Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-16T18:24:18.922Z Has data issue: false hasContentIssue false

Regeneration of spent bleaching clay by ultrasonic irradiation and its application in methylene blue adsorption

Published online by Cambridge University Press:  04 February 2020

Xiaoyu Liang
Affiliation:
College of Sciences, Henan Agricultural University, Zhengzhou, Henan450001, China The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), School of Environment and Energy, South China University of Technology, Guangzhou510006, China
Chao Yang
Affiliation:
Ministry Key Laboratory of Oil and Gas Fine Chemicals, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi830046, China
Xintai Su*
Affiliation:
The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters (Ministry of Education), School of Environment and Energy, South China University of Technology, Guangzhou510006, China
Xiaogang Xue
Affiliation:
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou350002, China

Abstract

An effective method that combines solvent extraction with ultrasonic irradiation was developed to recycle spent bleaching clay (SBC) from modern oil refinery plants. The principle of ‘waste to treasure’ was used to achieve the regenerated SBC. Various characterization techniques were applied to analyse and compare regenerated SBC and commercial bleaching clay (CBC). The structure of the regenerated SBC did not show any obvious change compared with that of CBC, but the Brunauer–Emmett–Teller-specific surface area (SBET) and pore-volume values of the regenerated SBC increased. At the same time, the parameters of the regenerated SBC reached national standards. In addition, the samples were used as low-cost adsorbents for the adsorption of methylene blue (MB) from water. The regenerated SBC had greater adsorption efficiency and cycle performance for MB than CBC. Hence, the SBC may be treated by ultrasonic radiation combined with extraction, and the regenerated SBC has better properties than CBC. This work opens up a new approach to the regeneration and utilization of SBC and raises the potential of ultrasonic irradiation as an environmentally friendly method to be applied to various regeneration systems.

