Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-27T01:25:56.113Z Has data issue: false hasContentIssue false
  • English
  • Français

Some Conditions Affecting the Adsorption of Quinoline by Clay Minerals in Aqueous Suspensions

Published online by Cambridge University Press:  01 January 2024

R. W. Doehler  and
W. A. Young
R. W. Doehler
Affiliation:
Jersey Production Research Company, Tulsa, Oklahoma, USA
W. A. Young
Affiliation:
Jersey Production Research Company, Tulsa, Oklahoma, USA
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The adsorption of quinoline by Na+- and Ca2+-montmorillonite, illite, and kaolinite in water suspensions was studied for varying physico-chemical conditions. The shapes of the adsorption isotherms depended upon these imposed environmental conditions, which were quinoline concentration, pH, salinity, time, and temperature.

In order to be in the range of concentrations of organic materials in natural waters, these studies covered the concentration range, from 0 to several hundred ppm. Of the variables studied, pH was critical. Throughout the pH range 8.5–6.0, adsorption increased as pH decreased. The change in adsorption as salinity increased depended on pH, clay mineral, and quinoline concentration. In our experiments, samples reached equilibrium within 2–3 hr, and moderate temperature changes made little difference in adsorption amounts.

Under the same conditions, Na+-montmorillonite adsorbed the most quinoline, kaolinite the least, and Ca2+-montmorillonite and illite intermediate amounts.

Two mechanisms seem to control this adsorption: ion exchange and molecular adsorption. This paper attempts to explain the effects of the physico-chemical environment on adsorption by these two mechanisms.

Type
Symposium on Clay—Organic Complexes
Information
Clays and Clay Minerals (National Conference on Clays and Clay Minerals) , Volume 9 , February 1960 , pp. 468 - 483
Copyright
Copyright © The Clay Minerals Society 1960

References

Bader, R. G. and Smith, J. B. (1959) Significance of adsorption isotherms for specific- organic materials on sedimentary minerals (abstr.): Bull. Geol. Soc. Amer., v. 70, p. 1564.Google Scholar
Bradley, W. F. (1945) Molecular associations between montmorillonite and some poly- functional organic liquids: J. Amer. Chem. Soc., v. 67, pp. 975–981.CrossRefGoogle Scholar
Brindley, G. W. and Rustom, Mahmoud (1958) Adsorption and retention of an organic- material by montmorillonite in the presence of water: Amer. Min., v. 43, pp. 627–640.Google Scholar
Grim, R. E. (1953) Clay Mineralogy·. McGraw-Hill Book Co., Inc., New York, 384 pp.Google Scholar
Hoffmann, R. W. and Brindley, G. W. (1959) Adsorption of organic molecules from aqueous solutions on montmorillonite (abstr.): Bull. Geol. Soc. Amer., v. 70, pp. 1618–1619.Google Scholar
MacEwan, D. M. C. (1951) The montmorillonite minerals (montmorillonoids): in X-ray Identification and Crystal Structures of Clay Minerals: Mineralogical Society, London, pp. 86–137.Google Scholar
Norrish, K. (1954) The swelling of montmorillonite: Faraday Soc. Disc., no. 18, pp. 120–134.Google Scholar