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Chlorite Geothermometry: A Review

Published online by Cambridge University Press:  28 February 2024

Patrice de Caritat ,
Ian Hutcheon  and
John L. Walshe
Patrice de Caritat
Affiliation:
Department of Geology and Geophysics, University of Calgary, Alberta, Canada T2N 1N4
Ian Hutcheon
Affiliation:
Department of Geology and Geophysics, University of Calgary, Alberta, Canada T2N 1N4
John L. Walshe
Affiliation:
Department of Geology, Australian National University, Canberra, A.C.T. 2601, Australia
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Abstract

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Chlorite minerals, found in a great variety of rocks and geological environments, display a wide range of chemical compositions and a variety of polytypes, which reflect the physicochemical conditions under which they formed. Of particular importance for studies dealing with ore deposit genesis, metamorphism, hydrothermal alteration or diagenesis is the paleotemperature of chlorite crystallization. However, in order to understand the relationship between chlorite composition and formation temperature and hence use chlorite as a geothermometer, one must determine how other parameters influence chlorite composition. These parameters may include fO2 and pH of the solution and Fe/(Fe + Mg) and bulk mineral composition of the host rock.

Four approaches to chlorite geothermometry, one structural and three compositional, have been proposed in the past: 1) a polytype method based on the (largely qualitative) observation that structural changes in chlorite may be partly temperature-dependent (Hayes, 1970); 2) an empirical calibration between the tetrahedral aluminum occupancy in chlorites and measured temperature in geothermal systems (Cathelineau, 1988), which has subsequently been modified by several workers; 3) a six-component chlorite solid solution model based upon equilibrium between chlorite and an aqueous solution, which uses thermodynamic properties calibrated with data from geothermal and hydrothermal systems (Walshe, 1986); and 4) a theoretical method based on the intersection of chlorite-carbonate reactions and the CO2-H2O miscibility surface in temperature-XCO2 space, which requires that the composition of a coexisting carbonate phase (dolomite, ankerite, Fe-calcite or siderite) be known or estimated (Hutcheon, 1990). These four approaches are reviewed and the different calculation methods for the compositional geothermometers are applied to a selection of chlorite analyses from the literature. Results of this comparative exercise indicate that no single chlorite geothermometer performs satisfactorily over the whole range of natural conditions (different temperatures, coexisting assemblages, Fe/(Fe + Mg), fO2, etc.). Therefore, chlorite geothermometry should be used with caution and only in combination with alternative methods of estimating paleotemperatures.

Keywords

ChloriteCompositionGeothermometryPolytypeReview
Type
Research Article
Information
Clays and Clay Minerals , Volume 41 , Issue 2 , April 1993 , pp. 219 - 239
Copyright
Copyright © 1993, The Clay Minerals Society