Type
Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Chun-Hui Zhou

References

Abdel-Gawad, F.M.H., Hashad, A. & Elgemeie, G.H. (2014) Fate of 14C-ethion insecticide in the presence of deltamethrin and dimilin pesticides in cotton seeds and oils, removal of ethion residues in oils, and bioavailability of its bound residues to experimental animals. Journal of Agriculural and Food Chemistry, 62, 1228712293.CrossRefGoogle ScholarPubMed
Alves, H.P.A., Silva, J.B., Campos, L.F.A., Torres, S.M., Dutra, R.P.S. & Macedo, D.A. (2016) Preparation of mullite based ceramics from clay–kaolin waste mixtures. Ceramics International, 42, 1908619090.CrossRefGoogle Scholar
Boey, P.L., Ganesan, S. & Maniam, G.P. (2011) Regeneration and reutilization of oil-laden spent bleaching clay via in situ transesterification and calcination. Journal of the American Oil Chemists Society, 88, 12471253.CrossRefGoogle Scholar
Boey, P.L., Ganesan, S., Maniam, G.P. & Ali, D.M.H. (2011) Ultrasound aided in situ transesterification of crude palm oil adsorbed on spent bleaching clay. Energy Conversion and Management, 52, 20812084.CrossRefGoogle Scholar
Boukerroui, A. & Ouali, M.S. (2000) Regeneration of a spent bleaching earth and its reuse in the refining of an edible oil. Journal of Chemical Technology and Biotechnology, 75, 773776.3.0.CO;2-L>CrossRefGoogle Scholar
Cantuaria, M.L., de Almeida Neto, A.F., Nascimento, E.S. & Vieira, M.G. (2016) Adsorption of silver from aqueous solution onto pre-treated bentonite clay: complete batch system evaluation. Journal of Cleaner Production, 112, 11121121.CrossRefGoogle Scholar
Chang, J.I., Tai, H.S. & Huang, T.H. (2006) Regeneration of spent bleaching earth by lye-extraction. Environmental Progress, 25, 373378.CrossRefGoogle Scholar
Cilla, M.S., de Melo Cartaxo, J., Menezes, R.R., delima Santana, L.N. & de Araujo Neves, G. (2016) Production of fire clay porous structure with no aligned macro porosity from water-based slurry by freeze casting process: a new approach. Ceramics International, 42, 92789282.CrossRefGoogle Scholar
Darvishi, Z. & Morsali, A. (2011) Synthesis and characterization of nano-bentonite by sonochemical method. Ultrasonics Sonochemistry, 18, 238242.CrossRefGoogle ScholarPubMed
DíazGómez-Treviño, A., Martínez-Miranda, V. & Solache-Ríos, M. (2013) Removal of remazol yellow from aqueous solutions by unmodified and stabilized iron modified clay. Applied Clay Science, 80, 219225.CrossRefGoogle Scholar
Dimirkou, A., Ioannou, A. & Doula, M.P. (2002) Preparation, characterization and sorption properties for phosphates of hematite, bentonite and bentonite–hematite systems. Advances in Colloid and Interface Science, 97, 3761.CrossRefGoogle ScholarPubMed
Eliche-Quesada, D. & Corpas-Iglesias, F. (2014) Utilisation of spent filtration earth or spent bleaching earth from the oil refinery industry in clay products. Ceramics International, 40, 1667716687.CrossRefGoogle Scholar
Eren, E. & Afsin, B. (2008) Investigation of a basic dye adsorption from aqueous solution onto raw and pre-treated bentonite surfaces. Dyes and Pigments, 76, 220225.CrossRefGoogle Scholar
Fei, J., Cui, Y., Yan, X., Qi, W., Yang, Y., Wang, K., He, Q. & Li, J. (2008) Controlled preparation of MnO2 hierarchical hollow nanostructures and their application in water treatment. Advanced Materials (Deerfield Beach), 20, 452456.CrossRefGoogle Scholar
Geleel, M.A., Atwa, S. & Sakr, A. (2013) Removal of Cr (IIIⅢ) from aqueous waste using spent activated clay. Journal of American Science, 9, 256262.Google Scholar
Guerrero, L.A., Mass, G. & Hogland, W. (2013) Solid waste management challenges for cities in developing countries. Waste Management, 33, 220232.CrossRefGoogle ScholarPubMed
Hao, T., Yang, C., Rao, X., Wang, J., Niu, C. & Su, X. (2014) Facile additive-free synthesis of iron oxide nanoparticles for efficient adsorptive removal of Congo red and Cr (VI). Applied Surface Science, 292, 174180.CrossRefGoogle Scholar
Hussin, F., Aroua, M.K. & Daud, W.M.A.W. (2011) Textural characteristics, surface chemistry and activation of bleaching earth: a review. Chemical Engineering Journal, 170, 90106.CrossRefGoogle Scholar
