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Authigenic Illite and Organic Matter: The Principal Hosts of Vanadium in the Mecca Quarry Shale at Velpen, Indiana

Published online by Cambridge University Press:  28 February 2024

Donald R. Peacor ,
Raymond M. Coveney Jr.  and
Gengmei Zhao
Donald R. Peacor*
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109, USA
Raymond M. Coveney Jr.
Affiliation:
Department of Geosciences, University of Missouri, Kansas City, Missouri 64110-2499, USA
Gengmei Zhao
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109, USA
*
E-mail of corresponding author: [email protected]
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Abstract

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The Mecca Quarry Shale Member from Velpen, Indiana contains abundant vanadium which occurs in solid solution within illite-rich illite-smectite (I-S) having an average content of 1.65 wt. % V, and an overall composition of K0.8(Al2.8Mg0.5Fe0.4V0.3)(Si7.2Al0.8 g)O20(OH)4, analogous to the V-rich dioctahedral mica, roscoelite. The illite contains more than twice as much V as the associated kerogen. Detrital mica has a composition typical of 2M1, muscovite and contains no vanadium. The V-rich illite has a structure and composition typical of formation during normal prograde diagenesis and probably is widespread in the Mecca Quarry Shale because the bed is enriched in V throughout the Midwest. The smectite-to-illite reaction can not be a result of passive burial metamorphism because the host strata were buried no deeper than ~0.5 km at Velpen. The formation of illite occurred in unlithified sediments at shallow depths under the influence of pervasive 80–110°C basinal brines, possibly the same fluids that were responsible for the Mississippi Valley-type lead-zinc mineralization common in the Midwest. The presence of two types of K-rich phyllosilicates may be part of the reason for the lack of correlation between bulk V concentrations and the intensities of X-ray diffraction peaks of illite reported by others.

Keywords

Black ShaleIlliteMecca QuarryOrganic MatterVanadium
Type
Research Article
Information
Clays and Clay Minerals , Volume 48 , Issue 3 , June 2000 , pp. 311 - 316
Copyright
Copyright © 2000, The Clay Minerals Society

