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Safranin removal by fine soil: thermodynamics and kinetics of adsorption

Published online by Cambridge University Press:  27 September 2024

Iraj Dehghanpour
Affiliation:
Department of Chemistry, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran
Ghazaleh Kouchakzadeh*
Affiliation:
Department of Chemistry, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran
*
Corresponding author: Ghazaleh Kouchakzadeh; Email: [email protected]

Abstract

Environmental problems caused by human intervention in nature are some of the most critical challenges facing human societies. It is essential to use suitable adsorbents to remove pollutants. The abundance, natural abundance and low cost of fine soil have made it a good candidate for removing environmental pollutants. In this research, removal of safranin dye by natural and acidic-organic-treated fine soil with sulfuric acid and ethanolamine was studied. The characteristics of natural and acidic-organic-treated fine soil were confirmed using X-ray diffraction, Fourier-transform infrared spectroscopy, Brunauer–Emmett–Teller and scanning electron microscopy techniques. The adsorbents were placed in contact with different concentrations of safranin dye solution separately. After that, the effects of adsorbent amount (0.4–3.2 g L−1), contact time (0–60 min), adsorbate concentration (5–20 ppm) and pH (3–11) were evaluated regarding the optimum safranin adsorption process. The greatest adsorption capacity of fine soil was calculated as 1250 mg g–1. The experimental results were evaluated using thermodynamic and kinetic models. The data showed that the process follows the Langmuir isotherm model and pseudo-second-order kinetic model. The intraparticle diffusion model estimated the possible mechanism of dye adsorption. Overall, it can be deduced that natural fine soil is an efficient remover of human pollutants.

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Article
Copyright
Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

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References

Abbou, B., Lebkiri, İ., Ouaddari, H., Kadiri, L., Ouass, A., Elamri, A., et al. (2022) Study of the adsorption performance of a cationic dye onto a Moroccan clay. Journal of Chemical Health Risks, 4, 563574.Google Scholar
Adebowale, K.O., Olu-Owolabi, B.I. & Chigbundu, E.C. (2014) Removal of safranin-O from aqueous solution by adsorption onto kaolinite clay. Journal of Encapsulation and Adsorption Sciences, 4, 89104.CrossRefGoogle Scholar
Akbar, S., Akhtar, M.A., Khan, A., Jilani, G., Fashina, B. & Deng, Y. (2022) Aflatoxin adsorption by natural and heated sepiolite and palygorskite in comparison with adsorption by smectite. Clays and Clay Minerals, 70, 733752.CrossRefGoogle Scholar
Albroomi, H.I., Elsayed, M.A., Baraka, A. & Abdelmaged, M.A. (2016) Batch and fixed-bed adsorption of tartrazine azo-dye onto activated carbon prepared from apricot stones. Applied Water Science, 7, 20632074.CrossRefGoogle Scholar
Alkherraz, A.M., Elsherif, K.M. & Blayblo, N.A. (2023) Safranin adsorption onto Acasia plant derived activated carbon: isotherms, thermodynamics and kinetic studies. Chemistry International, 9, 134145.Google Scholar
Amrhar, O., Berisha, A., Gana, L.E., Nassali, H. & Elyoubi, M.S. (2023) Removal of methylene blue dye by adsorption onto natural muscovite clay: experimental, theoretical and computational investigation. International Journal of Environmental Analytical Chemistry, 103, 24192444.CrossRefGoogle Scholar
