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Evaluation of Claytone-ER as a novel rheological additive for enhancing oil-based drilling fluid performance under high-pressure high-temperature conditions

Published online by Cambridge University Press:  13 January 2025

Ali Mahmoud
Affiliation:
Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia
Rahul Gajbhiye*
Affiliation:
Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia
Salaheldin Elkatatny
Affiliation:
Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia
*
Corresponding author: Rahul Gajbhiye; Email: [email protected]

Abstract

Conventional oil drilling fluids often fail under extreme (high-pressure high-temperature, HPHT) conditions, leading to wellbore instability and formation damage, causing substantial economic losses in the drilling industry. The objective of this study was to evaluate the performance of Claytone-ER, a novel rheological additive for oil-based drilling fluids (OBDF), compared with a conventional organoclay (OC). Claytone-ER improved the drilling fluid performance significantly, including enhancement of the emulsion stability by 3% (863 V to 891 V), mitigation of sagging behavior, and substantial improvement in key rheological parameters such as plastic viscosity (PV) by 26.5%, yield point (YP) by 98%, and apparent viscosity (AV) by 36.5%. Additionally, Claytone-ER enhanced gel strength (GS) and improved filtration properties, reducing filtrate volume by 8% (5.0 cm3 to 4.6 cm3) and filter cake thickness by 6% (2.60 mm to 2.45 mm). These results demonstrated the potential of Claytone-ER to enhance the stability and performance of OBDFs under extreme HPHT conditions, leading to improved drilling efficiency, reduced non-productive time, and cost savings for drilling operations. Furthermore, the enhanced rheological properties, sag resistance, and filtration control contribute to better wellbore stability and minimize the risk of formation damage, ensuring long-term well productivity. This study represents a significant advancement in drilling fluid technology, paving the way for safer and more efficient drilling operations in challenging HPHT environments. Future research will focus on field trials to validate the efficacy of Claytone-ER in real-world HPHT drilling scenarios.

Type
Original Paper
Copyright
© The Author(s), 2025. Published by Cambridge University Press on behalf of The Clay Minerals Society

