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Anauxite and Kaolinite Structures Identical

Published online by Cambridge University Press:  01 July 2024

S. W. Bailey
Affiliation:
Department of Geology and Geophysics, University of Wisconsin, Madison, Wisc. 53706
R. B. Langston
Affiliation:
Department of Materials Science and Engineering, University of California, Berkeley, Calif. 94720

Abstract

Single crystal X-ray diffraction patterns reveal that the structure of selected anauxite crystals is the same as the structure of macroscopic kaolinite crystals. Anauxite and kaolinite crystals are intergrowths on a domain scale of units in pseudotwin orientations. Individual domains in anauxite have the triclinic geometry of kaolinite, and give X-ray reflections that compare closely in intensity with those calculated from the atomic parameters of kaolinite. Large crushed crystals of anauxite give powder patterns identical with that of kaolinite. Because it has been shown recently that the chemical composition of anauxite is also identical with that of kaolinite, it is recommended that the term “anauxite” no longer be used.

Резюме

Резюме

Картины монокристальной рентгеновской съемки показывают, что кристаллы аноксита, выделенные из его агрегатов, имеют ту же структуру, что и макроскопические кристаллы каолинита. Кристаллы аноксита и каолинита представляют сростки в доменной области, индивиды которых находятся в псевдодвойниковой ориентировке. Отдельные домены в аноксите имеют триклинную геометрию каолинита и дают рефлексы на рентгенограммах, которые по интенсивности сравнимы с вычисленными по атомным параметрам каолинита. Крупные дробленные кристаллы аноксита дают порошкограммы, аналогичные порошкограммам каолинита. Так как недавно было доказано, что аноксит и по химическому составу аналогичен каолиниту, то рекомендуется название “ансхоит” впредь не употреблять.

Type
Research Article
Copyright
Copyright © 1969, The Clay Minerals Society

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References

Allen, V. T. (1928) Anauxite from the lone Formation of California: Am. Mineralogist 13, 145152.Google Scholar
Allen, Victor T., Fahey Joseph, J. and Ross, Malcolm (1969) Kaolinite and anauxite in the Ione Formation, California: Am. Mineralogist 54, 206211.Google Scholar
Brindley, G. W. (1961) Kaolin, serpentine, and kindred minerals: The X-Ray Identification and Crystal Structures of Clay Minerals (Edited by Brown, G.), Chap. 2, Mineral Soc. (London), 51131.Google Scholar
Brindley, G. W. and Nakahira, M. (1958) Further considerations of the structure of kaolinite: Mineral. Mag. 31, 781786.Google Scholar
Drits, V. A. and Kashaev, A. A. (1960) An X-ray study of a single crystal of kaolinite: Soviet Phys.-Cryst. (English Transi.) 5, 207210.Google Scholar
Gruner, J. W., (1932) The crystal structure of kaolinite: Z. Krist. 83, 7588.Google Scholar
Hendricks, S. V. (1929) X-ray diffraction from crystalline aggregates: Z. Krist. 71, 269273.Google Scholar
Hendricks, S. B. (1936) Concerning the crystal structure of kaolinite and the composition of anauxite: Z. Krist. 95, 247252.Google Scholar
Hendricks, S. B. (1942) Lattice structure of clay minerals and some properties of clays: J. Geol. 50, 276290.CrossRefGoogle Scholar
Langston, R. V. and Pask, J. A. (1968) The nature of anauxite: Clays and Clay Minerals 16, 425436.CrossRefGoogle Scholar
Mansfield, C. F. and Bailey, S. W., Pseudotwin inter-growths in kaolinite: (to be published).Google Scholar
Ross, C. S. and Foshag, W. G. (1928) Anauxite, a mineral species, based on material from Bilin, Czechoslovakia: Am. Mineralogist 13, 153155.Google Scholar
Ross, C. S. and Kerr, P. F. (1930) The kaolin minerals: U.S. Geol. Surv. Prof. Paper 165 E.Google Scholar