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Characterization of Organo-Bentonites Obtained from Different Linear-Chain Quaternary Alkylammmonium Salts

Published online by Cambridge University Press:  01 January 2024

Ïlker Erkan ,
Ïbrahim Alp  and
Mehmet SabrÏ Çelik
Ïlker Erkan
Affiliation:
Karadeniz Technical University, Department of Mining Engineering, Trabzon, Turkey
Ïbrahim Alp*
Affiliation:
Karadeniz Technical University, Department of Mining Engineering, Trabzon, Turkey
Mehmet SabrÏ Çelik
Affiliation:
İstanbul Technical University, Department of Mineral Processing Engineering, İstanbul, Turkey
*
* E-mail address of corresponding author: [email protected]
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Abstract

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The effects of surfactants on bentonites have been of great scientific interest for many years. Even though quaternary alkylammonium salts (QAS) have been studied, very few data are available on the comparative performance of different chain-length QAS for the modification of the surface properties and adsorption properties of bentonites. The objective of this study was to investigate the effect of chain length on the adsorption of cationic surfactants onto bentonite. The surface and adsorption properties of different chain-length QAS, i.e. hexadecyltrimethylammonium bromide (HTAB, C16), tetradecyltrimethylammonium bromide (TTAB, C14), and dodecyltrimethylammonium bromide (DTAB, C12), to produce organo- bentonites (OB) were studied. The concentrations of QAS were selected based on the cation exchange capacity (CEC) of the clay mineral. Zeta potential, swelling, and viscosity measurements and scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared (FTIR) analyses were used to explain the changes in surface properties. The results indicated that the best modification of bentonite was obtained using a 16-carbon chain length QAS (HTAB) in a 1:1 ratio of QAS to CEC. The basal spacing at this concentration was measured to be 22.19 Å, which also corresponded to the maximum adsorption density. The OB produced at this concentration showed the best hydrophobic character based on the swelling tests in toluene. The extent of hydrophobicity and adsorption density was correlated with the CEC and alkyl chain of the QAS. All these properties were used to elucidate the mechanism of modification governing the bentonite/QAS system.

Keywords

AdsorptionCation Exchange Capacity (CEC)Chain-lengthElectrokineticsOrgano BentoniteRheology
Type
Article
Information
Clays and Clay Minerals , Volume 58 , Issue 6 , December 2010 , pp. 792 - 802
Copyright
Copyright © Clay Minerals Society 2010