Jabariyan, S. & Zanjanchi, M.A. (2012) A simple and fast sonication procedure to remove surfactant templates from mesoporous MCM-41. Ultrasonics Sonochemistry, 19, 10871093.CrossRefGoogle ScholarPubMed
Jacobs, K.Y. & Schoonheydt, R.A. (2001) Time dependence of the spectra of methylene blue–clay mineral suspensions. Langmuir, 17, 51505155.CrossRefGoogle Scholar
Kamali, M., Costa, M.E.V., Otero-Irurueta, G. & Capela, I. (2018) Ultrasonic irradiation as a green production route for coupling crystallinity and high specific surface area in iron nanomaterials. Journal of Cleaner Production, 211, 185197.CrossRefGoogle Scholar
Lee, C., Seng, C. & Liew, K. (2000) Solvent efficiency for oil extraction from spent bleaching clay. Journal of the American Oil Chemists Society, 77, 12191223.CrossRefGoogle Scholar
Li, C.J., Wu, Q.Q., Petit, S., Gates, W.P., Yang, H.M., Yu, W.H. & Zhou, C.H. (2019) Insights into the rheological behavior of aqueous dispersions of synthetic saponite: effects of saponite composition and sodium polyacrylate. Langmuir, 35, 1304013052.CrossRefGoogle ScholarPubMed
Li, G.L., Luan, J.N., Zeng, X.S. & Shi, L. (2011) Removal of trace olefins from aromatics over metal-halides-modified clay and its industrial test. Industrial and Engineering Chemistry Research, 50, 66466649.CrossRefGoogle Scholar
Liu, B., Wen, L., Nakata, K., Zhao, X., Liu, S., Ochiai, T., Murakami, T. & Fujishima, A. (2012) Polymeric adsorption of methylene blue in TiO2 colloids – highly sensitive thermochromism and selective photocatalysis. Chemistry – A European Journal, 18, 1270512711.CrossRefGoogle ScholarPubMed
Lu, C.Y., Zhang, Z.P., Zhou, X.H., Hu, J.J., Ge, X.M., Xia, C.X., Zhao, J., Wang, Y., Jing, Y.Y., Li, Y.M. & Zhang, Q.G. (2018) Effect of substrate concentration on hydrogen production by photo-fermentation in the pilot-scale baffled bioreactor. Bioresource Technology, 247, 11731176.CrossRefGoogle ScholarPubMed
Lu, C.Y., Wang, Y., Lee, D-J., Zhang, Q.G, Zhang, H., Tahir, N., Jing, Y.Y., Liu, H. & Zhang, K. (2019) Biohydrogen production in pilot-scale fermenter: effects of hydraulic retention time and substrate concentration. Journal of Cleaner Production, 229, 751760.CrossRefGoogle Scholar
Luan, J.N., Li, G.L. & Shi, L. (2011) Study of modified clay and its industrial testing in aromatic refining. Industrial and Engineering Chemistry Research, 50, 71507154.CrossRefGoogle Scholar
Makhoukhi, B., Villemin, D. & Didi, M. (2013) Preparation, characterization and thermal stability of bentonite modified with bis-imidazolium salts. Materials Chemistry and Physics, 138, 199203.CrossRefGoogle Scholar
Malakootian, M., Fatehizadeh, A., Yousefi, N., Ahmadian, M. & Moosazadeh, M. (2011) Fluoride removal using regenerated spent bleaching earth (RSBE) from groundwater: case study on Kuhbonan water. Desalination, 277, 244249.CrossRefGoogle Scholar
Mana, M., Ouali, M.S. & de Menorval, L.C. (2007) Removal of basic dyes from aqueous solutions with a treated spent bleaching earth. Journal of Colloid and Interface Science, 307, 916.CrossRefGoogle ScholarPubMed
Mana, M., Ouali, M., Lindheimer, M. & de Menorval, L.C. (2008) Removal of lead from aqueous solutions with a treated spent bleaching earth. Journal of Hazardous Materials, 159, 358364.CrossRefGoogle ScholarPubMed
Mana, M., Ouali, M., de Menorval, L.C., Zajac, J. & Charnay, C. (2011) Regeneration of spent bleaching earth by treatment with cethyltrimethylammonium bromide for application in elimination of acid dye. Chemical Engineering Journal, 174, 275280.CrossRefGoogle Scholar
Meziti, C. & Boukerroui, A. (2012) Removal of a basic textile dye from aqueous solution by adsorption on regenerated clay. Procedia Engineering, 33, 303312.CrossRefGoogle Scholar
Mohamed, M., Mohand, S.O., Marc, L. & Louis, C.M. (2008) Removal of lead from aqueous solutions with a treated spent bleaching earth. Journal of Hazardous Materials, 159, 358364.Google Scholar
