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Combination Bands in the Infrared Spectroscopy of Kaolins—A Drift Spectroscopic Study

Published online by Cambridge University Press:  28 February 2024

Ray L. Frost  and
Ursula Johansson
Ray L. Frost
Affiliation:
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane Queensland 4001, Australia
Ursula Johansson*
Affiliation:
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane Queensland 4001, Australia
*
†Permanent address: Department of Chemical and Metallurgical Engineering, Division of Inorganic Chemistry, Luleå University of Technology, SE-971 87 Lulegå, Sweden.
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Abstract

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Kaolinites with varying degrees of defect structures have been studied by both mid-infrared (IR) and near-IR diffuse reflectance spectroscopy (DRIFT). Difference bands were observed in the 2650- to 2750-cm−1 region. This region coincides with the kaolinite-deuterated hydroxyl stretching region. Summation bands were observed in the near-IR spectra in the 4500- to 4650-cm−1 and in the 7050- to 7250- cm−1 region. Each of the spectral regions of the summation and difference bands is both kaolin polytype and sample dependent. It is proposed that each of these sets of bands arises from the combination of the hydroxyl stretching frequencies and the hydroxyl deformation frequencies and, to a lesser extent, the silicon-oxygen symmetric stretching vibration of the siloxane layer. Additional difference bands of very low intensity were also observed at 2930 and 2856 cm−1. Combination bands were observed in all kaolinites at 2137 and 2227 cm−1. Each of the 3 major combination spectral regions was composed of 5 component bands corresponding to the 4 IR active and the 1 Raman active kaolinite hydroxyl stretching frequencies. Combination bands were also observed at ~1932 and 1821 cm−1.

Keywords

Combination BandsDifference BandsDRIFTKaolinsKaolinitesMid-InfraredNear-InfraredRaman
Type
Research Article
Information
Clays and Clay Minerals , Volume 46 , Issue 4 , August 1998 , pp. 466 - 477
Copyright
Copyright © 1998, The Clay Minerals Society

