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Synthesis of ultramarine pigments from Na-A zeolite derived from kaolin waste from the Amazon

Published online by Cambridge University Press:  02 January 2018

R.A. Menezes ,
S.P.A. Paz ,
R.S. Angélica ,
R.F. Neves ,
R. Neumann ,
F.R.L. Faulstich  and
S.B.C. Pergher
R.A. Menezes*
Affiliation:
Instituto de Geociências, Laboratório de Caracterização Mineral, UFPA – Universidade Federal do Pará, Belém, PA 66075-110, Brazil
S.P.A. Paz
Affiliation:
Instituto de Geociências, Laboratório de Caracterização Mineral, UFPA – Universidade Federal do Pará, Belém, PA 66075-110, Brazil Faculdade de Engenharia de Materiais, UFPA – Universidade Federal do Pará, Campus Ananindeua, Belém, Brazil
R.S. Angélica
Affiliation:
Instituto de Geociências, Laboratório de Caracterização Mineral, UFPA – Universidade Federal do Pará, Belém, PA 66075-110, Brazil
R.F. Neves
Affiliation:
Instituto de Geociências, Laboratório de Caracterização Mineral, UFPA – Universidade Federal do Pará, Belém, PA 66075-110, Brazil
R. Neumann
Affiliation:
CETEM – Centro de Tecnologia Mineral, Rio de Janeiro, RJ, Brazil
F.R.L. Faulstich
Affiliation:
CETEM – Centro de Tecnologia Mineral, Rio de Janeiro, RJ, Brazil
S.B.C. Pergher
Affiliation:
Instituto de Química, UFRN – Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil
*
*E-mail: [email protected]
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Abstract

Ultramarine pigments were synthesized successfully from Na-A zeolite derived from kaolin waste. Na-A zeolite encapsulates the sulfur species formed and which act as chromophores, which circumvents their oxidation and the subsequent liberation of high levels of toxic gases during the reaction. Different Na-A zeolite matrices with various grain sizes (fine to coarse) were mixed with sulfur and sodium carbonate in various proportions to study the influence of these variables on the pigments’ colours and hues. After calcination at 500°C for 5 h, the products were characterized by X-ray diffraction, X-ray fluorescence and Raman spectroscopy and were classified by the Munsell system (colour and hue). Products with colour ranging from blue to green with various hues were obtained. Both colour and hue were affected by the amount of additives and by the particle size.

Keywords

kaolin wasteNa-A zeoliteultramarine pigments
Type
Research Article
Information
Clay Minerals , Volume 52 , Issue 1 , March 2017 , pp. 83 - 95
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2017