Morrow, C.P., Yazaydin, A.O.Z.R., Krishnan, M., Bowers, G.M., Kalinichev, A.G. & Kirkpatrick, R.J. (2013) Structure, energetics, and dynamics of smectite clay interlayer hydration: Molecular dynamics and metadynamics investigation of Na-hectorite. Journal of Physical Chemistry C, 117, 51725187.CrossRefGoogle Scholar
Mostafa, R., Mohamed, A. & Sherouk, M. (2019) Insight into the catalytic conversion of palm oil into biodiesel using Na+/K+ trapped muscovite/phillipsite composite as a novel catalyst: effect of ultrasonic irradiation and mechanism. Renewable and Sustainable Energy Reviews, 115, 109346.Google Scholar
Mullassery, M.D., Fernandez, N.B. & Anirudhan, T.S. (2014) Adsorptive removal of acid red from aqueous solutions by cationic surfactant-modified bentonite clay. Desalination and Water Treatment, 56, 111.Google Scholar
Namasivayam, C. & Kavitha, D. (2002) Removal of Congo red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes and Pigments, 54, 4758.CrossRefGoogle Scholar
Occelli, M. & Biz, S. (2000) Surfactant effects on the physical properties of mesoporous silica and silicates. Journal of Molecular Catalysis A: Chemical, 151, 225231.CrossRefGoogle Scholar
Sakizci, M., Alver, B.E., Alver, Ö. & Yörükoğullari, E. (2010) Spectroscopic and thermal studies of bentonites from Ünye, Turkey. Journal of Molecular Structure, 969, 187191.CrossRefGoogle Scholar
Santana, L., Gomes, J., Neves, G., Lira, H., Menezes, R. & Segadaes, A. (2014) Mullite formation from bentonites containing kaolinite: effect of composition and synthesis parameters. Applied Clay Science, 87, 2833.CrossRefGoogle Scholar
Sujana, M., Pradhan, H. & Anand, Y.S. (2009) Studies on sorption of some geomaterials for fluoride removal from aqueous solutions. Journal of Hazardous Materials, 161, 120125.CrossRefGoogle ScholarPubMed
Sutcu, M. (2015) Influence of expanded vermiculite on physical properties and thermal conductivity of clay bricks. Ceramics International, 41, 28192827.CrossRefGoogle Scholar
Tsai, W., Chen, H., Hsieh, M., Sun, H. & Chien, S. (2002) Regeneration of spent bleaching earth by pyrolysis in a rotary furnace. Journal of Analytical and Applied Pyrolysis, 63, 157170.CrossRefGoogle Scholar
Tsai, W., Chen, H., Hsieh, M., Sun, H. & Lai, C. (2003) Regeneration of bleaching clay waste by chemical activation with chloride salts. Journal of Environmental Science and Health Part A, 38, 685696.CrossRefGoogle ScholarPubMed
Unuabonah, E.I., Günter, C., Weber, J., Lubahn, S. & Taubert, A. (2013) Hybrid clay: a new highly efficient adsorbent for water treatment. ACS Sustainable Chemistry & Engineering, 1, 966973.CrossRefGoogle Scholar
Wambu, E.W., Muthakia, G.K. & Shiundu, P.M. (2009) Regeneration of spent bleaching earth and its adsorption of copper (II) ions from aqueous solutions. Applied Clay Science, 46, 176180.CrossRefGoogle Scholar
Wang, W., Wang, X., Song, C., Wei, X., Ding, J. & Xiao, J. (2013) Sulfuric acid modified bentonite as the support of tetraethylenepentamine for CO2 capture. Energy and Fuel, 27, 15381546.CrossRefGoogle Scholar
Wilke, I., Ramanathan, V., LaChance, J., Tamalonis, A., Aldersley, M., Joshi, P. C. & Ferris, J. (2014) Characterization of the terahertz frequency optical constants of montmorillonite. Applied Clay Science, 87, 6165.CrossRefGoogle Scholar
Yuan, J., Chadwick, D., Zhang, D., Li, G., Chen, S., Luo, W., Du, L., He, S. & Peng, S. (2016) Effects of aeration rate on maturity and gaseous emissions during sewage sludge composting. Waste Management, 56, 403410.CrossRefGoogle ScholarPubMed
Zhou, C.H., Zhao, L.Z., Wang, A.Q., Chen, T.H. & He, H.P. (2016) Current fundamental and applied research into clay minerals in China. Applied Clay Science, 119, 37.CrossRefGoogle Scholar
Zhou, C.H., Li, C.J., Gates, W.P., Zhu, T.T. & Yu, W.H. (2019) Co-intercalation of organic cations/amide molecules into montmorillonite with tunable hydrophobicity and swellability. Applied Clay Science, 179, 105157.CrossRefGoogle Scholar
Supplementary material: File

Liang et al. Supplementary Materials

Liang et al. Supplementary Materials

Download Liang et al. Supplementary Materials(File)
File 43.5 KB