References

Akin, Y., Çelik, M.S., Kose, H., and Kizil, M.S., 1995 Electrokinetic behavior of montmorillonite type clays Proceedings of the Industrial Raw Materials Symposium 95 izmir, Turkey The Chamber of Mining Engineers of Turkey 135–142 (in Turkish).Google Scholar
Baldassari, S., Komarneni, S., Mariani, E., and Villa, C., 2006 Microwave versus conventional preparation of organoclays from natural and synthetic clays Applied Clay Science 31 134–141 10.1016/j.clay.2005.09.005.CrossRefGoogle Scholar
Boylu, F., Cinku, K., Cetinel, T., Erkan, I., Demirer, N., Ku§cu, M., Cengiz, O., and Çener, E., 2007 The separation efficiency of Re§adiye Na+ bentonite by hydrocyclone Proceedings of the 13th National Clay Symposium Van, Turkey Turkish National Committee on Clay Science 213–227 (in Turkish).Google Scholar
Can, F., Erkan, I., Yildiz, E., Celik, M.S., Ku§cu, M., Cengiz, O., and Çener, E., 2007 Organoclay preparation and characterization from Na+ bentonites modified with cetyl pyridinium chloride (CPC) monohydrate Proceedings of the 13th National Clay Symposium Van, Turkey Turkish National Committee on Clay Science 365–377 (in Turkish).Google Scholar
Erkan, I., 2008 Amine modification of Re§adiye bentonite and preparation of epoxy based nanocomposite (in Turkish) Trabzon, Turkey MSc thesis, Karadeniz Technical University.Google Scholar
Erkan, I., Alp, I., Can, F.C., Karaka§, F., Celik, M.S., Yüzer, H., Ozbayoğlu, G., Arol, A., Hoşten, , and Atalay, , 2008 Adsorption, rheology and electrokinetic properties of organo modified sodium bentonites from Re§adiye region Proceedings of the 11th International Mineral Processing Symposium Antalya, Turkey Turkish Mining Development Foundation 743–748.Google Scholar
Ersoy, B., and Celik, M.S., 2003 Effect of hydrocarbon chain length on adsorption of cationic surfactants onto clinoptilolite Clays and Clay Minerals 51 173–181 10.1346/CCMN.2003.0510207.CrossRefGoogle Scholar
Faci, H., 2001 Open gear lubricants US Patent 6251839 .Google Scholar
Favre, H., and Lagaly, G., 1991 Organo-bentonites with quaternary alkylammonium ions Clay Minerals 26 19–32 10.1180/claymin.1991.026.1.03.CrossRefGoogle Scholar
Forland, G.M., and Blokhus, A.M., 2007 Adsorption of phenol and benzyl alcohol onto surfactant modied silica Journal of Colloid and Interface Science 310 431–435 10.1016/j.jcis.2007.02.016.CrossRefGoogle Scholar
Frost, R., Xi, Y., and He, H., 2007 Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyl trimethyl, dialkyl dimethyl and trialkyl methyl ammonium bromides Journal of Colloid and Interface Science 305 150–158 10.1016/j.jcis.2006.09.033.Google Scholar
Gorassi, G., Tortora, M., Vittoria, V., Kaempfer, D., and Miilhaupt, R., 2003 Transport properties of organic vapor in nanocomposites of organophilic layered silicate and syndiotactic polypropylene Polymer 44 3679–3685 10.1016/S0032-3861(03)00284-2.CrossRefGoogle Scholar
Ïşçι, S., Ece, O.I., and Giingor, N., 2006 Characterization of rheology, electrokinetic properties, and surface micromorphology of DTABr-MMT and CPBr-MMT organoclays Journal of Composite Materials 40 1105–1115 10.1177/0021998305057369.CrossRefGoogle Scholar
Kirsner, J., Miller, J., and Bracken, J., 2003 Additive for oil- based drilling fluids US Patent 6620770 .Google Scholar
Klapyta, Z., Fujita, T., and Iyi, N., 2001 Adsorption of dodecyl- and octadecyltrimethylammonium ions on a smectite and synthetic micas Applied Clay Science 19 5–10 10.1016/S0169-1317(01)00059-X.CrossRefGoogle Scholar
Klapyta, Z., Gawel, A., Fujita, T., and Iyi, N., 2003 Structural heterogeneity of alkylammonium-exchanged, synthetic fluorotetrasilicic mica Clay Minerals 38 151–160 10.1180/0009855033820085.CrossRefGoogle Scholar
Lagaly, G., 1986 Interaction of alkylamines with different types of layered compounds Solid State Ionics 22 43–51 10.1016/0167-2738(86)90057-3.CrossRefGoogle Scholar
Lagaly, G., Ogawa, M., Dekany, I., Bergaya, F., Theng, B.K.G., and Lagaly, G., 2006 Clay Mineral Organic Interactions Handbook of Clay Science, Developments in Clay Science, Vol.1 Amsterdam Elsevier 309–377.Google Scholar
Lan, T., and Pinnavaia, T.J., 1994 Clay-reinforced epoxy nanocomposites Chemistry of Materials 6 2216–2219 10.1021/cm00048a006.CrossRefGoogle Scholar
Lee, J.F., Crum, J.R., and Boyd, S.A., 1989 Enhanced retention of organic contaminants by soils exchanged with organic cations Environmental Science and Technology 23 1365–1372 10.1021/es00069a006.CrossRefGoogle Scholar
Liu, W., Hoa, S.V., and Pugh, M., 2005 Organoclay-modied high performance epoxy nanocomposites Composites Science and Technology 65 307–316 10.1016/j.compscitech.2004.07.012.CrossRefGoogle Scholar
