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Complex Formation of Cation-Exchanged Montmorillonites with Propylene Carbonate: Osmotic Swelling in Aqueous Electrolyte Solutions

Published online by Cambridge University Press:  28 February 2024

Masanobu Onikata ,
Mrrsuji Kondo ,
Naoki Hayashi  and
Shoji Yamanaka
Masanobu Onikata
Affiliation:
Laboratory of Applied Clay Technology (LACT), Hojun Kogyo Co., Ltd., 1433-1 Haraichi, Annaka, Gunma 379-0133, Japan
Mrrsuji Kondo
Affiliation:
Laboratory of Applied Clay Technology (LACT), Hojun Kogyo Co., Ltd., 1433-1 Haraichi, Annaka, Gunma 379-0133, Japan
Naoki Hayashi
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
Shoji Yamanaka
Affiliation:
Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan
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Abstract

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Montmorillonites saturated with Li+, Na+, K+, NH4+, Mg2+, Ca2+, Ba2+, or Ni2+ ions can form complexes with propylene carbonate (PC) by intercalation; the d(001) of montmorillonite expands to 19 Å. In the infrared absorption spectra of these complexes, the C=0 stretching band of the intercalated PC molecules shifts to lower frequencies, and the amount of the shift increased with the increase of the polarizing power of the interlayer cations. Water molecules were strongly bound to the cations. The PC molecules interacted with the cations by way of H2O molecules. With the removal of H2O, the PC molecules directly coordinate to the cations and the PC molecules show a much larger red-shift in the C=O frequency. The PC-montmorillonite complexes exhibited osmotic swelling, even in aqueous electrolyte solutions. This finding is interpreted in terms of the formation of thick electric double-layers consisting of PC and H2O between the 2:1 layers.

Keywords

Infra-Red SpectroscopyIntercalation ComplexMontmorilloniteOsmotic SwellingPropylene Carbonate
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 5 , October 1999 , pp. 672 - 677
Copyright
Copyright © 1999, The Clay Minerals Society

References

Calamai, L. Pantani, O. Pusino, A. Gessa, C. and Fusi, P., 1997 Interaction of rimsulfuron with smectites Clays and Clay Minerals 45 23–27 10.1346/CCMN.1997.0450103.CrossRefGoogle Scholar
Dowdy, R.H. and Mortland, M.M., 1967 Alcohol-water interactions on montmorillonite surfaces. I. Ethanol Clays and Clay Minerals 15 259–271 10.1346/CCMN.1967.0150131.CrossRefGoogle Scholar
Fusi, P. Ristori, G.G. and Franci, M., 1986 Interactions of carbaryl with homoionic montmorillonite Applied Clay Science 1 375–383 10.1016/0169-1317(86)90012-8.CrossRefGoogle Scholar
Fusi, P. Franci, M. and Bosetto, M., 1988 Interaction of fiuazifop-butyl and fluazifop with smectites Applied Clay Science 3 63–73 10.1016/0169-1317(88)90006-3.CrossRefGoogle Scholar
Glaeser, R., 1948 On the mechanism of formation of montmorillonite-acetone complexes Clay Minerals Bulletin 1 88–90.Google Scholar
Gutmann, V., 1976 Empirical parameters for donor and acceptor properties of solvents Electrochimica Acta 21 661–670 10.1016/0013-4686(76)85034-7.CrossRefGoogle Scholar
Israelachvili, J.N., 1991 Intermolecular and Surface Forces 2nd edition London Academic Press.Google Scholar
Kondo, M., 1996 US Patent 5,573,583 .Google Scholar
Konta, J., 1995 Clay and man: Clay raw materials in the service of man Applied Clay Science 10 275–335 10.1016/0169-1317(95)00029-4.CrossRefGoogle Scholar
MacEwan, D.M.C. Wilson, M.J., Brindley, G.W. and Brown, G., 1980 Interlayer and intercalation complexes of clay minerals Crystal Structures of Clay Minerals and Their X-ray Identification London Mineralogical Society 197–248.CrossRefGoogle Scholar
Mortland, M.M. and Brady, N.C., 1970 Clay-organic complexes and interactions Advances in Agronomy, Volume 22 New York Academic Press 75–117 10.1016/S0065-2113(08)60266-7.CrossRefGoogle Scholar
Norrish, K. and Quirk, J.P., 1954 Crystalline swelling of montmorillonite. Use of electrolytes to control swelling Nature 173 255–256 10.1038/173255a0.CrossRefGoogle Scholar
Olejnik, S. Posner, A.M. and Quirk, J.P., 1974 Swelling of montmorillonite in polar organic liquids Clays and Clay Minerals 22 361–365 10.1346/CCMN.1974.0220407.CrossRefGoogle Scholar
Onikata, M. Kondo, M. Kamon, M. and Kamon, M., 1996 Development and characterization of a multiswellable bentonite Environmental Geotechnics Rotterdam A.A. Balkema Publishers 587–590.Google Scholar
Parfitt, R.L. and Mortland, M.M., 1968 Ketone adsorption on montmorillonite Soil Science Society America Proceedings 32 355–363 10.2136/sssaj1968.03615995003200030027x.CrossRefGoogle Scholar
Pusino, A. Liu, W. and Gessa, C., 1993 Dimepiperate adsorption and hydrolysis on Al3+-, Fe3+-, Ca2+-, and Na+-montmorillonite Clays and Clay Minerals 41 335–340 10.1346/CCMN.1993.0410308.CrossRefGoogle Scholar
Tensmeyer, L.G. Hoffmann, R.W. and Brindley, G.W., 1960 Infrared studies of some complexes between ketones and calcium montmorillonite. Clay-organic studies. Part III Journal of Physical Chemistry 64 1655–1662 10.1021/j100840a013.CrossRefGoogle Scholar
Theng, B.K.G., 1974 The Chemistry of Clay-Organic Reactions London Adam Hilger.Google Scholar
Yamanaka, S. Kanamaru, F. and Koizumi, M., 1974 Role of interlayer cations in the formation of acrylonitrile-montmorillonite complexes Journal of Physical Chemistry 78 42–44 10.1021/j100594a008.CrossRefGoogle Scholar
Yamanaka, S. Kanamaru, F. and Koizumi, M., 1975 Studies on the orientation of acrylonitrile adsorbed on interlamellar surfaces of montmorillonites Journal of Physical Chemistry 79 1285–1288 10.1021/j100580a012.CrossRefGoogle Scholar