References

Albee, A., 1962 Relation between mineral association, chemical composition and physical properties of the chlorite series Amer. Mineral. 47 851 – 870.Google Scholar
Angus, S., Armstrong, B. and de Reuck, K. M., 1976 International Thermodynamic Tables of the Fluid State: Carbon Dioxide International Union of Pure and Applied Chemistry, Division of Physical Chemistry, Commission on Thermodynamics and Thermochemistry Elmsford, New York Pergamon Press.Google Scholar
Bailey, S. W., Brindley, G. W. and Brown, G., 1984 Structures of layer silicates Crystal Structures of Clay Minerals and Their X-Ray Identification 1 – 124.CrossRefGoogle Scholar
Bailey, S. W., 1988 Chlorites: Structures and crystal chemistry Hydrous Phyllosilicates (Exclusive of Micas) 19 347 – 403 10.1515/9781501508998-015.CrossRefGoogle Scholar
Bailey, S. W., 1988 X-ray diffraction identification of the polytypes of mica, serpentine, and chlorite Clays & Clay Minerals 36 193 – 213 10.1346/CCMN.1988.0360301.CrossRefGoogle Scholar
Bailey, S. W. and Brown, B. E., 1962 Chlorite polytypism: I. Regular and semi-random one-layer structures Amer. Mineral. 47 819 – 850.Google Scholar
Barta, L. and Bradley, D. J., 1985 Extension of the specific interaction model to include gas solubilities in high temperature brines Geochim. Cosmochim. Acta 49 195 – 203 10.1016/0016-7037(85)90204-2.CrossRefGoogle Scholar
Bevins, R. E., Robinson, D. and Rowbotham, G., 1991 Compositional variations in mafic phyllosilicates from regional low-grade metabasites and application of the chlorite geothermometer J. Metam. Geol. 9 711 – 721 10.1111/j.1525-1314.1991.tb00560.x.CrossRefGoogle Scholar
Bottinga, Y. and Richet, P., 1981 High pressure and temperature equation of state and calculation of the thermodynamic properties of gaseous carbon dioxide Amer. J. Sci. 281 615 – 660 10.2475/ajs.281.5.615.CrossRefGoogle Scholar
Bowers, T. S. and Helgeson, H. C., 1983 Calculation of the thermodynamic and geochemical consequences of nonideal mixing in the system H2O-CO2-NaCl on phase relations in geologic systems: Equation of state for H2O-CO2-NaCl fluids at high pressures and temperatures Geochim. Cosmochim. Acta 47 1247 – 1275 10.1016/0016-7037(83)90066-2.CrossRefGoogle Scholar
Brown, B. E. and Bailey, S. W., 1963 Chlorite polytypism: II. Crystal structure of a one-layer Cr-chlorite Amer. Mineral. 48 42 – 61.Google Scholar
Cathelineau, M., 1988 Cation site occupancy in chlorites and illites as a function of temperature Clay Miner. 23 471 – 485 10.1180/claymin.1988.023.4.13.CrossRefGoogle Scholar
Cathelineau, M. and Izquierdo, G., 1988 Temperature-composition relationships of authigenic micaceous minerals in the Los Azufres geothermal system Contrib. Mineral. Petrol. 100 418 – 428 10.1007/BF00371372.CrossRefGoogle Scholar
Cathelineau, M. and Nieva, D., 1985 A chlorite solid solution geothermometer. The Los Azufres (Mexico) geothermal system Contrib. Mineral. Petrol. 91 235 – 244 10.1007/BF00413350.CrossRefGoogle Scholar
Curtis, C. D., Hughes, C. R., Whiteman, J. A. and Whittle, C. K., 1985 Compositional variation within some sedimentary chlorites and some comments on their origin Mineral. Mag. 49 375 – 386 10.1180/minmag.1985.049.352.08.CrossRefGoogle Scholar
De Caritat, P. and Walshe, J. L., 1990 Chlorite geother-mometry in low-temperature (diagenetic) investigations Geol. Soc. Australia Abstracts 25 284 – 285.Google Scholar
Deer, W. A., Howie, R. A. and Zussman, J., 1966 An Introduction to the Rock Forming Minerals .Google Scholar
Egeberg, P. K. and Aagaard, P., 1989 Origin and evolution of formation waters from oil fields on the Norwegian shelf Appl. Geochem. 4 131 – 142 10.1016/0883-2927(89)90044-9.CrossRefGoogle Scholar
Eggleton, R. A., Foudoulis, C. and Varkevisser, D., 1987 Weathering of basalt: Changes in rock chemistry and mineralogy Clays & Clay Minerals 35 161 – 169 10.1346/CCMN.1987.0350301.CrossRefGoogle Scholar
