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Colloid Diffusion in Compacted Bentonite: Microstructural Constraints

Published online by Cambridge University Press:  01 January 2024

Michael Holmboe ,
Susanna Wold  and
Mats Jonsson
Michael Holmboe*
Affiliation:
KTH School of Chemical Science and Engineering, Nuclear Chemistry, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
Susanna Wold
Affiliation:
KTH School of Chemical Science and Engineering, Nuclear Chemistry, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
Mats Jonsson
Affiliation:
KTH School of Chemical Science and Engineering, Nuclear Chemistry, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
*
* E-mail address of corresponding author: [email protected]
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Abstract

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In Sweden and in many other countries, a bentonite barrier will be used in the repository for spent nuclear fuel. In the event of canister failure, colloidal diffusion is a potential, but scarcely studied mechanism of radionuclide migration through the bentonite barrier. Column and in situ experiments are vital in understanding colloid diffusion and in providing information about the micro structure of compacted bentonite and identifying cut-off limits for colloid filtration. This study examined diffusion of negatively charged 2-, 5-, and 15-nm gold colloids in 4-month diffusion experiments using MX-80 Wyoming bentonite compacted to dry densities of 0.6–2.0 g/cm3. Breakthrough of gold colloids was not observed in any of the three diffusion experiments. In a gold-concentration profile analysis, colloid diffusion was only observed for the smallest gold colloids at the lowest dry density used (estimated apparent diffusivity Da ≈ 5 × 10−13 m2/s). The results from a microstructure investigation using low-angle X-ray diffraction suggest that at the lowest dry density used, interlayer transport of the smallest colloids cannot be ruled out as a potential diffusion pathway, in addition to the expected interparticle transport. In all other cases, with either greater dry densities or larger gold colloids, compacted bentonite will effectively prevent diffusion of negatively charged colloids due to filtration.

Keywords

Colloid FiltrationCompacted BentoniteGold ColloidsDiffusionMicrostructureNuclear Waste Disposal
Type
Article
Information
Clays and Clay Minerals , Volume 58 , Issue 4 , August 2010 , pp. 532 - 541
Copyright
Copyright © The Clay Minerals Society 2010

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