Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-04T22:02:02.744Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterizing Clay Mineral Suspensions using Acoustic and Electroacoustic Spectroscopy — A Review

Published online by Cambridge University Press:  01 January 2024

Marianne Guerin  and
John C. Seaman
Marianne Guerin
Affiliation:
The University of Georgia, Savannah River Ecology Laboratory, Savannah River Site, Aiken, South Carolina 29802, USA
John C. Seaman*
Affiliation:
The University of Georgia, Savannah River Ecology Laboratory, Savannah River Site, Aiken, South Carolina 29802, USA
*
*E-mail address of corresponding author: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Recently, significant advances have been made in the theory and application of acoustic and electroacoustic spectroscopies for measuring the particle-size distribution (PSD) and zeta potential (ζ potential) of colloidal suspensions, respectively. These techniques extend or replace other techniques, such as light-scattering methods, particularly in concentrated suspensions. In this review, we summarize acoustic and electroacoustic theory and published results on clay mineral suspensions, detail theoretical constraints, and indicate potential applications for the study of environmentally significant clay mineral suspensions. Using commercially available instrumentation and suspension concentrations up to 45 vol.%, acoustic spectroscopy can characterize particle sizes from 10 nm to 10 µm, or greater. Electroacoustic spectroscopy can determine the ζ potential of a suspension with a precision and accuracy in the mV range. Despite the clear potential for their use in environmental settings, to date, acoustic methods have been used mainly on clay mineral colloids with industrial application, typically combined with similar measurements such as isoelectric point (IEP) determined from shear yield stress or ζ potential from electrophoretic mobility measurements. Potential applications in environmentally relevant suspension concentrations are significant, as PSD and ζ potential are important factors influencing the transport of mineral colloids and associated contaminants through porous media. Applications include determining the effects of suspension concentration, surfactants, electrolyte strength, pH and solution composition on soil clay properties and colloidal interactions, and determining changes in PSD, aggregation and ζ potential due to adsorption or variations in the clay mineralogy.

Keywords

AcousticsAggregationElectroacousticsElectrokineticsParticle-size DistributionPSDZeta Potential
Type
Research Article
Information
Clays and Clay Minerals , Volume 52 , Issue 2 , April 2004 , pp. 145 - 157
Copyright
Copyright © 2004, The Clay Minerals Society

