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Structural and chemical heterogeneity of layer silicates and clay minerals

Published online by Cambridge University Press:  09 July 2018

V. A. Drits
V. A. Drits*
Affiliation:
Geological Institute, Russian Academy of Sciences, 7 Pyzhevsky Street, 109017Moscow, Russia
*
*E-mail: [email protected]
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Abstract

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Different forms of structural and chemical heterogeneity are considered including mixed-layer minerals, disordered layer structures containing rotational and translational stacking faults, interstratification of trans-vacant (tv) and cis-vacant (cv) layers in true micas, illites and illitesmectite (I-S), short-range order in isomorphous cation distribution etc.

Because determination of various structural and chemical imperfections requires elaboration of new diffraction and spectroscopic methodologies, special attention is paid to recent achievements in the development of new methodological approaches such as a multispecimen simulation of experimental X-ray diffraction (XRD) patterns from mixed-layer minerals, with account taken of layer-thickness fluctuations of the second type and possible difference between structures of outer and core layers; experimental determination of thickness distribution of illite crystals by HRTEMand the modified Bertaut-Warren-Averbach technique; XRD and thermal methods for determination of cv and tv layers in true micas, illites and I-S; generalization of Méring's rules to account for the behaviour of non-basal reflections for any defective structure in which two translations are irregularly interstratified; various ab initio calculations devoted to modelling infrared OH vibrations, octahedral cation distribution in dioctahedral 2:1 layer silicates, etc. It is shown that these recentlydeveloped methodologies have revealed new diversity in the structural and chemical heterogeneity of phyllosilicates and clay minerals, provided new insight into the structural mechanisms of their transformation in different geological environments, and discovered new natural processes.

Keywords

heterogeneitylayer silicatesclay mineralsmixed layersilliteillite-smectitemica
Type
Research Article
Information
Clay Minerals , Volume 38 , Issue 4 , December 2003 , pp. 403 - 432
Creative Commons
Creative Common License - CCCreative Common License - BY
Copyright © The Mineralogical Society of Great Britain and Ireland 2003 This is an Open Access article, distributed under the terms of the Creative Commons Attribution license. (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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