Azad, F.N., Ghaedi, M., Dashtian, K., Hajati, S., Goudarzi, A. & Jamshidi, M. (2015) Enhanced simultaneous removal of malachite green and safranin O by ZnO nanorod-loaded activated carbon: modeling, optimization and adsorption isotherms. New Journal of Chemistry, 39, 79988005.CrossRefGoogle Scholar
Azizpourian, M., Kouchakzadeh, G. & Derikvand, Z. (2023) Removal of pharmaceutical compounds from aqueous solution by clay-based synthesized adsorbents: adsorption kinetics and isotherms studies. Chemical Papers, 77, 42454264.CrossRefGoogle Scholar
Baccar, R., Sarrà, M., Bouzid, J., Feki, M. & Blánquez, P. (2012) Removal of pharmaceutical compounds by activated carbon prepared from agricultural by-product. Chemical Engineering Journal, 211–212, 310317.CrossRefGoogle Scholar
Baloyi, J., Ntho, T. & Moma, J. (2018) Synthesis and application of pillared clay heterogeneous catalysts for wastewater treatment: a review. RSC Advances, 8, 51975211.CrossRefGoogle ScholarPubMed
Banerjee, P., Das, P., Zaman, A. & Das, P. (2016) Application of graphene oxide nanoplatelets for adsorption of Ibuprofen from aqueous solutions: evaluation of process kinetics and thermodynamics. Process Safety and Environmental Protection, 101, 4553.CrossRefGoogle Scholar
Bassir, S.M. & Shadizadeh, S.R. (2020) Static adsorption of a new cationic biosurfactant on carbonate minerals: application to EOR. Petroleum Science and Technology, 38, 462471.CrossRefGoogle Scholar
Bensalah, J., Habsaoui, A., Dagdag, O., Lebkiri, A., Ismi, I., Rifi, E.H. et al. (2021) Adsorption of a cationic dye (safranin) by artificial cationic resins Amberlite®IRC-50: equilibrium, kinetic and thermodynamic study. Chemical Data Collections, 35, 100756.CrossRefGoogle Scholar
Bentahar, S., Dbik, A., Khomri, M.E., Messaoudi, N.E. & Lacherai, A. (2018) Removal of a cationic dye from aqueous solution by natural clay. Groundwater for Sustainable Development, 6, 255262.CrossRefGoogle Scholar
Bergaya, F. & Lagaly, G. (2006) General introduction: clays, clay minerals, and clay science. Pp. 118 in: Handbook of Clay Science (Bergaya, F., Theng, B.K.G. & Lagaly, G., editors). Elsevier, Amsterdam, The Netherlands.Google Scholar
Bernal, V., Giraldo, L. & Moreno-Piraján, J.C. (2020) Adsorption of pharmaceutical aromatic pollutants on heat-treated activated carbons: effect of carbonaceous structure and the adsorbent–adsorbate interactions. ACS Omega, 5, 1524715256.CrossRefGoogle ScholarPubMed
Bhatnagar, A., Vilar, V.J.P., Botelho, C.M.S. & Boaventura, R.A.R. (2010) Coconut-based biosorbents for water treatment – a review of the recent literature. Advances in Colloid Interface Science, 160, 115.CrossRefGoogle ScholarPubMed
Boudriche, L., Calvet, R., Hamdi, B. & Balard, H. (2011) Effect of acid treatment on surface properties evolution of attapulgite clay: an application of inverse gas chromatography. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 392, 4554.CrossRefGoogle Scholar
Braja, M.D. & Dean, E. (2012) Principles of Geotechnical Engineering (8th edition). Cengage Learning, Boston, MA, USA, 766 pp.Google Scholar
Campos, N.F., Barbosa, C.M.B.M., Rodríguez-Díaz, J.M. & Duarte, M.M.M.B. (2018) Removal of naphthenic acids using activated charcoal: kinetic and equilibrium studies. Adsorption Science & Technology, 36, 14051421.CrossRefGoogle Scholar