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References

Agarwal, S., Phuoc, T.X., Soong, Y., Martello, D., & Gupta, R.K. (2013). Nanoparticle-stabilised invert emulsion drilling fluids for deep-hole drilling of oil and gas. Canadian Journal of Chemical Engineering, 91, 16411649.CrossRefGoogle Scholar
Akkal, R., Cohaut, N., Khodja, M., Ahmed-Zaid, T., & Bergaya, F. (2013). Rheo-SAXS investigation of organoclay water in oil emulsions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 436, 751762.CrossRefGoogle Scholar
AlAbdullatif, Z., Al-Yami, A., Wagle, V., Bubshait, A., & Al-Safran, A. (2014). Development of New Kill Fluids with Minimum Sagging Problems for High Pressure Jilh Formation in Saudi Arabia. OnePetro.CrossRefGoogle Scholar
Aldea, C., Growcock, F.B., Lee, L.J., Friedheim, J.E., Oort, E. Van. (2001). Prevention of Dynamic Sag in Deepwater Invert Emulsion Fluids. AADE Paper Presented at AADE 2001 National Drilling Conference, “Drilling Technology.” AADE Natl. Drill. Conf. Houston, Texas, 110.Google Scholar
Ali, M., Jarni, H.H., Aftab, A., Ismail, A.R., Saady, N.M.C., Sahito, M.F., Keshavarz, A., Iglauer, S., & Sarmadivaleh, M. (2020). Nanomaterial-based drilling fluids for exploitation of unconventional reservoirs: a review. Energies, 13, 3417.CrossRefGoogle Scholar
Amani, M., Al-Jubouri, M., & Shadravan, A. (2012). Comparative study of using oil-based mud versus water-based mud in HPHT fields. Advances in Petroleum Exploration and Development, 4, 1827.Google Scholar
Amighi, M.R., & Shahbazi, K. (2010). Effective Ways to Avoid Barite Sag and Technologies to Predict Sag in HPHT and Deviated Wells. OnePetro.CrossRefGoogle Scholar
Bergane, C., & Hammadi, L. (2020). Impact of organophilic clay on rheological properties of gasoil-based drilling muds. Journal of Petroleum Exploration and Production Technology, 10, 35333540. Springer.CrossRefGoogle Scholar
Borges, R.F.O., De Souza, R.S.V.A., Vargas, M.L.V., Scheid, C.M., Calçada, L.A., & Meleiro, L.A.C. (2022). Analysis of the stability of oil-based drilling muds by electrical stability measurements as a function of oil-water ratio, weighting material and lubricant concentrations. Journal of Petroleum Science and Engineering, 218, 110924.CrossRefGoogle Scholar
Brigatti, M.F., Galán, E., & Theng, B.K.G. (2013). Chapter 2 – Structure and Mineralogy of Clay Minerals. In Developments in Clay Science (ed. Bergaya, F. and Lagaly, G.), pp. 2181. Elsevier.Google Scholar
Bui, B., Saasen, A., Maxey, J., Ozbayoglu, M.E., Miska, S.Z., Yu, M., & Takach, N.E. (2012). Viscoelastic properties of oil-based drilling fluids. Annual Transactions of the Nordic Rheology Society, 20, 3347.Google Scholar
Caenn, R., & Chillingar, G.V. (1996). Drilling fluids: state of the art. Journal of Petroleum Science and Engineering, 14, 221230.CrossRefGoogle Scholar
Caenn, R., Darley, H.C.H., & Gray, G.R. (2011). Composition and Properties of Drilling and Completion Fluids, 721 pp. Gulf Professional Publishing.Google Scholar
de Brito Buriti, B.M.A., Barsosa, M.E., da Silva Buriti, J., de Melo Cartaxo, J., Ferreira, H.S., & de Araújo Neves, G. (2022). Modification of palygorskite with cationic and nonionic surfactants for use in oil-based drilling fluids. Journal of Thermal Analysis and Calorimetry, 147, 29352945.CrossRefGoogle Scholar
de Paiva, L.B., Morales, A.R., & Valenzuela Díaz, F.R. (2008). Organoclays: properties, preparation and applications. Applied Clay Science, 42, 824.CrossRefGoogle Scholar
Ettehadi, A., Ülker, C., Altun, G. (2022). Nonlinear Viscoelastic Rheological Behavior of Bentonite and Sepiolite Drilling Fluids under Large Amplitude Oscillatory Shear. J. Pet. Sci. Eng., 208, 109210. https://doi.org/10.1016/J.PETROL.2021.109210.CrossRefGoogle Scholar
Fakoya, M.F., & Ahmed, R.M. (2018). A generalized model for apparent viscosity of oil-based muds. Journal of Petroleum Science and Engineering, 165, 777785.CrossRefGoogle Scholar
Geng, T., Qiu, Z., Zhao, C., Zhang, L., & Zhao, X. (2019). Rheological study on the invert emulsion fluids with organoclay at high aged temperatures. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 573, 211221.CrossRefGoogle Scholar