Engel, A E J and Engel, C. G., 1960 Progressive meta-morphism and granitization of the Major paragneiss, northwest Adirondack Mountains, New York. Part II: Mineralogy Bull. Geol. Soc. Amer. 71 1 – 58 10.1130/0016-7606(1960)71[1:PMAGOT]2.0.CO;2.CrossRefGoogle Scholar
Foster, M. D., (1962) Interpretation of the composition and a classification of the chlorites: U.S. Geological Survey Professional Paper 414–A, 33 pp.Google Scholar
Hayes, J. B., 1970 Polytypism of chlorite in sedimentary rocks Clays & Clay Minerals 18 285 – 306 10.1346/CCMN.1970.0180507.CrossRefGoogle Scholar
Hey, M. H., 1954 A new review of the chlorites Mineral. Mag. 30 277 – 292.Google Scholar
Hillier, S. and Velde, B., 1991 Octahedral occupancy and the chemical composition of diagenetic (low-temperature) chlorites Clay Miner. 26 149 – 168 10.1180/claymin.1991.026.2.01.CrossRefGoogle Scholar
Hutcheon, I., 1977 The Metamorphism of Sulfide-Bearing Pelitic Rocks from Snow Lake, Manitoba Ottawa, Canada Carleton University 10.22215/etd/1977-00341.CrossRefGoogle Scholar
Hutcheon, I., 1990 Clay-carbonate reactions in the Venture area, Scotia Shelf, Nova Scotia, Canada Fluid-Mineral Interactions: A Tribute to H. P. Eugster 2 199 – 212.Google Scholar
Hutcheon, I., Oldershaw, A. and Ghent, E. D., 1980 Diagenesis of Cretaceous sandstones of the Kootenay Formation at Elk Valley (southeastern British Columbia) and Mt. Allan (southwestern Alberta) Geochim. Cosmochim. Acta 44 1425 – 1435 10.1016/0016-7037(80)90108-8.CrossRefGoogle Scholar
Hutcheon, I., Shevalier, M. and Abercrombie, H., 1993 pH buffering by metastable mineral-fluid equilibria and evolution of carbon dioxide fugacity during burial diagenesis Geochim. Cosmochim. Acta 57 1017 – 1027 10.1016/0016-7037(93)90037-W.CrossRefGoogle Scholar
Jahren, J. S., 1991 Evidence for Ostwald ripening related recrystallization of diagenetic chlorites from reservoir rocks offshore Norway Clay Miner. 26 169 – 178 10.1180/claymin.1991.026.2.02.CrossRefGoogle Scholar
Jahren, J. S. and Aagaard, P., 1989 Compositional variations in diagenetic chlorites and illites, and relationships with formation-water chemistry Clay Miner. 24 157 – 170 10.1180/claymin.1989.024.2.04.CrossRefGoogle Scholar
Jahren, J. S. and Aagaard, P., 1992 Illite-chlorite assemblages in arenite: Chemical evolution Clays & Clay Minerals .CrossRefGoogle Scholar
Johnson, J. W., Oelkers, E. H. and Helgeson, H. C., 1992 SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0° to 1000°C Computers & Geosciences 18 899 – 947 10.1016/0098-3004(92)90029-Q.CrossRefGoogle Scholar
Jowett, E. C., 1991 Fitting iron and magnesium into the hydrothermal chlorite geothermometer GAC/MAC/SEG Joint Annual Meeting (Toronto, May 27–29, 1991), Program with Abstracts 16 A62.Google Scholar
Karpova, G. V., 1969 Clay mineral post-sedimentary ranks in terrigenous rocks Sedimentology 13 5 – 20 10.1111/j.1365-3091.1969.tb01118.x.CrossRefGoogle Scholar
Kavalieris, I., Walshe, J. L., Halley, S. and Harrold, B. P., 1990 Dome-related gold mineralization in the Pani Volcanic Complex, North Sulawesi, Indonesia: A study of geologic relations, fluid inclusions and chlorite composition Econ. Geol. 85 1208 – 1225 10.2113/gsecongeo.85.6.1208.CrossRefGoogle Scholar
Kranidiotis, P. and MacLean, W. H., 1987 Systematics of chlorite alteration at the Phelps Dodge massive sulfide deposit, Matagami, Quebec Econ. Geol. 82 1898 – 1911 10.2113/gsecongeo.82.7.1898.CrossRefGoogle Scholar
Lister, J. S. and Bailey, S. W., 1967 Chlorite polytypism: IV. Regular two-layer structures Amer. Mineral. 52 1614 – 1631.Google Scholar
Lonker, S. W., Fitzgerald, J., Hedenquist, J. W. and Walshe, J. L., 1990 Mineral-fluid interaction in the Broadlands-Ohaaki geothermal system, New Zealand Amer. J. Sci. 290 995 – 1068 10.2475/ajs.290.9.995.CrossRefGoogle Scholar