Cardona, Y., Korili, S. & Gil, A. (2023) Use of clays and pillared clays in the catalytic photodegradation of organic compounds in aqueous solutions. Catalysis Reviews, 10.1080/01614940.2023.2178736.CrossRefGoogle Scholar
Casti, F., Basoccu, F., Mocci, R., De Luca, L., Porcheddu, A. & Cuccu, F. (2022) Appealing renewable materials in green chemistry. Molecules, 27, 1988.CrossRefGoogle ScholarPubMed
Chakravarty, R. & Banerjee, P. (2012) Mechanism of cadmium binding on the cell wall of an acidophilic bacterium. Bioresource Technology, 108, 176183.CrossRefGoogle ScholarPubMed
Chen, Z., Jin, X., Chen, Z., Megharaj, M. & Naidu, R. (2011) Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron. Journal of Colloid and Interface Science, 363, 601607.CrossRefGoogle ScholarPubMed
Chisholm, H. (1911) Safarine. P. 1000 in: Encyclopaedia Britannica, vol. 23 (11th ed.). Cambridge University Press, Cambridge, UK.Google Scholar
Choi, H., Choi, H., Inoue, M. & Sengoku, R. (2017) Control of the polymorphism of calcium carbonate produced by self-healing in the cracked part of cementitious materials. Applied Sciences, 7, 546.CrossRefGoogle Scholar
Chowdhury, P. & Viraraghavan, T. (2009) Sonochemical degradation of chlorinated organic compounds, phenolic compounds and organic dyes – a review. Science of the Total Environment, 407, 24742492.CrossRefGoogle ScholarPubMed
Christidis, G.E. (2012). Industrial clays. Pp. 341414 in: Advances in the Characterization of Industrial Minerals (Christidis, G.E., editor). The Mineralogical Society of Great Britain and Northern Ireland, Twickenham, UK.Google Scholar
Derikvand, Z., Akbari, S., Kouchakzadeh, G., Azadbakht, A. & Nemati, A. (2019) High performance removal of azo and cationic dyes pollutants with Mn-aluminophosphate particles: kinetics, thermodynamics, and adsorption equilibrium studies. Russian Journal of Physical Chemistry A, 93, 26042612.CrossRefGoogle Scholar
Ding, M., Zuo, S. & Qi, C. (2015) Preparation and characterization of novel composite AlCr-pillared clays and preliminary investigation for benzene adsorption. Applied Clay Science, 115, 916.CrossRefGoogle Scholar
Duan, Y., Song, Y. & Zhou, L. (2019) Facile synthesis of polyamidoamine dendrimer gel with multiple amine groups as a super adsorbent for highly efficient and selective removal of anionic dyes. Journal of Colloid and Interface Science, 546, 351360.CrossRefGoogle ScholarPubMed
Edet, U.A. & Ifelebuegu, A.O. (2020) Kinetics, isotherms, and thermodynamic modeling of the adsorption of phosphates from model wastewater using recycled brick waste. Processes, 8, 665.CrossRefGoogle Scholar
El-Kemary, M., Abdel-Moneam, Y.K., Madkour, M. & El-Mehasseb, I.M. (2011) Enhanced photocatalytic degradation of safranin-O by heterogeneous nanoparticles for environmental applications. Journal of Luminescence, 131, 570576.CrossRefGoogle Scholar
Elaiyappillai, E., Meena, B.C., Renuka, N., Santhiya, M., George, J., Kanimozhi, E.P. et al. (2021) Walnut shell derived mesoporous activated carbon for high performance electrical double layer capacitors. Journal of Electroanalytical Chemistry, 901, 115762.Google Scholar
Fayazi, M., Afzali, D., Taher, M.A., Mostafavi, A. & Gupta, V.K. (2015) Removal of safranin dye from aqueous solution using magnetic mesoporous clay: optimization study. Journal of Molecular Liquids, 212, 675685.CrossRefGoogle Scholar
Foo, K. & Hameed, B. (2010) Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156, 210.CrossRefGoogle Scholar
Gillott, J. (1987) Physical chemistry of clays. Pp. 143166 in: Clay in Engineering Geology (Gillott, J.E., editor), Development in Geotechnical Engineering, 41. Elsevier, Amsterdam, The Netherlands.Google Scholar