Marras, S.I., Tsimpliaraki, A., Zuburtikudis, I., and Panayiotou, C., 2007 Thermal and colloidal behavior of amine-treated clays: The role of amphiphilic organic cation concentration Journal of Colloid and Interface Science 315 520–527 10.1016/j.jcis.2007.06.023.CrossRefGoogle ScholarPubMed
Medrzycka, K., and Zwierzykowski, W., 2000 Adsorption of alkyltrimethylammonium bromides at the various interfaces Journal of Colloid and Interface Science 230 67–72 10.1006/jcis.2000.7045.CrossRefGoogle ScholarPubMed
Mohammad, A., and Bhawani, S.A., 2008 LC separation of coexisting cetylpyridinium chloride, tetradecyltrimethylammonium bromide and dodecyltrimethylammonium bromide on silica TLC plates with aqueous-organic eluents Chromatographia 67 659–663 10.1365/s10337-008-0552-3.CrossRefGoogle Scholar
Nuntiya, A., Sompech, S., Aukkaravittayapun, S., and Pumchusak, J., 2008 The effect of surfactant concentration on the interlayer structure of organoclay Chiang Mai Journal of Science 35 199–205.Google Scholar
Paiva, L.B., Morales, A.R., and Diaz, F.R.V., 2008 Organoclays: properties, preparation and applications Applied Clay Science 42 8–24 10.1016/j.clay.2008.02.006.CrossRefGoogle Scholar
Patel, H.A., Somani, R.S., Bajaj, H.C., and Jasra, R.V., 2006 Nanoclays for polymer nanocomposites, paints, inks, greases and cosmetics formulations, drug delivery vehicle and waste water treatment Bulletin of Materials Science 29 133–145 10.1007/BF02704606.CrossRefGoogle Scholar
Reid, V.W., Longman, G.F., and Heinerth, E., 1967 Determination of anionic active detergents by two phase titration Tenside Surfactants Detergents 4 292–304.CrossRefGoogle Scholar
Sabah, E., Kara, M., Hancer, M., and Celik, M.S., 1998 Adsorption mechanism of organic and inorganic ions by a clay absorbent: sepiolite, Preprint No. 98–152 SME Annual Meeting .Google Scholar
Sabah, E., Mart, U., Cinar, M., and Celik, M.S., 2007 Zeta potentials of sepiolite suspensions in concentrated monovalent electrolytes Separation Science and Technology 42 2275–2288 10.1080/15275920701313616.CrossRefGoogle Scholar
Smith, J.A., Jaffe, P.R., and Chlou, C.T., 1990 Effect of ten quaternary ammonium cations on tetrachloromethane sorption to clay from water Environmental Science and Technology 24 1167–1172 10.1021/es00078a003.CrossRefGoogle Scholar
Somasundaran, P., Healy, T.W., and Fuerstenau, D.W., 1964 Surfactant adsorption at the solid-liquid interface-dependence of mechanism on chain length The Journal of Physical Chemistry 68 3562–3566 10.1021/j100794a021.CrossRefGoogle Scholar
Sompech, S., Nuntiya, A., Aukkaravittayapun, S., and Pumchusak, J., 2008 Interlayer expansion of organoclay by cationic surfactant Chiang Mai University Journal of Natural Science Special Issue on Nanotechnology 7 89–93.Google Scholar
Tjandra, W., Yao, J., and Tam, K.C., 2006 Interaction between silicates and ionic surfactants in dilute solution Langmuir 22 1493–1499 10.1021/la0521185.CrossRefGoogle ScholarPubMed
Vazquez, A., Lopez, M., Kortaberria, G., Martin, L., and Mondragon, I., 2008 Modification of montmorillonite with cationic surfactants. Thermal and chemical analysis including CEC determination Applied Clay Science 41 24–36 10.1016/j.clay.2007.10.001.CrossRefGoogle Scholar
Vougaris, D., and Petridis, D., 2002 Emulsifying effect of dimethyldioctadecylammonium-hectorite in polystyrene/ poly(ethyl methacrylate) blends Polymer 43 2213–2218 10.1016/S0032-3861(02)00039-3.CrossRefGoogle Scholar
Xi, Y., Martens, X., He, H., and Frost, R.L., 2005 Thermogravimetric analysis of organoclays intercalated with the surfactant octadecyltrimethylammonium bromide Journal of Thermal Analysis and Calorimetry 81 91–97 10.1007/s10973-005-0750-2.CrossRefGoogle Scholar
Xie, W., Gao, Z., Liu, K., Pan, W.-P., Vaia, R., Hunter, D., and Singh, A., 2001 Thermal characterization of organically modified montmorillonite Thermochimica Acta 367–368.CrossRefGoogle Scholar
Yang, L., Jiang, L., Zhou, Z., Chen, Y., and Wang, X., 2002 The sedimentation capabilities of hexadecyltrimethylammonium-modied montmorillonites Chemosphere 48 461–466 10.1016/S0045-6535(02)00072-3.CrossRefGoogle ScholarPubMed
Yilmaz, N., and Yapar, S., 2004 Adsorption properties of tetradecyl- and hexadecyl trimethylammonium bentonites Applied Clay Science 27 223–228 10.1016/j.clay.2004.08.001.CrossRefGoogle Scholar
Zhu, L., Li, Y., and Zhang, J., 1997 Sorption of organobentonites to some organic pollutants in water Environmental Science and Technology 31 1407–1410 10.1021/es960641n.CrossRefGoogle Scholar
Zhu, L., Zhu, R., Xu, L., and Ruan, X., 2007 Influence of clay charge densities and surfactant loading amount on the microstructure of CTMA-montmorillonite hybrids Colloids and Surfaces A: Physicochemical and Engineering Aspects 304 41–48 10.1016/j.colsurfa.2007.04.019.CrossRefGoogle Scholar