Ghavami, M., Hasanzadeh, B., Zhao, Q., Javadi, S., & Kebria, D.Y. (2018). Experimental study on microstructure and rheological behavior of organobentonite/oil-based drilling fluid. Journal of Molecular Liquids, 263, 147157.CrossRefGoogle Scholar
Growcock, F.B., Ellis, C.F., & Schmidt, D.D. (1994). Electrical stability, emulsion stability, and wettability of invert oil-based muds. SPE Drilling & Completion, 9, 3946.CrossRefGoogle Scholar
Guégan, R. (2019). Organoclay applications and limits in the environment. Comptes Rendus Chimie, 22, 132141.CrossRefGoogle Scholar
Hermoso, J., Martinez-Boza, F., & Gallegos, C. (2014). Influence of viscosity modifier nature and concentration on the viscous flow behaviour of oil-based drilling fluids at high pressure. Applied Clay Science, 87, 1421.CrossRefGoogle Scholar
Hermoso, J., Martinez-Boza, F., & Gallegos, C. (2015). Influence of aqueous phase volume fraction, organoclay concentration and pressure on invert-emulsion oil muds rheology. Journal of Industrial and Engineering Chemistry, 22, 341349.CrossRefGoogle Scholar
Jaber, M., & Miehé-Brendlé, J. (2008). Synthesis, characterization and applications of 2:1 phyllosilicates and organophyllosilicates: contribution of fluoride to study the octahedral sheet. Microporous and Mesoporous Materials, 107, 121127.CrossRefGoogle Scholar
Jordan, J.W. (1961). Organophilic clay-base thickeners. Clays and Clay Minerals, 10, 299308.Google Scholar
Karakosta, K., Mitropoulos, A.C., & Kyzas, G.Z. (2021). A review in nanopolymers for drilling fluids applications. Journal of Molecular Structure, 1227, 129702.CrossRefGoogle Scholar
Liu, D., Zhang, H., Li, Y., Li, C., Chen, X., Yang, F., Sun, G., & Zhao, Y. (2021). Co-adsorption behavior of asphaltenes and carboxylic acids with different alkyl chain lengths and its effects on the stability of water/model oil emulsion. Fuel, 295, 120603.CrossRefGoogle Scholar
Magalhães, S.C., Calçada, L.A., Scheid, C.M., Almeida, H., & Waldmann, A.T.A. (2016). Improving drilling performance with continuous online measurements of electrical stability and conductivity in oil based drilling fluids. Journal of Petroleum Science and Engineering, 146, 369379.CrossRefGoogle Scholar
Mahmoud, A., Gajbhiye, R., & Elkatatny, S. (2023). Application of organoclays in oil-based drilling fluids: a review. ACS Omega, 8, 2984729858. American Chemical Society.CrossRefGoogle ScholarPubMed
Mahmoud, A., Gajbhiye, R., & Elkatatny, S. (2024a). Evaluating the effect of Claytone-EM on the performance of oil-based drilling fluids. ACS Omega. American Chemical Society.CrossRefGoogle Scholar
Mahmoud, A., Gajbhiye, R., & Elkatatny, S. (2024b). Investigating the efficacy of novel organoclay as a rheological additive for enhancing the performance of oil-based drilling fluids. Scientific Reports, 14, 5323.CrossRefGoogle ScholarPubMed
Maxey, J. (2007). Rheological analysis of static and dynamic sag in drilling fluids. Annual Transactions of the Nordic Rheology Society, 15, 181.Google Scholar
Msadok, I., Hamdi, N., Rodríguez, M.A., Ferrari, B., & Srasra, E. (2020). Synthesis and characterization of Tunisian organoclay: application as viscosifier in oil drilling fluid. Chemical Engineering Research and Design, 153, 427434.CrossRefGoogle Scholar
Murray, H.H. (1991). Overview – clay mineral applications. Applied Clay Science, 5, 379395.CrossRefGoogle Scholar
Ofei, T.N., Lund, B., Saasen, A., Sangesland, S., Richard, K., & Linga, H. (2019). A new approach to dynamic barite sag analysis on typical field oil-based drilling fluid. Annual Transactions of the Nordic Rheology Society, 27.Google Scholar
Ofei, T.N., Lund, B., Saasen, A., & Sangesland, S. (2022). The effect of oil–water ratio on rheological properties and sag stability of oil-based drilling fluids. Journal of Energy Resources Technology, 144, 073008.CrossRefGoogle Scholar
Ogawa, M., & Kuroda, K. (1997). Preparation of inorganic–organic nanocomposites through intercalation of organoammonium ions into layered silicates. Bulletin of the Chemical Society of Japan, 70, 25932618.CrossRefGoogle Scholar
Ratkievicius, L.A., Cunha Filho, F.J.V.D., Barros Neto, E.L.D., & Santanna, V.C. (2017). Modification of bentonite clay by a cationic surfactant to be used as a viscosity enhancer in vegetable-oil-based drilling fluid. Applied Clay Science, 135, 307312.CrossRefGoogle Scholar
