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The use of nuclear magnetic resonance (NMR) for the determination of tetrahedral aluminium in montmorillonite

Published online by Cambridge University Press:  09 July 2018

B. A. Goodman
Affiliation:
Department of Spectrochemistry, Macaulay Institute for Soil Research, Aberdeen AB9 2QJ, UK
J. W. Stucki
Affiliation:
Department of Agronomy, University of Illinois, Urbana, Illinois 61801, USA

Abstract

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Type
Note
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1984

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References

Bragg, L. & Claringbull, G.F. (1965) Crystal Structures of Minerals. G. Bell and Sons Ltd., London.Google Scholar
Coey, J.M.D. (1980) Clay minerals and their transformations studied with nuclear techniques. Atomic Energy Review 181, 73184.Google Scholar
Deer, W.A., Howie, R.A. & Zussman, J. (1962) Rock Forming Minerals, Vol. 3 Sheet Silicates. Longmans, London.Google Scholar
Goodman, B.A., Russell, J.D., Fraser, A.R. & Woodhams, F.W.D. (1976) A Mössbauer and infra-red spectroscopic study of the structure of nontronite. Clays Clay Miner. 24, 5359.Google Scholar
Heller, L., Farmer, V.C., Mackenzie, R.C., Mitchell, B.D. & Taylor, H.F.W. (1962) The dehydroxylation and rehydroxylation of trimorphic dioctahedral clay minerals. Clay Miner. Bull. 5, 5672.Google Scholar
De Jong, H.W.S., Schramm, C.M. & Parziale, V.E. (1983) Polymerization of silicate and aluminate tetrahedra in glasses, melts, and aqueous solutions and comments on the aluminium avoidance principle. Geochim. Cosmochim. Acta 47, 12231236.Google Scholar
Kinsey, R.A., Smith, K.A., Oldfield, E. & Hower, J. (1984) Aluminium-27 and silicon-29 nuclear magnetic resonance spectroscopic investigation of natural and synthetic clays, and other phyllosilicate structures. Am. Miner. (in press).Google Scholar
Mackenzie, R.C. (1960) The evaluation of clay mineral composition with particular reference to smectites. Silicates Ind. 25, 1218, 71-75.Google Scholar
Meadows, M.D., Smith, K.A., Kinsey, R.A., Rothgeb, T.M., Skarjune, R.P. & Oldfield, E. (1982) High resolution solid state NMR of quadrupolar nuclei. Proc. Natl. Acad. Sci. USA 79, 13511355.Google Scholar
Mehring, M. (1983) Principles of High Resolution NMR in solids. Springer-Verlag, Berlin.Google Scholar
Meuller, D., Gessner, W., Behrens, H.J. & Scheller, G. (1981) Determination of the aluminium coordination in aluminium-oxygen compounds by solid state high resolution 27Al NMR. Chem. Phys. Letters 79, 5962.Google Scholar
Oldfield, E., Kinsey, R.A., Smith, K.A., Nichols, J.A. & Kirkpatrick, R.J. (1983) High resolution NMR of inorganic solids. Influence of magnetic centers on magic-angle sample-spinning line shapes in some natural aluminosilicates. J. Magn. Res. 51, 325329.Google Scholar
Oldfield, E., Schramm, S., Meadows, M.D., Smith, K.A., Kinsey, R.A. & Ackerman, J. (1982) High resolution NMR spectroscopy of quadrupolar nuclei in solids: sodium salts. J. Am. Chem. Soc. 104, 919920.Google Scholar
Rozenson, I. & Heller-Kallai, L. (1977) Mössbauer spectra of dioctahedral smectites. Clays Clay Miner. 25, 94101.Google Scholar
Samoson, A., Kundla, E. & Lippmaa, E. (1982) High resolution MAS-NMR of quadrupolar nuclei in powders. J. Magn. Res. 49, 350357.Google Scholar
Sanz, J., Meyers, J., Vielvoye, L. & Stone, W.E.E. (1978) The location and content of iron in natural biotites and phlogopites: a comparison of several methods. Clay Miner. 13, 4552.Google Scholar
Sanz, J. & Serratosa, J.M. (1984) Distinction of tetrahedrally and octahedrally coordinated Al in phyllosilicates by NMR spectroscopy. Clay Miner. 19, 113115.Google Scholar
Schmidt, V.H. (1972) Pulse response in the presence of quadrupolar splitting. Pp. 7583 in. Pulsed Magnetic and Optical Resonance, Proc. Ampere Int. Summer School 11, Basko polje. Univ. Ljubljana, Yugoslavia.Google Scholar
Schultz, L.G. (1969) Lithium and potassium absorption, dehydroxylation temperature, and structural water content of aluminious smectites. Clays Clay Miner. 17, 115149.Google Scholar