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Electrokinetic Phenomena in Colloidal Clays

Published online by Cambridge University Press:  01 January 2024

D. T. Oakes  and
Emil J. Burcik
D. T. Oakes*
Affiliation:
The Pennsylvania State University, University Park, Pennsylvania, USA
Emil J. Burcik
Affiliation:
The Pennsylvania State University, University Park, Pennsylvania, USA
*
1Present address: Research Department, Lion Oil Company, EI Dorado, Arkansas.
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Abstract

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While the variations of the physical properties of colloidal suspensions of bentonite clays under various conditions of contamination have been the subject of extensive investigations, the role of the associated electrical phenomena in the impartation of these physical properties is virtually undefined. Successful techniques for the measurement of the electrical phenomena have been reported previously but they are applicable only to very dilute clay suspensions in which negligible electrical interference between clay particles exists. Apparatus and techniques applicable to concentrations of colloidal material normally used in bentonite oil-well drilling fluids were developed and are discussed.

Measurement of electrokinetic phenomena in concentrated suspensions was effected by application of the principle of electroosmosis by suitable modification of existing apparatus. The distinguishing modification was replacement of the conventional, consolidated diaphragm with a diaphragm of colloidal material supported by thin membranes.

The applicability of the apparatus and techniques is demonstrated by qualitative comparison with data of previous investigations wherein the comparable depression of the electro-kinetic potential by the addition of various contaminating ions is shown. In addition, the relation between the measured electrokinetic potential and the filtration rate is shown to be linear and independent of the valence or type of contaminant for a major portion of the investigated concentration range. This suggests that for ions which appreciably repress the electrokinetic potential the fluid-loss may be used as a means of approximating the changes of the electrokinetic potential.

Type
Article
Information
Clays and Clay Minerals (National Conference on Clays and Clay Minerals) , Volume 4 , February 1955 , pp. 225 - 239
Copyright
Copyright © The Clay Minerals Society 1955

References

Adam, N. K., 1941, The physics and chemistry of surfaces (3d ed.): Oxford University Press, London, 436 p.Google Scholar
Briggs, T. R., 1917, Electrical endosmose, I: J. Phys. Chem., v. 21, p. 198–237.CrossRefGoogle Scholar
Briggs, T. R., Bennett, H. S., and Pierson, H. L., 1918, Electrical endosmose, II: J. Phys. Chem., v. 22, p. 256–272.CrossRefGoogle Scholar
Chaney, P. E., and Oxford, W. F., 1946, The chemical treatment of drilling fluids: A. and M. College of Texas, Bull. 96, 93 p.Google Scholar
Creighton, H. J., 1943, Principles of electrochemistry, v. 1; John Wiley & Sons Inc., NewYork, 477 p.Google Scholar
Debye, P., and Hückel, E., 1923, Zur Theorie der Electrolyte: Phyzikal. Z., v. 24, p. 185–206.Google Scholar
Debye, P., and Hückel, E., 1924, Bemerkungen zu einem Sätze über die kataphoretische Wanderungsge schwindig-keit suspendierter Teilchen: Phyzikal. Z., v. 25, p. 49–52.Google Scholar
Freundlich, H., 1909, Kapillarchemie: Leipzig, 1181 p.Google Scholar
Freundlich, H., Schmidt, O., and Lindau, G., 1932, Über die Thixotropie von Bentonit- Suspensionen: Kolloid-Beihefte, v. 36, p. 43–81.CrossRefGoogle Scholar
Hartley, G. S., 1935, The application of the Debye-Hückel theory to colloidal-electrolytes: Faraday Soc. Trans., v. 31, p. 31–50.CrossRefGoogle Scholar
Hauser, E. A., and leBeau, D. S., 1941, Studies in colloidal clays. II: J. Phys. Chem., v. 45, p. 54–65.CrossRefGoogle Scholar
Helmholtz, H., 1879, Studien über elektrische Grenschichten: Ann. Physik, v. 7, p. 337–382.CrossRefGoogle Scholar
Henry, D. C., 1931, The cataphoresis of suspended particles: Proe. Roy. Soc. A, v. 133, p. 106–140.Google Scholar
Jenny, H., and Reitemeier, R. F., 1935, Ionic exchange in relation to the stability of colloidal systems: J. Phys. Chem., v. 39, p. 593–604.CrossRefGoogle Scholar
Kemp, I., 1935, On the relation between particle size and cataphoretic mobility: Faraday Soc. Trans., v. 31, p. 1347–1357.CrossRefGoogle Scholar
Marshall, C. E., 1949, Colloid chemistry of the silicate minerals: Academic Press, New York, 180 p.Google Scholar
Marshall, C. E., and Gupta, R. S., 1933, Base exchange equilibria in clays: J. Soc. Chem. Ind., v. 52, p. 433T.Google Scholar
Mukherjee, J. N., Sen Gupta, N. C., and Indra, M. K., 1943, Effect of concentration and pH on the viscous and electrochemical properties of hydrogen bentonite: J. Phys. Chem., v. 47, p. 553–577.CrossRefGoogle Scholar
Perrin, J., 1904, Mécanisme de l’électrisation de contact et solutions colloïdales: J. Chem. Phys., v. 2, p. 601–651.Google Scholar
Perrin, J., 1905, Mécanisme de l'electrisation de contact et solutions colloïdales: J. Chem. Phys., v. 3, p. 50–110.Google Scholar
Rogers, W. F., 1953, Composition and properties of oil well drilling fluids (revised): Gulf Publishing Co., Houston, 676 p.Google Scholar
Stern, , 1924: Z. Elektrochem., v. 30, p. 508.Google Scholar
Weidemann, G., 1852, Über die Bewegung von Flüssigkeiten im Kreise der geschlossenen galvanischen Säule: Pogg, Ann., v. 87, p. 321–352.Google Scholar
Weidemann, G., 1856, Über die Bewegung von Flüssigkeiten im Kreise der geschlossenen galvanischen Säule und ihre Beziehungen zur Electrolyse: Pogg. Ann., v. 99, p. 177–233.Google Scholar