References

Anderson, P.R. and Benjamin, M.M., (1990) Surface and bulk characteristics of binary oxide suspensions Environmental Science and Technology 24 692–698 10.1021/es00075a013.CrossRefGoogle Scholar
Babick, F. and Ripperger, S., (2002) Information content of acoustic spectra Particles and Particle System Characterization 19 176–185 10.1002/1521-4117(200207)19:3<176::AID-PPSC176>3.0.CO;2-8.3.0.CO;2-8>CrossRefGoogle Scholar
Babick, F. Hinze, F. and Ripperger, S., (2000) Dependence of ultrasonic attenuation on the material properties Colloids and Surfaces A: Physicochemical and Engineering Aspects 172 33–46 10.1016/S0927-7757(00)00571-9.CrossRefGoogle Scholar
Barrow, N.J., (1985) Reaction of anions and cations with variable-charge soils Advances in Agronomy New York Academic Press.Google Scholar
Barrow, N.J. and Shaw, T.C., (1979) Effects of solution-soil ratio and vigor of shaking on the rate of phosphate adsorption by soil Journal of Soil Science 30 67–76 10.1111/j.1365-2389.1979.tb00965.x.CrossRefGoogle Scholar
Bertsch, P. and Seaman, J., (1999) Characterization of complex mineral assemblages: Implications for contaminant transport and remediation Proceedings of the National Academies of Science, USA 96 3350–3357 10.1073/pnas.96.7.3350 March.CrossRefGoogle Scholar
Costa, A.L. Galassi, C. and Greenwood, R., (1999) Alpha-alumina-H2O interface analysis by electroacoustic measurements Journal of Colloid and Interface Science 212 350–356 10.1006/jcis.1998.6070.CrossRefGoogle ScholarPubMed
Dukhin, A.S. and Goetz, P.J., (1996) Acoustic and electro-acoustic spectroscopy Langmuir 12 4336–4344 10.1021/la951086q.CrossRefGoogle Scholar
Dukhin, A.S. and Goetz, P.J., (1996) Acoustic spectroscopy for concentrated polydisperse colloids with high density contrast Langmuir 12 4987–4997 10.1021/la951085y.CrossRefGoogle Scholar
Dukhin, A.S. and Goetz, P.J., (1998) Characterization of aggregation phenomena by means of acoustic and electro-acoustic spectroscopy Colloids and Surfaces 144 49–58 10.1016/S0927-7757(98)00565-2.CrossRefGoogle Scholar
Dukhin, A.S. and Goetz, P.J., (2000) Characterization of concentrated dispersions with several dispersed phases by means of acoustic spectroscopy Langmuir 16 7597–7604 10.1021/la991600i.CrossRefGoogle Scholar
Dukhin, A.S. and Goetz, P.J., (2001) Acoustic and electro-acoustic spectroscopy for characterizing concentrated dispersions and emulsions Advances in Colloid and Interface Science 92 73–132 10.1016/S0001-8686(00)00035-X.CrossRefGoogle Scholar
Dukhin, A.S. and Goetz, P.J., (2001) Installation Handbook and User Manual — Model DT-1200 Electroacoustic Spectrometer Bedford Hills, New York, USA Dispersion Technology.Google Scholar
Dukhin, A.S. and Goetz, P.J., (2002) Ultrasound for Characterizing Colloids Amsterdam Elsevier 372 pp.Google Scholar
Dukhin, A.S. Ohshima, H. Shilov, V.N. and Goetz, P.J., (1999) Electroacoustics for concentrated dispersions Langmuir 15 3445–3451 10.1021/la9813836.CrossRefGoogle Scholar
Dukhin, A.S. Shilov, V.N. Ohshima, H. and Goetz, P.J., (1999) Electroacoustic phenomena in concentrated dispersions: New theory and CVI experiment Langmuir 15 6692–6706 10.1021/la990317g.CrossRefGoogle Scholar
Dukhin, A.S. Goetz, P.J. and Truesdail, S., (2001) Titration of concentrated dispersions using electroacoustic potential probe Langmuir 17 964–968 10.1021/la001024m.CrossRefGoogle Scholar
Galassi, C. Costa, A.L. and Pozzi, P., (2001) Influence of ionic environment and pH on the electrokinetic properties of ball clays Clays and Clay Minerals 49 263–269 10.1346/CCMN.2001.0490309.CrossRefGoogle Scholar
Guerin, M. and Seaman, J.C., (2004) Acoustic and electro-acoustic characterization of variable-charge mineral suspensions Clays and Clay Minerals 52 158–170 10.1346/CCMN.2004.0520202.CrossRefGoogle Scholar
Hunter, R.J., (1981) Zeta Potential in Colloid Science New York Academic Press.Google Scholar
Hunter, R.J., (1998) Recent development in the electroacoustic characterization of colloidal suspensions and emulsions Colloids and Surfaces 141 37–65 10.1016/S0927-7757(98)00202-7.CrossRefGoogle Scholar
Hunter, R.J., (2001) Foundations of Colloid Science New York Oxford University Press.Google Scholar
Hunter, R.J. and James, M., (1992) Charge reversal of kaolinite by hydrolyzable metal ions: An electroacoustic study Clays and Clay Minerals 40 644–649 10.1346/CCMN.1992.0400603.CrossRefGoogle Scholar
Johnson, S.B. Russell, A.S. and Scales, P.J., (1998) Volume fraction effects in shear rheology and electroacoustic studies of concentrated alumina and kaolin suspensions Colloids and Surfaces 141 119–130 10.1016/S0927-7757(98)00208-8.CrossRefGoogle Scholar
Johnson, S.B. Dixon, D.R. and Scales, P.J., (1999) The electrokinetic and shear yield stress properties of kaolinite in the presence of aluminum ions Colloids and Surfaces 146 281–291 10.1016/S0927-7757(98)00726-2.CrossRefGoogle Scholar
