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Studies in Position and Mobility of the H Atoms in Hydrous Micas

Published online by Cambridge University Press:  01 January 2024

I. Th. Rosenqvist
I. Th. Rosenqvist*
Affiliation:
Institutt for Geologi, Blindern, Oslo, Norway
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Abstract

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The hydrogen content of dioctahedral and trioctahedral micas has been investigated by means of infrared spectroscopy and radioactivo measurements. Dioctahedral and trioctahedral micas have been treated with deuterium oxide and tritium-bearing water. The introduced isotopes of hydrogen have been determined after various thermal treatments.

It is concluded that dioctahedral hydrous micas may represent mixed crystals between K(Si3Al)Al2O10(OH)2 and H2O(Si3Al)Al2O9(OH)3, whereas trioctahedral micas seem to represent mixed layer minerals between phlogopite and vermiculite.

Type
Symposium on Clay Mineral Transformation
Information
Clays and Clay Minerals (National Conference on Clays and Clay Minerals) , Volume 11 , February 1962 , pp. 117 - 135
Copyright
Copyright © The Clay Minerals Society 1962

References

Brown, G. and Norrish, K. (1952) Hydrous micas: Min. Mag., v. 29, pp. 929–932.Google Scholar
Erdelyi, J., Koblencz, V. and Tolnay, V. (1958) Uber Hydroparagonit, ein neues Glimmermineral, sowie über seine Beziehungen zum Hydromuskovit, Natronillit und Brammallit: Acta Geologica, A Magyar Tudomanyos Akademia Földtani Közlemenyei, Tomus V, Fasciculus 2, pp. 169–186.Google Scholar
Erdelyi, J., Koblencz, V. and Varga, N. S. (1959) Neuere strukturelle Regeln der Hydro- glimmer, Hydroantigorit, ein neues Serpentinmincral und Metakolloidaler Brucit vom Csodi-Berg bei Dunabogdany (Ungarn): Acta Geologica, A Magyar Tudomanyos Akademia Földtani Közlönye, Tomus VI, Fasciculi 1-2, pp. 65–93.Google Scholar
Erdelyi, J., Koblencz, V. and Varga, N. S. (1959) Hydroamesit, ein noues Mineral aus den Hohlräumen des Basaltes von dem Halap-Berge am Plattonsecgobiet: Acta Geologica, A Magyar Tudomanyos Akademia Földtani Közlönye, Tomus VI, Fasciculi 1-2, pp. 95–106.Google Scholar
Fripiat, J. J., Chaussidon, J. and Touillaux, (1960) Study of dehydration of montmorillonite and vermiculite by infrared spectroscopy: J. Phy. Chem., v. 64, pp. 1231–1241.CrossRefGoogle Scholar
Garrels, R. M. and Howard, Peter (1959) Reactions of feldspar and mica with water at low temperature and pressure: Clays and Clay Minerals, 6th Conf., Pergamon Press, pp. 68–88.Google Scholar
Grim, R. E., Bray, R. H. and Bradley, W. F. (1937) The mica in argillaceous sediments: Amer. Min., v. 22, pp. 813–829.Google Scholar
Hendricks, S. B. and Jefferson, M. E. (1938) Vermiculite structure: Amer. Min., v. 23, pp. 851–862.Google Scholar
Lindqvist, Bengt (1959) The clay minerals of the Yühuat'ai vermiculated clay at Kiukiang in the lower Yangtze Valley, China: Bull. Geol. Inst, of the University of Uppsala, v. XXXVIII, pp. 89–103.Google Scholar
Maegdefrau, E. (1941) Die Gruppe der glimmerartigen Tonmineralien: Sprechsaal f. Keram. Glas-Email 74 (1941).Google Scholar
Moum, J. and Rosenqvist, I. Th. (1958) Hydrogen (protium) deuterium exchange in clays: Geochim. et Cosmochim. Acta, v. 14, pp. 250–252.CrossRefGoogle Scholar
Ockman, Nathan (1958) The infra-red and Raman spectra of ice: Advances in Physics, v. VII, Nos. 25-28, pp. 199–220.CrossRefGoogle Scholar
Radoslovich, E. W. (1960) The structure of muscovite, KAl2(Si3Al)O10(OH): Acta Cryst., v. 13, pp. 919–939.CrossRefGoogle Scholar
Radoslovich, E. W. and Norrish, K. (1962) The Celldimensions and Symmetry of Layer- Lattice Silicates, Amer. Min., v. 47, pp. 599–616.Google Scholar
Serratosa, J. M. and Bradley, W. F. (1958) Infra-red absorption of OH bonds in micas: Nature, v. 181, p. 111.CrossRefGoogle Scholar
White, Joe L., Bailey, G. W., Brown, C. B. and Alrichs, J. L. (1961) Infra-red investigation of the migration of lithium ions into empty octahedral sites in museovite and montmorillonite, Nature, v. 190, No. 4773, p. 342.CrossRefGoogle Scholar