Hostname: page-component-cd9895bd7-lnqnp Total loading time: 0 Render date: 2024-12-23T16:09:19.087Z Has data issue: false hasContentIssue false
  • English
  • Français

Natural clay from Cuba for environmental remediation

Published online by Cambridge University Press:  02 July 2018

S. A. Martín ,
L. Valdés ,
F. Mérida ,
L. C. de Ménorval ,
M. Velázquez  and
A. Rivera
S. A. Martín
Affiliation:
Zeolites Engineering Laboratory, Institute of Materials Science and Technology (IMRE), University of Havana, 10400 Havana, Cuba
L. Valdés
Affiliation:
Department of Pharmacy, Institute of Pharmacy and Food (IFAL), University of Havana, 17100 Havana, Cuba
F. Mérida
Affiliation:
Zeolites Engineering Laboratory, Institute of Materials Science and Technology (IMRE), University of Havana, 10400 Havana, Cuba
L. C. de Ménorval
Affiliation:
Institut Charles Gerhardt Montpellier, Equipe Agrégats, Interface, et Matériaux pour l'Energie (AIME), Université Montpellier 2, 34900France
M. Velázquez
Affiliation:
Research Center for Mining Metallurgy Industries (CIPIMM), 10800 Havana, Cuba
A. Rivera*
Affiliation:
Zeolites Engineering Laboratory, Institute of Materials Science and Technology (IMRE), University of Havana, 10400 Havana, Cuba
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

The use of natural clays for the removal of dyes from wastewater, an important part of environmental remediation, is desirable due, not least, to their low cost. Palygorskite (PAL), a rigid-structure clay, is a good candidate for use in the elimination of industrial effluents, based on its exceptional adsorptive properties. Recently, a new palygorskite deposit has been discovered in Cuba and its use in the adsorption of dyes has not yet been explored in detail. In the present study, the use of unmodified natural Cuban palygorskite as a host for dyes was evaluated. Congo red (CR) and methylene blue (MB) were the anionic and cationic dyes tested, respectively, because of their wide use and toxicity to the environment. Several physical-chemical parameters were studied in order to establish the best experimental conditions under which to achieve the greatest dye load per gram of clay. Natural mixtures with different percentages of montmorillonite were also tested to evaluate their effect on the adsorption of the dyes. The results indicated that at pH values of ~7–9 and an initial dye concentration of 0.1 mg mL–1, the process was efficient. X-ray diffraction (XRD) analysis proved the surface adsorption of both dyes on the clays. The main interactions involved in the clay-dye system were electrostatic forces and H-bonds. Adsorption of CR seemed to be controlled fundamentally by the palygorskite phase. Such results support the use of this natural clay as an efficient host for the removal of MB and CR from wastewater.

Keywords

dyesnatural claypalygorskite-montmorilloniteremovalCongo redmethylene blue
Type
Article
Information
Clay Minerals , Volume 53 , Issue 2 , June 2018 , pp. 193 - 201
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

This paper was originally presented during the session: ‘ES-02: Environmental applications of clay minerals’ of the International Clay Conference 2017.

§

Contributed equally to this work.