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References

Alkan, M., Hopa, C., Yilmaz, Z. & Guler, H. (2005) The effect of alkali concentration and solid/liquid ratio on the hydrothermal synthesis of zeolite NaA from natural kaolinite. Microporous and Mesoporous Materials, 86, 176–184.Google Scholar
Barata, M.S. & Angélica, R.S. (2012) Caracterização dos resíduos cauliníticos das indústrias de mineração de caulim da Amazônia como matéria-prima para produção de pozolanas de alta reatividade. Cerâmica, 58, 36–42.CrossRefGoogle Scholar
Barata, M.S., Angélica, R.S., Pollmann, H. & Costa, M.L. (2005) The use of wastes derived from kaolin processing industries as a pozzolanic material for high-performance mortars and concrete. European Journal of Mineralagy, 17, 10–10.Google Scholar
Bieseki, L., Penha, F.G. & Pergher, S.B.C. (2013) Zeolite A synthesis employing a Brazilian coal ash as the silicone and aluminum source and its application in adsorption and pigment formulation. Materials Research, 16, 38–43.CrossRefGoogle Scholar
Booth, D.G., Dann, S.E. & Weller, M.T. (2003) The effect of the cation composition on the synthesis and properties of ultramarine blue. Dyes and Pigments, 58, 73–82.Google Scholar
Brasil (2016) Ministério de Minas e Energia. Departamento Nacional de Produção Mineral. Sumário Mineral, Ministério de Minas e Energia, 135 pp. Brasília. Disponível em: <http://www.dnpm.gov.br>. Acesso em: 01/2016..+Acesso+em:+01/2016.>Google Scholar
Carneiro, B.S., Angélica, R.S., Scheller, T., De Castro, E.A.S. & Neves, R.F. (2003) Caracterização mineralógica e geoquímica e estudo das transformações de fase do caulim duro da região do Rio Capim, Pará. Cerâmica, 49, 273–244.CrossRefGoogle Scholar
Ding, L., Yang, H., Rahimi, P., Omotoso, O., Friesen, W., Fairbridge, C., Shi, Y. & Ng, S. (2010) Solid transformation of zeolite NaA to sodalite. Microporous and Mesoporous Materials, 130, 303–308.CrossRefGoogle Scholar
Gerrits, P.P.K., Vos, D.E.D., Feijen, E.J.P. & Jacobs, P.A. (1997) Raman spectroscopy on zeolites. Microporous Materials, 8, 3–17.CrossRefGoogle Scholar
Gobeltz, N., Demortier, A. & Lelieur, J.P. (1998a) Identification of the products of the reaction between sulfur and sodium carbonate. Inorganic Chemistry, 37, 136–138.Google Scholar
Gobeltz, N., Demotier, A., Lelieur, J.P. & Duhayon, C. (1998b) Encapsulation of the chromophores into the sodalite structure during the synthesis of the blue ultramarine pigment. Journal of the Chemical Society, Faraday Transactions, 94, 2257–2260.CrossRefGoogle Scholar
Gobeltz, N., Ledé, B., Raulin, K., Demortier, A. & Lelieur I., P. (2011) Synthesis of yellow and green pigments of zeolite LTA structure: Identification of their chromophores. Microporous and Mesoporous, 141, 214–221.Google Scholar
Heller-Kallai, L. & Lapides, I. (2007) Reactions of kaolinites and metakaolinites with NaOH - comparison of different samples (part 1). Applied Clay Science, 35, 99–107.CrossRefGoogle Scholar
Jankowska, A. & Kowalak, S. (2008) Synthesis of ultramarine analogs from erionite. Microporous and Mesoporous Materials, 110, 570–578.Google Scholar
Kowalak, S. & Jankowska, A. (2003) Application of zeolites as matrices for pigments. Microporous and Mesoporous Material, 61, 213–222.Google Scholar
Kowalak, S., Pawłowska, M., Miluśka, M., Stróżyk, M., Kania, J. & Przystajko, W. (1995) Synthesis of ultramarine from synthetic molecular sieves. Colloids and Surfaces, 101, 179–185.CrossRefGoogle Scholar
Kowalak, S., Wróbel, M., Gołebniak, N., Jankowska, A. & Turkot, B. (1999) Zeolite matrices for pigments. Studies in Surface Science and Catalysis, 125, 753—760.Google Scholar
Kowalak, S., Jankowska, A. & Łączkowska, S. (2004) Preparation of various color ultramarine from zeolite A under environment-friendly conditions. Catalysis Today, 90, 167–172.Google Scholar
Kowalak, S., Jankowska, A., & Laczkowska, S. (2005) Influence of cations on color and structure of ultramarine prepared from zeolite A. Studies in Surface Science and Catalysis, 158, 215–222.Google Scholar
Lapides, I. & Heller-Kallai, L. (2007) Reactions of metakaolinite with NaOH and colloidal silica — comparison of different samples (part 2). Applied Clay Science, 35, 94–98.Google Scholar
Ledé, B., Demortier, A., Gobeltz, N., Lelieur, J.P., Picquenard, E. & Duhayon, C. (2007) Observation of the υ3 Raman band of S3 inserted into sodalite cages. Journal of Raman Spectroscopy, 38, 1461–1468.CrossRefGoogle Scholar
Lewicka, E. (2016) Origin of colour after firing feldspar-quartz raw material from the Sobotka region (Lower Silesia, SW Poland). Mineral Engineering Conference, 8, 01022.Google Scholar
Loera, S., Ibarra, I.A., Laguna, H., Lima, E., Bosch, P., Lara, V. & Haro-Poniatowski, E. (2006) Colored sodalite and A zeolites. Industrial & Engineering Chemistry, 45, 9195–9200.Google Scholar
Maia, A.A.B., Saldanha, E., Angélica, R.S., Souza, C.A.G. & Neves, R.F. (2007) Utilização de rejeito de caulim da Amazônia na síntese da zeólita A. Cerâmica, 53, 319–324.Google Scholar
Maia, A.A.B., Angélica, R.S. & Neves, R.F. (2008) Estabilidade térmica da zeólita A sintetizada a partir de um rejeito de caulim da Amazônia. Cerâmica, 54, 345–350.Google Scholar
Menezes, R.A., Paz, S.P.A., Angélica, R.S., Neves, R.F. & Pergher, S.B.C. (2014) Color and shade parameters of ultramarine zeolitic pigments synthetized from kaolin waste. Materials Research, 17, 23–27.Google Scholar
Murad, E. & Köster, H.M. (1999) Determination of the Ti speciation in comercial kaolins by Raman spectroscopy. Clay Minerals, 34, 479–485.Google Scholar
Paz, S.P.A., Angélica, R.S. & Neves, R.F. (2010) Síntese hidrotermal de sodalita básica a partir de um rejeito de caulim termicamente ativado. Química Nova, 33, 579–583.CrossRefGoogle Scholar
Rigo, R.T., Pergher, S.B.C., Petkowicz, D.I. & Santos, J.H.Z. (2009) Um novo procedimento de síntese de zeólita A empregando argilas naturais. Química Nova, 32, 21—25.Google Scholar
Steufel, R. (2003) Elemental Sulfur und Sulfur Rich Compounds-II. Springer, Berlin.Google Scholar
Tarling, S.E., Barnes, P. & Klinowski, J. (1988) The structure and Si, Al distribution of the ultramarines. Acta Crystallographica, B44, 128–135.Google Scholar