7 adsorbents: 2 commercial clays, a natural clay and its protonated form, γ-alumina and porous and nonporous silicas. These adsorbents were characterized by X-ray diffraction (XRD), chemical analysis, thermogravimetric analysis (TGA), differential thermal analysis (DTA) and determination of specific surface area measurement by the BET method. The experiments were carried out gravimetrically, in gas- or vapor-solid systems, at 25 °C and on adsorbents dried at 120 °C. Adsorption-condensation of olefins are fast processes, diffusion controlled. Alumina and silicas adsorb olefins and paraffins only reversibly, but are unable to condense olefins. The water polarized by the countercations is the source of Brønsted acid sites. When the gas phase is evacuated or swept with inert gas, the condensation terminates. On clays, paraffins are reversibly adsorbed but no condensation was observed.

Keywords

AdsorptionClaysCondensationOlefinsOligomerizationParaffins
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 2 , April 1997 , pp. 213 - 220
Copyright
Copyright © 1997, The Clay Minerals Society

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