Guo, F., Aryana, S.A., Han, Y. & Jiao, Y. (2018) A review of the synthesis and applications of polymer–nanoclay composites. Applied Sciences, 8, 1696.CrossRefGoogle Scholar
Guo, F., Liu, Y., Wang, H., Zeng, G., Hu, X., Zheng, B. et al. (2015) Adsorption behavior of Cr(VI) from aqueous solution onto magnetic graphene oxide functionalized with 1,2-diaminocyclohexanetetraacetic acid. RSC Advances, 5, 4538445392.CrossRefGoogle Scholar
Gupta, V.K., Jain, R., Nayak, A., Agarwal, S. & Shrivastava, M. (2011) Removal of the hazardous dye – tartrazine by photodegradation on titanium dioxide surface. Materials Science and Engineering: C, 31, 10621067.CrossRefGoogle Scholar
Haleta, A.M.B., Catrinescu, C. & Macoveanu, M. (2009) Adsorption of n-hexane vapors onto non-functionalized hypercrosslinked polymers (Hypersol-Macronet™) and activated carbon: equilibrium studies. Environmental Engineering and Management Journal, 8, 173181.CrossRefGoogle Scholar
Haoue, S., Derdar, H., Belbachir, M. & Harrane, A. (2020) Polymerization of ethylene glycol dimethacrylate (EGDM), using an Algerian clay as eco-catalyst (Maghnite-H+ and Maghnite-NA+). Bulletin of Chemical Reaction Engineering, 15, 221230.CrossRefGoogle Scholar
Hebert, J., Wang, L., Wang, X., Baker, J., Rivera, N., Troedel, M. & Li, Z. (2020) Mechanisms of safranin O interaction with 1:1 layered clay minerals. Separation Science and Technology, 56, 19851995.CrossRefGoogle Scholar
Hongsawat, P. & Prarat, P. (2022) Comparative adsorption performance of oxytetracycline and sulfamethoxazole antibiotic on powder activated carbon and graphene oxide. Chemical Papers, 76, 22932305.CrossRefGoogle Scholar
Irandoost, M., Pezeshki-Modaress, M. & Javanbakht, V. (2019). Removal of lead from aqueous solution with nanofibrous nanocomposite of polycaprolactone adsorbent modified by nanoclay and nanozeolite. Journal of Water Process Engineering, 32, 100981.CrossRefGoogle Scholar
Ismail, W.N.W. & Mokhtar, S.U. (2021) Various methods for removal, treatment, and detection of emerging water contaminants. Ch. 3 in: Emerging Contaminants (Nuro, A., editor). IntechOpen, London, UK.Google Scholar
İyim, T.B. & Güçlü, G. (2009) Removal of basic dyes from aqueous solutions using natural clay. Desalination, 249, 13771379.CrossRefGoogle Scholar
Kamaraj, C., Lakshmi, S., Rose, C. & Muralidharan, C. (2017) Wet blue fiber and lime from leather industry solid waste as stabilizing additive and filler in design of stone matrix asphalt. Asian Journal of Research in Social Sciences and Humanities, 7, 240.CrossRefGoogle Scholar
Karthikeyan, S., Sivakumar, B. & Sivakumar, N. (2010) Film and pore diffusion modeling for adsorption of Reactive Red 2 from aqueous solution on to activated carbon preparedfrom bio-diesel industrial waste. E-Journal of Chemistry, 7, S175S184.Google Scholar
Kassimi, A.E., Achour, Y., Himri, M.E., Laamari, R. & Haddad, M.E. (2021) Removal of two cationic dyes from aqueous solutions by adsorption onto local clay: experimental and theoretical study using DFT method. International Journal of Environmental Analytical Chemistry, 103, 12231244.CrossRefGoogle Scholar
Kaur, S., Rani, S., Mahajan, R.K., Asif, M. & Gupta, V.K. (2015) Synthesis and adsorption properties of mesoporous material for the removal of dye safranin: kinetics, equilibrium, and thermodynamics. Journal of Industrial and Engineering Chemistry, 22, 1927.CrossRefGoogle Scholar