References

Brindley, G.W. Chih-Chun, K. Harrison, J.L. Lipsiscas, M. and Raythatha, R., 1986 Relation between the structural disorder and other characteristics of kaolinites and dickites Clays Clay Miner 34 34–249 10.1346/CCMN.1986.0340303.CrossRefGoogle Scholar
Cases, J.M. Lietard, O. Yvon, J. and Delon, J.F., 1992 Étude des propriétés cristallochimiques, morphologiques, superficielles de kaolinites déordonnées Bull Mineral 105 439–455.Google Scholar
Crowley, J.K. and Vergo, N., 1988 Near-infrared reflectance spectra of mixtures of kaolin-group minerals: Use in clay mineral studies Clays Clay Miner 36 36 16 10.1346/CCMN.1988.0360404.CrossRefGoogle Scholar
Cruz-Cumplido, M. Sow, C. and Fripiat, J.J., 1992 Spectre infrarouge des hydroxyles, cristallinit6é et énergie de cohésion des kaolins Bull Mineral 105 493–498.Google Scholar
Delineau, T. Allard, T. Muller, J. and Barres, V., 1994 FTIR reflectance vs. EPR studies of structural iron in kaolinites Clays Clay Miner 42 308–320 10.1346/CCMN.1994.0420309.CrossRefGoogle Scholar
Farmer, V.C. and Farmer, V.C., 1974 The layer silicates The Infrared spectra of minerals London Mineral. Soc 331–363 10.1180/mono-4.15.CrossRefGoogle Scholar
Farmer, V.C. and Russell, J.D., 1964 The infrared spectra of layered silicates Spectrochim Acta 20 20–1173 10.1016/0371-1951(64)80165-X.CrossRefGoogle Scholar
Frost, R.L. and Vassallo, A.M., 1996 The dehydroxylation of the kaolinite clay minerals using infrared emission spectroscopy Clays Clay Miner 44 44–651 10.1346/CCMN.1996.0440506.CrossRefGoogle Scholar
Frost, R.L. Fredericks, P.M. and Bartlett, J.R., 1993 Fourier transform Raman spectroscopy of kandite clays Spectrochim Acta 20 667–674 10.1016/0584-8539(93)80088-R.CrossRefGoogle Scholar
Frost, R.L., 1995 Fourier transform Raman spectroscopy of kaolinite, dickite and halloysite Clays Clay Miner 43 191–195 10.1346/CCMN.1995.0430206.CrossRefGoogle Scholar
Frost, R.L., 1997 The Structure of the kaolin clay minerals—An FT Raman study Clay Miner 32 32–85.Google Scholar
Frost, R.L. and van der Gaast, S.J., 1997 Kaolinite hydroxyls—A Raman microscopy study Clay Miner 32 32–306.Google Scholar
Frost, R.L., 1998 Hydroxyl deformation in kaolinites Clays Clay Miner 46 46–289.CrossRefGoogle Scholar
Giese, R.F. and Bailey, S.W., 1988 Kaolin minerals: Structures and stabilities. Rev Mineral 19 Hydrous phyllosilicates. Mineral Soc Am. Chelsea, MI BookCrafters 29–66 10.1515/9781501508998-008.CrossRefGoogle Scholar
Hess, C.A. and Saunders, V.R., 1992 Periodic ab initio Hartree-Fock calculations of the low symmetry mineral kaolinite I Phys Chem 96 96–4374.Google Scholar
Hinckley, D.N., 1963 Variability in “crystallinity” values among the kaolin deposits of the coastal plain of Georgia and South Carolina Clays Clay Miner 11 11–235.Google Scholar
Hunt, G.R. and Hall, R.B., 1981 Identification of kaolins and associated minerals in altered volcanic rocks by infrared spectroscopy Clays Clay Miner 29 29–78 10.1346/CCMN.1981.0290114.CrossRefGoogle Scholar
Hunt, G.R. and Ashley, R.P., 1979 Spectra of altered rocks in the visible and near infrared Econ Geol 74 74–1629 10.2113/gsecongeo.74.7.1613.CrossRefGoogle Scholar
Hunt, G.R. Salisbury, J.W. and Lenhoff, C.J., 1973 Visible and near-IR spectra of minerals and rocks. VI. Additional silicates Modern Geol 4 4–106.Google Scholar
Johansson, U. Holmgren, A. Forsling, W. and Frost, R.L., 1998 Isotopic exchange of kaolinite hydroxyl protons—A diffuse reflectance infrared Fourier transform spectroscopic study Analyst 123 123–645.CrossRefGoogle Scholar
Karakassides, K. Petridis, D. and Gournis, D., 1997 Infrared reflectance studies of thermally treated Li- and Cs- montmorillonites Clays Clay Miner 45 45–658 10.1346/CCMN.1997.0450504.CrossRefGoogle Scholar
Lazarev, A.N., 1972 Vibrational spectra and structure of silicates New York Plenum Pr. 178–182.Google Scholar
Lindberg, J.D. and Snyder, D.G., 1972 Diffuse reflectance spectra of several clay minerals Am Mineral 57 57–493.Google Scholar
Matsunaga, T. and Uwasawa, M., 1993 Near infrared diffuse reflectance spectra of clay minerals Nippon Dojo Hiryogaku Zasshi 64 64–331.Google Scholar
Michaelian, K.H. Bukka, K. and Permann, D.N.S., 1987 Photoacoustic infrared spectra (250–10,000 cm−1) of partially deuterated kaolinite #9 Can J Chem 65 65–1423.Google Scholar
Michaelian, K.H., 1986 The Raman spectrum of kaolinite #9 at 21°C Can J Chem 64 64–289 10.1139/v86-048.CrossRefGoogle Scholar
Tanabe, K. Uesaka, H. Inoue, T. Takahashi, H. and Tanaka, S., 1994 Identification of mineral components from near infrared spectra by a neural network Bunseki Kagaku 43 43–769 10.2116/bunsekikagaku.43.765.CrossRefGoogle Scholar
Yvon, J. Lietard, O. Cases, J.M. and Delon, J.F., 1992 Minéralogie des argiles kaoliniques des Charentes Bull Mineral 105 105–581.Google Scholar