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Acid Dissolution of a Texas Bentonite

Published online by Cambridge University Press:  01 January 2024

W. T. Granquist
Affiliation:
Mellon Institute, Pittsburgh, Pennsylvania, USA
G. Gardner Sumner
Affiliation:
Mellon Institute, Pittsburgh, Pennsylvania, USA
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Abstract

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Various physical properties of an acid-treated Texas bentonite were studied as a function of treatment time. The observed kinetics were pseudo first-order (large excess of acid) and on this basis and the x-ray results a model and mechanism are proposed that are consistent with observed surface area, exchange capacity, and surface acidity changes. A crude estimation of activation energy gave a value lower than that of Osthaus (1956) but of the right magnitude.

Type
Article
Copyright
Copyright © Clay Minerals Society 1957

References

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