Kilislioğlu, A. & Aras, G. (2010) Adsorption of uranium from aqueous solution on heat and acid treated sepiolites. Applied Radiation and Isotopes, 68, 20162019.CrossRefGoogle ScholarPubMed
Kuang, Y., Zhang, X. & Zhou, S. (2020) Adsorption of methylene blue in water onto activated carbon by surfactant modification. Water, 12, 587.CrossRefGoogle Scholar
Kyzas, G.Z. & Kostoglou, M. (2014) Green adsorbents for wastewaters: a critical review. Materials, 7, 333364.CrossRefGoogle ScholarPubMed
Langmuir, I. (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40, 13611403.CrossRefGoogle Scholar
Largitte, L. & Pasquier, R. (2016) A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chemical Engineering Research and Design, 109, 495504.CrossRefGoogle Scholar
Lezehari, M., Basly, J., Baudu, M. & Bouras, O. (2010) Alginate encapsulated pillared clays: removal of a neutral/anionic biocide (pentachlorophenol) and a cationic dye (safranine) from aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 366, 8894.CrossRefGoogle Scholar
Lima, É.C., Sher, F., Guleria, A., Saeb, M.R., Anastopoulos, I., Tran, H.N. & Hosseini-Bandegharaei, A. (2021) Is one performing the treatment data of adsorption kinetics correctly? Journal of Environmental Chemical Engineering, 9, 104813.CrossRefGoogle Scholar
Lόpez-Chavez, M.C., Osorio-Revilla, G., Arellano-Cárdenas, S., Gallardo-Velázquez, T., Flores-Valle, S.O. & Lόpez-Cortez, MS. (2017) Preparation of starch/clay/glycerol nanocomposite films and their FTIR, XRD, SEM and mechanical characterizations. Revista Mexicana de Ingenieria Quimica, 16, 793804.Google Scholar
Mahdi, A.B., Aljeboree, A.M. & Alkaim, A.F. (2021) Adsorption and removal of pollutants (dyes) from wastewater using different types of low-cost adsorbents: a review. Journal of Chemical Health Risks, 11, 203212.Google Scholar
Mahmoud, M.E., Abdelfattah, A.M., Tharwat, R.M. & Nabil, G.M. (2020) Adsorption of negatively charged food tartrazine and sunset yellow dyes onto positively charged triethylenetetramine biochar: optimization, kinetics and thermodynamic study. Journal of Molecular Liquids, 318, 114297.CrossRefGoogle Scholar
Manjuladevi, M., Anitha, R. & Manonmani, S. (2018) Kinetic study on adsorption of Cr(VI), Ni(II), Cd(II) and Pb(II) ions from aqueous solutions using activated carbon prepared from Cucumis melo peel. Applied Water Science, 8, 36.CrossRefGoogle Scholar
Marsh, A., Heath, A., Patureau, P., Evernden, M. & Walker, P. (2019) Phase formation behaviour in alkali activation of clay mixtures. Applied Clay Science, 175, 1021.CrossRefGoogle Scholar
Mohamed, F. & Abukhadra, M.R. (2018) Removal of safranin dye from water using polypyrrole nanofiber/Zn-Fe layered double hydroxide nanocomposite (Ppy NF/Zn-Fe LDH) of enhanced adsorption and photocatalytic properties. Science of the Total Environment, 640–641, 352363.CrossRefGoogle ScholarPubMed
Mohan, C., Kumari, P., Kumari, N. & Negi, A. (2023) Fabrication of colored polymeric membrane using clay-based nano pigments of safranin O (SO) dye. Membranes, 13, 619.CrossRefGoogle ScholarPubMed
Mondal, S., Aikat, K. & Halder, G. (2016) Biosorptive uptake of Ibuprofen by chemically modified Parthenium hysterophorus derived biochar: equilibrium, kinetics, thermodynamics and modeling. Ecological Engineering, 92, 158172.CrossRefGoogle Scholar
