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Base-Exchange: An Analytical Tool for Mixed-Layer Aggregates

Published online by Cambridge University Press:  01 January 2024

W. C. Ormsby
Affiliation:
Division of Ceramics, School of Mineral Industries, The Pennsylvania State University, USA Engineering Research Department, Standard Oil Company, Indiana, USA
L. B. Sand
Affiliation:
Division of Ceramics, School of Mineral Industries, The Pennsylvania State University, USA Engineering Research Department, Standard Oil Company, Indiana, USA
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Abstract

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Base-exchange determinations were made on selected clays of the montmorillonite-illite group to test this method as an analytical tool for the analysis of mixed-layer aggregates. The relatively rapid manganese method developed by Bower and Truog was used and its precision determined on monodisperse, monomineralic fractions and monodisperse fractions of prepared mixtures of illite and montmorillonite. The particle size range 1-0.25 micron was chosen for all determinations exclusive of those on bulk samples.

To establish end members, determinations were made on a series of illites, finegrained muscovite and both natural and synthetic montmorillonites.

In order to test the validity of this method, determinations were made on mixed-layer aggregates on which illite-montmorillonite percentages had been determined by other workers using x-ray techniques and chemical analysis.

Type
Article
Copyright
Copyright © Clay Minerals Society 1953

References

Bower, C. A., and Truog, E. (1940) Base-exchange capacity determination of soils and other materials: Ind. Eng. Chem. (Anal. Ed.), v. 12, p. 411413.10.1021/ac50147a012CrossRefGoogle Scholar
Bradley, W. F. (1945) Diagnostic criteria for clay minerals: Am. Mineral., v. 30, p. 704713.Google Scholar
Bradley, W. F. (1950) Interstratified growths in clays and clay-like minerals: Int. Congr. Soil Sci. Trans., v. 1, p. 421427.Google Scholar
Brown, G., and MacEwan, D. M. C. (1951) X-ray diffraction by structures with random interstratification: In “X-ray identification and crystal structures of clay minerals,” Mineralogical Society of Great Britain Monograph, Chap. 11, p. 266284.Google Scholar
Dyal, R. S., and Hendricks, S. B. (1950) Total surface of clays in polar liquids as a characteristic index: Soil Sci., v. 69, p. 421432.10.1097/00010694-195006000-00014CrossRefGoogle Scholar
Earley, J. W., Osthaus, B. B., and Milne, I. H. (1953) Purification and properties of montmorillonite: Am. Mineral., v. 38, p. 707724.Google Scholar
Foster, M. D. (1951) The importance of exchangeable magnesium and cation exchange capacity in the study of montmorillonitic clays: Am. Mineral, v. 36, p. 717730.Google Scholar
Grim, R. E. (1953) Clay Mineralogy: New York, McGraw-Hill Book Co., Inc., 384 p.Google Scholar
Grim, R. E., and Rowland, R. A. (1942) Differential thermal analysis of clay minerals and other hydrous materials: Am. Mineral., v. 27, p. 746761, 801-818.Google Scholar
Hendricks, S. B., and Alexander, L. T. (1940) Semi-quantitative estimation of montmorillonite in clays: Soil Sci. Soc. Am. Proc., v. 5, p. 95.10.2136/sssaj1941.036159950005000C0018xCrossRefGoogle Scholar
Hendricks, S. B., and Teller, E. (1942) X-ray interference in partially ordered layer lattices: J. Chem. Phys., v. 10, p. 147167.10.1063/1.1723678CrossRefGoogle Scholar
Kerr, P. F., Kulp, J. L., and Hamilton, P. K. (1949) Differential thermal analysis of reference clay mineral specimens: Am. Petrol. Inst. Proj. 49, Prelim. Report No. 3, 48 p.Google Scholar
Lewis, D. R. (1950) Base-exchange data: Am. Petrol. Inst. Proj. 49, Prelim. Report No. 7, Section 3, p. 91124.Google Scholar
MacKenzie, R. C. (1952) A micro method for determination of cation-exchange: Clay Minerals Bulletin, v. 1, p. 203.10.1180/claymin.1952.001.7.03CrossRefGoogle Scholar
Mehlig, J. P. (1939) Colormetric determination of manganese with periodate. A spectrophotometry study: Ind. Eng. Chem. (Anal. Ed.), v. 11, p. 274.10.1021/ac50133a015CrossRefGoogle Scholar
Mering, J. (1949) L'Interference des rayons X dans les systèmes à stratification desordonnée: Acta Cryst., v. 2, p. 371377.10.1107/S0365110X49000977CrossRefGoogle Scholar
Ross, C. S., and Hendricks, S. B. (1945) Minerals of the montmorillonite group, their origin and relation to soils and clays: U.S. Geol. Surv., pP 205-b, p. 2379.Google Scholar
Weaver, C. E. (1952) Mineralogy and petrology of some Paleozoic clays of central Pennsylvania: Ph.D. Thesis, The Pennsylvania State University.Google Scholar
Weaver, C. E. (1953) Mineralogy and petrology of some Ordovician K-bentonites and related limestones: Bull. Geol. Soc. America, v. 64, p. 921944.10.1130/0016-7606(1953)64[921:MAPOSO]2.0.CO;2CrossRefGoogle Scholar
Willard, H. H., and Greathouse, L. H. (1917) The colorimetric determination of manganese by oxidation with periodate: J. Am. Chem. Soc, v. 39, p. 2366.10.1021/ja02256a014CrossRefGoogle Scholar