Ruiz-Hitzky, E., Darder, M., Alcântara, A.C.S., Wicklein, B., & Aranda, P. (2015). Recent advances on fibrous clay-based nanocomposites. In Organic-Inorganic Hybrid Nanomaterials (ed. Kalia, S. & Haldorai, Y.), pp. 3986. Springer International Publishing, Cham.Google Scholar
Shi, H., Jiang, G., Shi, H., & Luo, S. (2020). Study on morphology and rheological property of organoclay dispersions in soybean oil fatty acid ethyl ester over a wide temperature range. ACS Omega, 5, 18511861.CrossRefGoogle Scholar
Silva, I.A., Sousa, F.K.A., Menezes, R.R., Neves, G.A., Santana, L.N.L., & Ferreira, H.C. (2014). Modification of bentonites with nonionic surfactants for use in organic-based drilling fluids. Applied Clay Science, 95, 371377.CrossRefGoogle Scholar
Sinha Ray, S. & Bousmina, M. (2005) Biodegradable polymers and their layered silicate nanocomposites: in greening the 21st century materials world. Progress in Materials Science, 50, 9621079.CrossRefGoogle Scholar
Vryzas, Z., & Kelessidis, V.C. (2017). Nano-based drilling fluids: a review. Energies, 10, 540. Multidisciplinary Digital Publishing Institute.CrossRefGoogle Scholar
Weng, J., Gong, Z., Liao, L., Lv, G., & Tan, J. (2018). Comparison of organo-sepiolite modified by different surfactants and their rheological behavior in oil-based drilling fluids. Applied Clay Science, 159, 94101.CrossRefGoogle Scholar
Werner, B., Myrseth, V., & Saasen, A. (2017). Viscoelastic properties of drilling fluids and their influence on cuttings transport. Journal of Petroleum Science and Engineering, 156, 845851.CrossRefGoogle Scholar
Yang, J., Sun, J., Bai, Y., Lv, K., Zhang, G., & Li, Y. (2022). Status and prospect of drilling fluid loss and lost circulation control technology in fractured formation. Gels, 8, 260. Multidisciplinary Digital Publishing Institute.CrossRefGoogle ScholarPubMed
Yang, J., Wang, R., Sun, J., Qu, Y., Ren, H., Zhao, Z., Wang, P., Li, Y., & Liu, L. (2024). Comb polymer/layered double hydroxide (LDH) composite as an ultrahigh temperature filtration reducer for water-based drilling fluids. Applied Surface Science, 645, 158884.CrossRefGoogle Scholar
Zanten, R.V., Miller, J.J., & Baker, C. (2012). Improved stability of invert emulsion fluids. SPE-151404. OnePetro.CrossRefGoogle Scholar
Zhang, J.R., Xu, M.D., Christidis, G.E., & Zhou, C.H. (2020). Clay minerals in drilling fluids: functions and challenges. Clay Minerals, 55, 111.CrossRefGoogle Scholar
Zhou, D., Zhang, Z., Tang, J., Wang, F., & Liao, L. (2016). Applied properties of oil-based drilling fluids with montmorillonites modified by cationic and anionic surfactants. Applied Clay Science, 121–122, 18.Google Scholar
Zhuang, G., Zhang, Z., Fu, M., Ye, X., & Liao, L. (2015). Comparative study on the use of cationic–nonionic-organo-montmorillonite in oil-based drilling fluids. Applied Clay Science, 116–117, 257262.CrossRefGoogle Scholar
Zhuang, G., Zhang, H., Wu, H., Zhang, Z., & Liao, L. (2017). Influence of the surfactants’ nature on the structure and rheology of organo-montmorillonite in oil-based drilling fluids. Applied Clay Science, 135, 244252.CrossRefGoogle Scholar
Zhuang, G., Zhang, Z., Peng, S., Gao, J., & Jaber, M. (2018a). Enhancing the rheological properties and thermal stability of oil-based drilling fluids by synergetic use of organo-montmorillonite and organo-sepiolite. Applied Clay Science, 161, 505512.CrossRefGoogle Scholar
Zhuang, G., Zhang, Z., Yang, H., & Tan, J. (2018b) Structures and rheological properties of organo-sepiolite in oil-based drilling fluids. Applied Clay Science, 154, 4351.CrossRefGoogle Scholar
Zhuang, G., Zhang, Z., & Jaber, M. (2019a). Organoclays used as colloidal and rheological additives in oil-based drilling fluids: an overview. Applied Clay Science, 177, 6381.CrossRefGoogle Scholar
Zhuang, G., Gao, J., Peng, S., & Zhang, Z. (2019b). Synergistically using layered and fibrous organoclays to enhance the rheological properties of oil-based drilling fluids. Applied Clay Science, 172, 4048.CrossRefGoogle Scholar
Zhuang, G., Zhang, Z., Peng, S., Gao, J., Pereira, F.A.R., & Jaber, M. (2019c). The interaction between surfactants and montmorillonite and its influence on the properties of organo-montmorillonite in oil-based drilling fluids. Clays and Clay Minerals, 67, 190208.CrossRefGoogle Scholar