Moradi, M., Moradkhani, M., Hosseini, S.H. & Olazar, M. (2022). Intelligent modeling of photocatalytically Reactive Yellow 84 azo dye removal from aqueous solutions by ZnO-light expanded clay aggregate nanoparticles. International Journal of Environmental Science and Technology, 20, 30093022.CrossRefGoogle Scholar
Morrison, A.B., Strezov, V., Niven, R.K., Taylor, M.P., Wilson, S.P., Wang, J. et al. (2023) Impact of salinity and temperature on removal of PFAS species from water by aeration in the absence of additional surfactants: a novel application of green chemistry using adsorptive bubble fractionation. Industrial & Engineering Chemistry Research, 62, 56355645.CrossRefGoogle Scholar
Natal, J.P.S., Cusioli, L.F., Magalhães-Ghiotto, G.A.V., Bergamasco, R. & Gomes, R.G. (2023) Removal of methylene blue and safranin orange pollutants from liquid effluents by soy residue. Canadian Journal of Chemical Engineering, 101, 55615575.CrossRefGoogle Scholar
Njaramba, L.K., Kim, M., Yea, Y., Yoon, Y. & Park, C.M. (2023) Efficient adsorption of naproxen and ibuprofen by gelatin/zirconium-based metal–organic framework/sepiolite aerogels via synergistic mechanisms. Chemical Engineering Journal, 452, 139426.CrossRefGoogle Scholar
Nooryazdan, A. & Ghobadi, M.H. (2019) The Landslide Lake of Jaydar. Journal of Earth Science & Climate Change, 10, 507.Google Scholar
Nourmoradi, H., Moghadam, K.F., Jafari, A. & Kamarehie, B. (2018) Removal of acetaminophen and ibuprofen from aqueous solutions by activated carbon derived from Quercus brantii (oak) acorn as a low-cost biosorbent. Journal of Environmental Chemical Engineering, 6, 68076815.CrossRefGoogle Scholar
Obradović, B. (2020) Guidelines for general adsorption kinetics modeling. Hemijska Industrija, 74, 6570.CrossRefGoogle Scholar
Panda, A.K., Mishra, B.G., Mishra, D.K. & Singh, R. (2010) Effect of sulphuric acid treatment on the physico-chemical characteristics of kaolin clay. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 363, 98104.CrossRefGoogle Scholar
Pap, S., Kirk, C.A., Bremner, B., Sekulić, M.T., Shearer, L., Gibb, S.W. & Taggart, M.A. (2020) Low-cost chitosan–calcite adsorbent development for potential phosphate removal and recovery from wastewater effluent. Water Research, 173, 115573.CrossRefGoogle ScholarPubMed
Perri, F., Cirrincione, R., Critelli, S., Mazzoleni, P. & Pappalardo, A. (2008) Clay mineral assemblages and sandstone compositions of the Mesozoic Longobucco Group, northeastern Calabria: implications for burial history and diagenetic evolution. International Geology Review, 50, 11161131.CrossRefGoogle Scholar
Pouretedal, H.R. & Sadegh, N. (2014) Effective removal of amoxicillin, cephalexin, tetracycline and penicillin G from aqueous solutions using activated carbon nanoparticles prepared from vine wood. Journal of Water Process Engineering, 1, 6473.CrossRefGoogle Scholar
Rezende, J.C.T., Ramos, V.H.S., De Oliveira, H.A., Oliveira, R.M.P.B. & De Jesús, E. (2018) Removal of Cr(VI) from aqueous solutions using clay from Calumbi Geological Formation, N. Sra. Socorro, SE State, Brazil. Materials Science Forum, 912, 16.CrossRefGoogle Scholar
Roosta, M., Ghaedi, M. & Yousefi, F. (2015) Optimization of the combined ultrasonic assisted/adsorption method for the removal of malachite green by zinc sulfide nanoparticles loaded on activated carbon: experimental design. RSC Advances, 5, 100129100141.CrossRefGoogle Scholar
Ruíz-Agudo, E., Álvarez-Lloret, P., Ibáñez-Velasco, A. & Ortega-Huertas, M. (2016) Crystallographic control in the replacement of calcite by calcium sulfates. Crystal Growth & Design, 16, 49504959.CrossRefGoogle Scholar