McDowell, S. D. and Elders, W. A., 1980 Authigenic layer silicate minerals in borehole Elmore 1, Salton Sea geothermal field, California, USA Contrib. Mineral. Petrol. 74 293 – 310 10.1007/BF00371699.CrossRefGoogle Scholar
McDowell, S. D. and Paces, J. B., 1985 Carbonate alteration minerals in the Salton Sea geothermal system, California, USA Mineral. Mag. 49 469 – 479 10.1180/minmag.1985.049.352.17.CrossRefGoogle Scholar
Muffler, L P J and White, D. E., 1969 Active metamorphism of Upper Cenozoic sediments in the Salton Sea geothermal field and the Salton Trough, southeastern California Bull. Geol. Soc. Amer. 80 157 – 182 10.1130/0016-7606(1969)80[157:AMOUCS]2.0.CO;2.CrossRefGoogle Scholar
Nockolds, S. R., 1947 The relation between chemical composition and paragenesis in biotite micas of igneous rocks Amer. J. Sci. 245 401 – 420 10.2475/ajs.245.7.401.CrossRefGoogle Scholar
Rutherford, M. J., 1973 The phase relations of aluminous iron biotites in the system KAlSi3O8-KAlSiO4-Al2O3-Fe-O-H J. Petrol. 14 159 – 180 10.1093/petrology/14.1.159.CrossRefGoogle Scholar
Shirozu, H. and Bailey, S. W., 1965 Chlorite polytypism: III. Crystal structure of an orthohexagonal iron chlorite Amer. Mineral. 50 868 – 885.Google Scholar
Smith, J. T. and Ehrenberg, S. N., 1989 Correlation of carbon dioxide abundance with temperature in clastic hydrocarbon reservoirs: Relationship to inorganic chemical equilibrium Mar. Pet. Geol. 6 129 – 135 10.1016/0264-8172(89)90016-0.CrossRefGoogle Scholar
Sourirajan, S. and Kennedy, G. C., 1962 The system H2O-NaCl at elevated temperatures and pressures Amer. J. Sci. 260 115 – 141 10.2475/ajs.260.2.115.CrossRefGoogle Scholar
Takenouchi, S. and Kennedy, G. C., 1965 The solubility of carbon dioxide in NaCl solutions at high temperatures and pressures Amer. J. Sci. 263 445 – 454 10.2475/ajs.263.5.445.CrossRefGoogle Scholar
Thompson, J. B. Jr., 1982 Composition space: an algebraic and geometric approach Characterization of Metamorphism Through Mineral Equilibria 10 1 – 31.Google Scholar
Velde, B. and Medhioub, M., 1988 Approach to chemical equilibrium in diagenetic chlorite Contrib. Mineral. Petrol. 98 122 – 127 10.1007/BF00371916.CrossRefGoogle Scholar
Velde, B., El Moutaouakkil, N. and Iijima, A., 1991 Compositional homogeneity in low-temperature chlorites Contrib. Mineral. Petrol. 107 21 – 26 10.1007/BF00311182.CrossRefGoogle Scholar
Walker, J. R., 1989 Polytypism of chlorite in very low grade metamorphic rocks Amer. Mineral. 74 738 – 743.Google Scholar
Walker, J. R. and Thompson, G. R., 1990 Structural variations in chlorite and illite in a diagenetic sequence from the Imperial Valley, California Clays & Clay Minerals 38 315 – 321 10.1346/CCMN.1990.0380311.CrossRefGoogle Scholar
Walshe, J. L., 1986 A six-component chlorite solid solution model and the conditions of chlorite formation in hydro-thermal and geothermal systems Econ. Geol. 81 681 – 703 10.2113/gsecongeo.81.3.681.CrossRefGoogle Scholar
Weaver, C. E., Highsmith, P. B., Wampler, J. M. and Weaver, C. E., 1984 Chlorite Shale-Slate Metamorphism in the Southern Appalachians 99 – 139 10.1016/B978-0-444-42264-4.50010-4.CrossRefGoogle Scholar
Whittle, C. K., 1986 Comparison of sedimentary chlorite compositions by X-ray diffraction and analytical TEM Clay Miner. 21 937 – 947 10.1180/claymin.1986.021.5.07.CrossRefGoogle Scholar
Wiewióra, A. and Weiss, Z., 1990 Crystallochemical classifications of phyllosilicates based on the unified system of projection of chemical composition: II. The chlorite group Clay Miner. 25 83 – 92 10.1180/claymin.1990.025.1.09.CrossRefGoogle Scholar
Zen, E.-A., 1959 Clay mineral-carbonate relations in sedimentary rocks Amer. J. Sci. 257 29 – 43 10.2475/ajs.257.1.29.CrossRefGoogle Scholar