Johnson, S.B. Scales, P.J. and Healy, T.W., (1999) The binding of monovalent electrolyte ions on alpha-alumina. 1. Electroacoustic studies at high electrolyte concentrations Langmuir 15 2836–2843 10.1021/la980875f.CrossRefGoogle Scholar
Lykelema, J., (1995) Fundamentals of Interface and Colloid Science: Volume II London Academic Press.Google Scholar
McCarthy, J.F. and Zachara, J.M., (1989) Mobile colloids in the subsurface environment may alter the transport of contaminants Environmental Science and Technology 23 496–502.Google Scholar
McClements, D.J., (1991) Ultrasonic characterization of emulsions and suspensions Advances in Colloid and Interface Science 37 33–72 10.1016/0001-8686(91)80038-L.CrossRefGoogle Scholar
O’Brien, R.W., (1995) The dynamic mobility of a porous particle Journal of Colloid and Interface Science 171 495–504 10.1006/jcis.1995.1208.CrossRefGoogle Scholar
O’Brien, R.W. and Rowlands, W.N., (1993) Measuring the surface conductance of kaolinite particles Journal of Colloid and Interface Science 159 471–476 10.1006/jcis.1993.1348.CrossRefGoogle Scholar
O’Brien, R.W. and White, L.R., (1978) Electrophoretic mobility of a spherical colloidal particle Journal of the Chemical Society 74 1607–1626.Google Scholar
O’Brien, R.W. Cannon, D.W. and Rowlands, W.N., (1995) Electroacoustic determination of particle size and zeta potential Journal of Colloid and Interface Science 173 406–418 10.1006/jcis.1995.1341.CrossRefGoogle Scholar
Ohshima, H., (1997) Electrophoretic mobility of spherical colloidal particles in concentrated suspensions Journal of Colloid and Interface Science 188 481–485 10.1006/jcis.1997.4790.CrossRefGoogle Scholar
Ohshima, H., (1998) Sedimentation potential in a concentrated suspension of spherical colloidal particles Journal of Colloid and Interface Science 208 295–301 10.1006/jcis.1998.5821.CrossRefGoogle Scholar
Ohshima, H. and Dukhin, A.S., (1999) Colloid vibration potential in a concentrated suspension of spherical colloidal particles Journal of Colloid and Interface Science 212 449–452 10.1006/jcis.1998.6059.CrossRefGoogle Scholar
Oja, T. and Alba, F., (1998) Acoustic Attenuation Spectroscopy for Particle Sizing of High Concentration Dispersions Westerville, Ohio, USA American Ceramic Society 205–215.Google Scholar
Rasmusson, M. and Wall, S., (1997) Electrostatic characterization of Al-modified, nanosized silica particles Colloids and Surfaces 122 169–181 10.1016/S0927-7757(96)03850-2.CrossRefGoogle Scholar
Rowlands, W.N. and Hunter, R.J., (1992) Electroacoustic study of adsorption of cetylpryidinium chloride on kaolinite Clays and Clay Minerals 40 287–291 10.1346/CCMN.1992.0400306.CrossRefGoogle Scholar
Rowlands, W.N. and O’Brien, R.W., (1995) The dynamic mobility and dielectric response of kaolinite particles Journal of Colloid and Interface Science 175 190–200 10.1006/jcis.1995.1445.CrossRefGoogle Scholar
Rowlands, W. O’Brien, R. Hunter, R. and Patrick, V., (1997) Surface properties of aluminum hydroxide at high salt concentrations Journal of Colloid and Interface Science 188 325–335 10.1006/jcis.1997.4762.CrossRefGoogle Scholar
Roy, W.R. Krapac, I. Chow, S.F.J. and Griffin, R.A., (1991) Batch-type Procedures for Estimating Soil Adsorption of Chemicals Champaign, Illinois, USA US Environmental Protection Agency EPA/530-SW-87-006-F.Google Scholar
Seaman, J.C. and Bertsch, P.M., (2000) Selective colloid mobilization through surface charge manipulation Environmental Science and Technology 34 3749–3755 10.1021/es001056w.CrossRefGoogle Scholar
Seaman, J.C. Bertsch, P.M. and Miller, W.P., (1995) Chemical controls on colloid generation and transport in a sandy aquifer Environmental Science and Technology 29 1808–1815 10.1021/es00007a018.CrossRefGoogle Scholar
Seaman, J.C. Bertsch, P.M. and Miller, W.P., (1995) Ionic tracer movement through highly weathered sediments Journal of Contaminant Hydrology 20 127–143 10.1016/0169-7722(95)00043-U.CrossRefGoogle Scholar
Stolojanu, V. and Prakash, A., (2001) Characterization of slurry systems by ultrasonic techniques Chemical Engineering Journal 84 215–222 10.1016/S1385-8947(00)00278-3.CrossRefGoogle Scholar
Strom, R.N. and Kaback, D.S. (1992) SRP Baseline Hydrogeologic Investigation: Aquifer Characterization Groundwater Geochemistry of the Savannah River Site and Vicinity (U). Westinghouse Savannah River Company, Environmental Sciences Section, 98 pp.CrossRefGoogle Scholar
Takeda, S. and Goetz, P.J., (1998) Dispersed/flocculated size characterization of alumina particles in highly concentrated slurries by ultrasonic attenuation spectroscopy Colloids and Surfaces A: Physicochemical and Engineering Aspects 143 35–39 10.1016/S0927-7757(98)00501-9.CrossRefGoogle Scholar