Saha, N., Das, L., Das, P., Bhowal, A. & Bhattacharjee, C. (2021) Comparative experimental and mathematical analysis on removal of dye using raw rice husk, rice husk charcoal and activated rice husk charcoal: batch, fixed-bed column, and mathematical modeling. Biomass Conversion and Biorefinery, 13, 1102311040.CrossRefGoogle Scholar
Sayed, M.Y.E., Abdel-Gaber, A.M. & Rahal, H.T. (2019) Safranin – a potential corrosion inhibitor for mild steel in acidic media: a combined experimental and theoretical approach. Journal of Failure Analysis and Prevention, 19, 11741180.CrossRefGoogle Scholar
Sepehr, M.N., Amrane, A., Karimaian, K.A., Zarrabi, M. & Ghaffari, H.R. (2014) Potential of waste pumice and surface modified pumice for hexavalent chromium removal: characterization, equilibrium, thermodynamic and kinetic study. Journal of the Taiwan Institute of Chemical Engineers, 45, 635647.CrossRefGoogle Scholar
Shaltout, W.A., El-Naggar, G.A., Esmail, G. & Hassan, A.F. (2024) Synthesis and characterization of ferric@nanocellulose/nanohydroxyapatite bio-composite based on sea scallop shells and cotton stalks: adsorption of safranin-O dye. Biomass Conversion and Biorefinery, 14, 47594776.CrossRefGoogle Scholar
Sharma, M., Mishra, N., Bansal, S., Siddiqui, A.M. & Khanuja, M. (2024) Efficient adsorption and photocatalytic degradation of textile dye from metal ion-substituted ferrite for environmental remediation. International Journal of Environment Science and Technology, 21, 60756092.CrossRefGoogle Scholar
Sharma, P., Kaur, H., Sharma, M. & Sahore, V. (2011) A review on applicability of naturally available adsorbents for the removal of hazardous dyes from aqueous waste. Environmental Monitoring and Assessment, 183, 151195.CrossRefGoogle ScholarPubMed
Shi, Y., Wang, X., Wang, X., Carlson, K. & Li, Z. (2021) Removal of toluidine blue and safranin O from single and binary solutions using zeolite. Crystals, 11, 1181.CrossRefGoogle Scholar
Shirsath, S.R., Hage, A., Zhou, M., Sonawane, S.H. & Ashokkumar, M. (2011) Ultrasound assisted preparation of nanoclay bentonite–FeCo nanocomposite hybrid hydrogel: a potential responsive sorbent for removal of organic pollutant from water. Desalination, 281, 429437.CrossRefGoogle Scholar
Shivaraju, H.P., Egumbo, H., Madhusudan, P., Kumar, K. & Midhun, G. (2018) Preparation of affordable and multifunctional clay-based ceramic filter matrix for treatment of drinking water. Environmental Technology, 40, 16331643.CrossRefGoogle ScholarPubMed
Shrivastava, R., Jain, S.R. & Frank, S.G. (1985) Dissolution dialysis studies of metronidazole–montmorillonite adsorbates. Journal of Pharmaceutical Sciences, 74, 214216.CrossRefGoogle ScholarPubMed
Shwan, D.M.S. (2022) Characterization of local natural clay and it's using for adsorption removal of gram stain wastes (safranin-O and Crystal Violet) from microbiological laboratories. Iranian Journal of Science, 47, 6371.CrossRefGoogle Scholar
Sieren, B., Baker, J., Wang, X., Rozzoni, S.J., Carlson, K., McBain, A. et al. (2020) Sorptive removal of color dye safranin O by fibrous clay minerals and zeolites. Advances in Materials Science and Engineering, 2020, 112.CrossRefGoogle Scholar
Silva, D.L., Balaba, N., Horsth, D.F.L., Jaerger, S. & Anaissi, F.J. (2023) Characterization of calcined red soil applied in the removal of methylene blue dye from wastewater to produce a hybrid pigment. Clay Minerals, 58, 8394.CrossRefGoogle Scholar