References

Breit, G.N. and Wanty, R.B., 1991 Vanadium accumulation in carbonaceous rocks: A review of geochemical controls during deposition and diagenesis Chemical Geology 91 83–97 10.1016/0009-2541(91)90083-4.CrossRefGoogle Scholar
Breit, G.N., Wanty, R.B. and Turtle, M.L. (1989) Geochemical Control on the Abundance of Vanadium in Black Shales and Other Carbonaceous Rocks, Grauch, R.I. and Huyck, H.L.O., eds. U.S. Geological Survey Circular 1058, Washington, D.C., 6–8.Google Scholar
Collinson, C. Sargent, M.L. Jennings, J.R. and Sloss, L.L., 1988 The Illinois Basin region in Phanerozoic time The Geology of North America, Volume D-2 Boulder, Colorado Geological Society of America 383–426.Google Scholar
Coveney, R.M. Jr. and Glascock, M.D., 1989 A review of the origins of metal-rich Pennsylvanian black shales, central U.S.A., with an inferred role for basinal brines Applied Geochemistry 4 347–367 10.1016/0883-2927(89)90012-7.CrossRefGoogle Scholar
Coveney, R.M. Jr. and Martin, S.P., 1983 Molybdenum and other heavy metals of the Mecca Quarry and Logan Quarry shales Economic Geology 78 132–149 10.2113/gsecongeo.78.1.132.CrossRefGoogle Scholar
Coveney, RM L JS Jr. Glascock, M.D. and Hatch, J.R., 1987 Origins of metals and organic matter in the Mecca Quarry Shale Member and stratigraphically equivalent beds across the Midwest Economic Geology 82 915–933 10.2113/gsecongeo.82.4.915.CrossRefGoogle Scholar
Coveney, R.M. Jr. Goebel, E.D. and Ragan, V.M., 1987 Pressures and temperatures from aqueous fluid inclusions in sphalerite from midwestern country rocks Economic Geology 82 740–751 10.2113/gsecongeo.82.3.740.CrossRefGoogle Scholar
Desborough, G.A., Hatch, J.R. and Leventhal, J.S. (1989) Geochemical Comparison of the Upper Pennsylvanian Stark Shale Member of the Dennis Limestone, East Central Kansas, with the Middle Pennsylvanian Mecca Quarry Shale Member of the Carbondale Formation Illinois and of the Linton Formation in Indiana, Grauch, R.I. and Huyck, H.L.O., eds., U.S. Geological Survey Circular 1058, Washington, D.C., 12–30.Google Scholar
Dong, H. and Peacor, D.R., 1996 TEM observations of coherent stacking relations in smectite, I/S and illite of shales: Evidence for McEwan crystallites and dominance of 2M1 polytypism Clays and Clay Minerals 44 257–275 10.1346/CCMN.1996.0440211.CrossRefGoogle Scholar
Erickson, R.L. Mosier, E.L. Odland, S.K. and Erickson, M.L., 1981 A favorable belt for possible mineral discovery in subsurface Cambrian rocks in southern Missouri Economic Geology 76 921–933 10.2113/gsecongeo.76.4.921.CrossRefGoogle Scholar
Gaines, R.V. Skinner, H.C.W. Foord, E.E. Mason, B. Rosenzweig, A. King, V.T. and Dowty, E., 1997 Dana’s New Mineralogy New York John Wiley & Sons, Inc..Google Scholar
Hatch, J.R. Gluskoter, H. J. and Lindahl, P.C., 1976 Sphalerite in coals from the Illinois Basin Economic Geology 71 613–624 10.2113/gsecongeo.71.3.613.CrossRefGoogle Scholar
Heckel, P.H., 1977 Origin of phosphatic black shale facies in Pennsylvanian cyclothems of midcontinent North America Bulletin of the American Association of Petroleum Geologists 61 1045–1068.Google Scholar
Heiz, G.R. Miller, C.V. Charnock, J.M. Mosselmans, J.F.W. Patrick, R.A.D. Garner, D. and Vaughan, D.J., 1996 Mechanism of molybdenum removal from the sea and its concentration in black shales: EXAFS evidence Geochimica et Cosmochimica Acta 60 3631–3642 10.1016/0016-7037(96)00195-0.Google Scholar
Holland, H.D., 1979 Metals in black shales: A reassessment Economic Geology 74 1676–1680 10.2113/gsecongeo.74.7.1676.CrossRefGoogle Scholar
Kim, J.-W. Peacor, D.R. Tessier, D. and Elsass, F.A., 1995 Technique for maintaining texture and permanent expansion of smectite interlayers for TEM observations Clays and Clay Minerals 43 51–57 10.1346/CCMN.1995.0430106.CrossRefGoogle Scholar
Merriman, R.J. Peacor, D.R., Frey, M. and Robinson, D., 1999 Very low grade me-tapelites: Mineralogy, microfabrics and measuring reaction progress Low-Grade Metamorphism Oxford Blackwell Science Ltd. 10–60.Google Scholar
Meunier, J.D., 1994 The composition and origin of vanadium-rich clay minerals in Colorado Plateau Jurassic sandstones Clay Minerals 42 391–401 10.1346/CCMN.1994.0420403.CrossRefGoogle Scholar
Ohr, M. Halliday, A.N. and Peacor, D.R., 1991 Sr and Nd isotopic evidence for punctuated clay diagenesis, Texas Gulf Coast Earth and Planetary Science Letters 105 110–126 10.1016/0012-821X(91)90124-Z.CrossRefGoogle Scholar
Piper, D.J.W., 1994 Sea water as a source of minor elements for black shales, phosphorites, and other sediments—A review Chemical Geology 114 295–314 10.1016/0009-2541(94)90044-2.CrossRefGoogle Scholar
Ripley, E.M. Shaffer, N.R. and Gilstrap, M.S., 1990 Distribution and geochemical characteristics of metal enrichment in the New Albany Shale (Devonian-Mississippian), Indiana Economic Geology 85 1790–1807 10.2113/gsecongeo.85.8.1790.CrossRefGoogle Scholar
Saunders, J.A. and Savrda, C.E., 1993 Geochemistry of the Athens Shale: Implications of the genesis of Mississippi Valley-type deposits of the southernmost Appalachians Southeastern Geology .Google Scholar
Sloss, L.L. and Sloss, L.L., 1988 Tectonic evolution of the craton in Phan-erozoic time The Geology of North America, Volume D-2 Boulder, Colorado Geological Society of America 25–51.Google Scholar
Vine, J.D. and Tourtelot, E.B., 1970 Geochemistry of black shale deposits—A summary report Economic Geology 65 253–272 10.2113/gsecongeo.65.3.253.CrossRefGoogle Scholar
Zangerl, R. and Richardson, E.S., 1963 The paleoecological history of two Pennsylvanian black shales Fieldiana Geology Memoir 4 Chicago, Illinois Chicago Natural History Museum.Google Scholar
Zhang, A.Y. Wu, D.M. Guo, L.N. and Wang, Y.L., 1987 The Geochemistry of Marine Black Shale Formation and its Metallogenic Significance Beijing Scientific Publishing House.Google Scholar
Zhao, G. Peacor, D.R. and McDowell, S.D., 1999 “Retrograde Diagenesis” of clay minerals of the Freda Sandstone, Wisconsin Clays and Clay Minerals 47 119–130 10.1346/CCMN.1999.0470202.Google Scholar