Guest Associate Editor: Claudio Camesselle

References

REFERENCES

Al-Futaisi, A., Jamrah, A. & Al-Hanai, R. (2007) Aspects of cationic dye molecule adsorption to palygorskite. Desalination, 214, 327–342.Google Scholar
Bergaya, F. & Lagaly, G. (2006) General Introduction: Clays, Clays Minerals, and Clay Science. Pp. 3–43 in: Handbook of Clay Science (Bergaya, F., Theng, B.K.G., and Lagaly, G., editors). Developments in Clay Science, 1, Elsevier, Amsterdam.Google Scholar
Chang, P.-H., Li, Z., Yu, T.-L., Munkhbayer, S., Kuo, T.-H., Hung, Y.-C., Jean, J.-S. & Lin, K.-H. (2009) Sorptive removal of tetracycline from water by palygorskite. Journal of Hazardous Materials, 165, 148–155.Google Scholar
Chemeda, Y.C., Christidis, G.E., Tauhid-Khan, N.M., Koutsopoulou, E., Hatzistamou, V. & Kelessidis, V.C. (2014) Rheological properties of palygorskite-bentonite and sepiolite-bentonite mixed clay suspensions. Applied Clay Science, 90, 165–174.Google Scholar
Chen, H. & Zhao, J. (2009) Adsorption study for removal of Congo red anionic dye using organo-attapulgite. Adsorption, 15, 381–389.Google Scholar
Chen, H., Zhao, J., Zhong, A. & Jin, Y. (2011) Removal capacity and adsorption mechanism of heat-treated palygorskite clay for methylene blue. Chemical Engineering Journal, 174, 143–150.Google Scholar
Chen, H., Zhong, A., Wu, J., Zhao, J. & Yan, H. (2012) Adsorption behaviors and mechanisms of methyl orange on heat-treated palygorskite clays. Industrial & Engineering Chemistry Research, 51, 14026–14036.Google Scholar
da Silva, M.P., Ferreira-Santos, M.S., Chaves-Santos, M.R.M., Santos Júnior, L.S., da Fonseca, M.G. & da Silva Filho, E.C. (2016) Natural palygorskite as an industrial dye remover in single and binary systems. Materials Research, 19, 1232–1240.Google Scholar
Galán, E. (1996) Properties and applications of palygorskite-sepiolite clays. Clay Minerals, 31, 443–453.Google Scholar
Gupta, V.K., Khamparia, S., Tyagi, I., Jaspal, D. & Malviya, A. (2015) Decolorization of mixture of dyes: A critical review. Global Journal Environmental Science Management, 1, 71–94.Google Scholar
Hajjaji, W., Andrejkovičová, S., Pullar, R.C., Tobaldi, D.M., Lopez-Galindo, A., Jammousi, F., Rocha, F. & Labrincha, J.A. (2016) Effective removal of anionic and cationic dyes by kaolinite and TiO2/kaolinite composites. Clay Minerals, 51, 19–27.Google Scholar
Ismadji, S., Edi, F. & Ayucitra, A. (2015) Natural clay minerals as environmental cleaning agents. Pp. 5–52 in: Clay Materials for Environmental Remediation (Sharma, S.K., editor). Springer, London.Google Scholar
Mills, A., Hazafy, D., Parkinson, J., Tuttle, T. & Hutchings, M.G. (2011) Effect of alkali on methylene blue (C.I. Basic Blue 9) and other thiazine dyes. Dyes and Pigments, 88, 149–155.Google Scholar
Milošević, M., Logar, M., Dojčinović, B., Rosić, A. & Erić, S. (2016) Diffuse reflectance spectra of methylene blue adsorbed on different types of clay samples. Clay Minerals, 51, 81–96.Google Scholar
Mineralogy Database (2012) http://webmineral.com/.Google Scholar
Moreira, M.A., Ciuffi, K.J., Rives, V., Vicente, M.A., Trujillano, R., Gil, A., Korili, S.A. & de Faria, E.H. (2017) Effect of chemical modification of palygorskite and sepiolite by 3-aminopropyltriethoxisilane on adsorption of cationic and anionic dyes. Applied Clay Science, 135, 394–404.Google Scholar
Mu, B. & Wang, A. (2016) Adsorption of dyes onto palygorskite and its composites: A review. Journal of Environmental Chemical Engineering, 4, 1274–1294.Google Scholar
Mukherjee, K., Kedia, A., Rao, K.J., Dhir, S. & Paria, S. (2015) Adsorption enhancement of methylene blue dye at kaolinite clay–water interface influenced by electrolyte solutions. Royal Society of Chemistry Advances, 5, 30654–30659.Google Scholar
Myllykylá, E., Tanhua-Tyrkko, M., Bouchet, A. & Tiljander, M. (2013) Dissolution experiments of Na- and Ca-montmorillonite in groundwater simulants under anaerobic conditions. Clay Minerals, 48, 295–308.Google Scholar
Rafatullah, M., Othman Sulaiman, O., Hashim, R. & Ahmad, A. (2010) Adsorption of methylene blue on low-cost adsorbents: A review. Journal of Hazardous Materials, 177, 70–80.Google Scholar
Rozalén, M.L., Huertas, F.J., Brady, P.V., Cama, J., García-Palma, S. & Linares, J. (2008) Experimental study of the effect of pH on the kinetics of montmorillonite dissolution at 25°C. Geochimica et Cosmochimica Acta, 72, 4224–4253.Google Scholar
Rozalén, M., Huertas, F.J. & Brady, P.V. (2009) Experimental study of the effect of pH and temperature on the kinetics of montmorillonite dissolution. Geochimica et Cosmochimica Acta, 73, 3752–3766.Google Scholar
Sarkar, B., Erming Liua, E., McClure, S., Sundaramurthy, J., Srinivasan, M. & Naidua, R. (2015) Biomass derived palygorskite–carbon nanocomposites: Synthesis, characterisation and affinity to dye compounds. Applied Clay Science, 114, 617–626.Google Scholar
Sattler, K.D. (2010) Handbook of Nanophysics: Functional Nanomaterials. Pp. 3-1–3-15. Taylor & Francis Group, New York.Google Scholar
Shuchuan, P., Shisheng, W., Tianhu, C., Shaotong, J. & Chuanhu, H. (2006) Adsorption kinetics of methylene blue from aqueous solutions onto palygorskite. Acta Geologica Sinica, 80, 236–242.Google Scholar
Taha, D.N. & Samaka, I. S. (2012) Natural Iraqi palygorskite clay as low cost adsorbent for the treatment of dye containing industrial wastewater. Journal of Oleo Science, 61, 729–736.Google Scholar
Tsai, Y., Chang, P., Gao, Z., Xu, X., Chen, Y., Wang, Z., Chen, X., Yang, Z., Jean, J. & Lia, Z. (2016) Amitriptyline removal using palygorskite clay. Chemosphere, 115, 292–299.Google Scholar
Valdés, L., Martín, S.A., Hernandez, D., Lazo, L., de Ménorval, L.C. & Rivera, A. (2017) Glycopeptide–clay nanocomposite: chemical–physical characterization. Revista Cubana de Física, 34, 35–37.Google Scholar
Yaneva, Z.L. & Georgieva, N.V. (2012) Insights into Congo red adsorption on agro-industrial materials – spectral, equilibrium, kinetic, thermodynamic, dynamic and desorption studies. A review. International Review of Chemical Engineering, 4, 127–146.Google Scholar
Yang, R., Li, D., Li, A. & Yang, H. (2018) Adsorption properties and mechanisms of palygorskite for removal of various ionic dyes from water. Applied Clay Science, 151, 20–28.Google Scholar