Suleman, M., Zafar, M., Ahmed, A., Rashid, M.U., Hussain, S., Razzaq, A. et al. (2021). Castor leaves-based biochar for adsorption of safranin from textile wastewater. Sustainability, 13, 6926.CrossRefGoogle Scholar
Tezcanli-Güyer, G. & Ince, N.H. (2004) Individual and combined effects of ultrasound, ozone and UV irradiation: a case study with textile dyes. Ultrasonics, 42, 603609.CrossRefGoogle ScholarPubMed
Uğraşkan, V., Işık, B., Yazıcı, Ö. & Çakar, F. (2022) Removal of safranine T by a highly efficient adsorbent (Cotinus coggygria leaves): isotherms, kinetics, thermodynamics, and surface properties. Surfaces and Interfaces, 28, 101615.CrossRefGoogle Scholar
Uygun, O., Murat, A. & Çakal, G.Ö. (2023) Magnetic sepiolite/iron(III) oxide composite for the adsorption of lead(II) ions from aqueous solutions. Clay Minerals, 58, 267279.CrossRefGoogle Scholar
Vicente, M., Gil, A. & Bergaya, F. (2013) Pillared clays and clay minerals. Pp. 523557 in: Handbook of Clay Science (Bergaya, F., Theng, B.K.G. & Lagaly, G., editors). Elsevier, Amsterdam, The Netherlands.CrossRefGoogle Scholar
Vifttaria, M., Nurhayati, N. & Anita, S. (2019) Surface acidity of sulfuric acid activated Maredan clay catalysts with Boehm titration method and pyridine adsorption-FTIR. Journal of Physics: Conference Series, 1351, 012040.Google Scholar
Wahab, N., Saeed, M., Ibrahim, M., Munir, A., Saleem, M., Zahra, M. & Waseem, A. (2019) Synthesis, characterization, and applications of silk/bentonite clay composite for heavy metal removal from aqueous solution. Frontiers in Chemistry, 7, 654.CrossRefGoogle Scholar
Wang, Z., Zhao, Q., Wang, D. & Cui, C. (2021) Synthesis and characterization of ordered mesoporous MCM-41 from natural chlorite and its application in methylene blue adsorption. Clays and Clay Minerals, 69, 217231.CrossRefGoogle Scholar
Xu, J., Wang, L. & Zhu, Y. (2012) Decontamination of bisphenol A from aqueous solution by graphene adsorption. Langmuir, 28, 84188425.CrossRefGoogle ScholarPubMed
Yarmohammadi, N., Ghadermazi, M., Derikvand, Z. & Mozafari, R. (2022) In situ synthesis of bimetallic γ-Fe2O3/Cu nanoparticles over pectin hydrogel obtained from biomass resource (orange peel) as a reusable green catalyst for oxidation and C–S cross-coupling reactions. Chemical Papers, 76, 42894307.CrossRefGoogle Scholar
Yin, J., Deng, C., Yu, Z., Wang, X. & Xu, G. (2018) Effective removal of lead ions from aqueous solution using nano illite/smectite clay: isotherm, kinetic, and thermodynamic modeling of adsorption. Water, 10, 210.CrossRefGoogle Scholar
Yurtay, A. & Kılıç, M. (2023) Biomass-based activated carbon by flash heating as a novel preparation route and its application in high efficiency adsorption of metronidazole. Diamond and Related Materials, 131, 109603.CrossRefGoogle Scholar
Zawrah, M., Khattab, R., Saad, E. & Gado, R. (2014) Effect of surfactant types and their concentration on the structural characteristics of nanoclay. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 122, 616623.CrossRefGoogle ScholarPubMed
Zeng, P., Nie, X., Qin, Z., Luo, S., Fu, Y., Yu, W. et al. (2023) Adsorption of gold nanoparticles on illite under high solid/liquid ratio and initial pH conditions. Clay Minerals, 58, 245257.CrossRefGoogle Scholar
Żółtowska-Aksamitowska, S., Bartczak, P., Zembrzuska, J. & Jesionowski, T. (2018) Removal of hazardous non-steroidal anti-inflammatory drugs from aqueous solutions by biosorbent based on chitin and lignin. Science of the Total Environment, 612, 12231233.CrossRefGoogle ScholarPubMed