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Potassium-Depleted Muscovite. Part I. Preparation Using Filtration Process for Treatment with Molten Lithium Nitrate

Published online by Cambridge University Press:  01 January 2024

R. D. Bronson
Affiliation:
Agronomy Department, Purdue University, Lafayette, Indiana, USA
J. M. Spain*
Affiliation:
Agronomy Department, Purdue University, Lafayette, Indiana, USA
J. L. White
Affiliation:
Agronomy Department, Purdue University, Lafayette, Indiana, USA
*
2Present address: North Carolina State College, c/o P.C.E.A. Ediflcio Ministerio de Trabajo, Lima, Peru.
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Abstract

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The reaction between molten lithium nitrate and muscovite does not go to completion in a single treatment because of the equilibrium restriction imposed by the presence of potassium in the melt. An apparatus consisting of a stainless steel vessel with a porous stainless steel filter, valve and vacuum connections was designed to eliminate this restriction and to provide for more complete removal of the equilibrium melt in each successive treatment.

Macroscopic swelling of the muscovite in the molten lithium nitrate was observed after prolonged treatment. x-Ray diffraction examination of samples of solidified melt revealed intracrystalline swelling in the muscovite.

Type
Article
Copyright
Copyright © The Clay Minerals Society 1959

Footnotes

Journal Article no. 1510, Purdue University Agr. Exp. Sta., Lafayette, Indiana.

References

Barshad, I. (1948) Vermieulite and its relation to biotite as revealed by base exchange reactions, x-ray analyses, differential thermal curves, and water content: Amer. Min., v. 33, pp. 655678.Google Scholar
De Mumbrum, L. E. (1959) Exchangeable potassium levels in vermieulite and K-depleted micas, and implications relative to potassium levels in soils: Soil Sci. Soc. Amer. Proc., v. 23, pp. 192194.CrossRefGoogle Scholar
Denison, I. A., Fry, W. E. and Gile, P. L. (1929) Alteration of muscovite and biotite in the soil: U.S. Dept. Agr. Tech. Bull. 128, 32 pp.Google Scholar
Mortland, M. M. (1958) Kinetics of potassium release from biotites: Soil Sci. Soc. Amer. Proc., v. 22, pp. 503508.CrossRefGoogle Scholar
Spain, J. M. (1958) A study of the structures and properties of certain tetra-alkyl ammonium montmorillonites: Ph.D. Thesis, Purdue University.Google Scholar
White, J. L. (1956) Reactions of molten salts with layer-lattice silicates: Clays and Clay Minerals, Natl Acad. Sci.—Natl. Res. Council pub. 454, pp. 133146.Google Scholar