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Kaolin in the net-like horizon of laterite in Hubei, south China

Published online by Cambridge University Press:  09 July 2018

Hanlie Hong ,
Zhaohui Li ,
Muzhuang Yang ,
Ping Xiao  and
Huijuan Xue
Hanlie Hong*
Affiliation:
Faculty of Earth Sciences, China University of Geosciences, Wuhan, Hubei, China 430074
Zhaohui Li
Affiliation:
Geosciences Department, University of Wisconsin – Parkside, Kenosha, WI 53141-2000, USA Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan, 70101, Taiwan
Muzhuang Yang
Affiliation:
School of Geographical Sciences, Guangzhou University, Guangzhou, Guangdong, China
Ping Xiao
Affiliation:
Faculty of Earth Sciences, China University of Geosciences, Wuhan, Hubei, China 430074
Huijuan Xue
Affiliation:
Faculty of Earth Sciences, China University of Geosciences, Wuhan, Hubei, China 430074
*
*E-mail: [email protected]
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Abstract

The clay mineralogy and chemical composition of the white veins, red matrix and both Fe- and Mn-bearing nodules occurring in a laterite profile in Hubei, south China were investigated using X-ray diffraction, scanning electron microscopy equipped with an energy-dispersive spectrometer, and high-resolution transmission electron microscopy. The results show that the mineral components of the red matrix are mainly quartz, kaolinite, halloysite, goethite and minor illite, whereas the white net-like veins contain mostly quartz, kaolinite, halloysite, and illite. In the net-like horizon, the chemical index of alteration (CIA, the ratio of Al2O3/(Al2O3+CaO+K2O+Na2O)) and the TiO2/Al2O3 ratio are 89.8% and 0.021 for the white vein and 90.7% and 0.025 for the red matrix, respectively. Both white-vein and red-matrix components have similar TiO2/Al2O3 ratios, and are similar to the ratio 0.027 of the unaltered bedrock. The similarity in TiO2/Al2O3 values indicates that all three portions of the laterite soil share the same origin. Also, although the white-vein and red-matrix components differ in Fe2O3 abundance, the similar CIA values do imply similar degrees of alteration. The Fe-bearing and Mn-bearing nodules were produced by the local accumulation of Fe2O3 and MnO, respectively. Halloysite in the weathering profile occurs in two different morphologies, tubular and platy crystals. Tubular halloysite occurs both in the red matrix and the Fe-bearing nodule whereas platy halloysite occurs only in the white vein and Mn-bearing nodule assemblages. Crystallization of small tubular halloysite from Si and Al concretions in the red matrix is observed, indicating that the morphology of these crystals in the weathering environment is mainly controlled by Fe3+ cations, whereas platy halloysite may be derived from the hydration of kaolinite.

Keywords

net-like soil horizonlateriteweatheringFe oxideskaolinHubeisouth China
Type
Research Article
Information
Clay Minerals , Volume 44 , Issue 1 , March 2009 , pp. 51 - 66
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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References

Aleva, G.J.J. (1994) Laterites. Concepts, Geology, Morphology and Chemistry. ISRIC, Wageningen, Germany.Google Scholar
Ambrosi, J.P. & Nahon, D. (1986) Petrological and geochemical differentiation of lateritic iron crust profile. Chemical Geology, 57, 371–393.Google Scholar
Arslan, M., Kadr, S., Abdoðlu, E. & Kolayli, H. (2006) Origin and formation of kaolin minerals in saprolite of Tertiary alkaline volcanic rocks, Eastern Pontides, NE Turkey. Clay Minerals, 41, 597–617.Google Scholar
Bailey, S.W. (1989) Halloysite - a critical assessment. Pp. 89–98 in: Proceedings of 9th International Clay Conference, Strasbourg, France (Farmer, V.C. & Tardy, Y., editors. Sciences Geologiques: Memoire, 86.Google Scholar
Beauvais, A. (1999) Geochemical balance of lateritization processes and climatic signatures in weathering profiles overlain by ferricretes in Central Africa. Geochimica et Cosmochimica Ada, 63, 3939–3957.Google Scholar
Bobos, L., Duplay, J., Rocha, J. & Gomes, C. (2001) Kaolinite to halloysite-7 Å transformation in the kaolin deposit of Sao Vicente De Pereira, Portugal. Clays and Clay Minerals, 49, 596–607.Google Scholar
Bourman, R.P. (1993) Perennial problems in the study of laterite — a review. Australian Journal of Earth Sciences, 40, 387–401.Google Scholar
Brimhall, G.H., Christopher, J.L., Ford, C., Bratt, L., Taylor, G. & Warin, Q. (1991) Quantitative geochemical approach to pedogenesis: importance of parent material reduction, volumetric expansion, and eolian influx in lateritization. Geoderma, 51, 51–91.Google Scholar
Brown, D.J., Helmke, P.A. & Clayton, M.K. (2003) Robust geochemical indices for redox and weathering on a granitic laterite landscape in central Uganda. Geochimica et Cosmochimica Ada, 67, 2711–2723.Google Scholar
Churchman, G.J. & Gilkes, R.J. (1989) Recognition of intermediates in the possible transformation of halloysite to kaolinite in the weathering profiles. Clay Minerals, 24, 579–590.Google Scholar
Churchman, G.J., Whitton, J.S., Claridge, G.G.C. & Theng, B.K.G. (1984) Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals, 32, 241–248.Google Scholar
Ding, Q.X. (1992) Some new knowledge on the stratigraphy of the Shewushan area. Hubei Geology, 8, 4–6 (Chinese with English abstract).Google Scholar
Eusterhues, K., Rumpel, C. & Kogel-Knabner, I. (2005) Organo-mineral associations in sandy acid forest soils: importance of specific surface area, iron oxides and micropores. European Journal of Soil Science, 56, 753–763.Google Scholar
Hong, H.L. & Tie, L.Y. (2005) Characteristics of the minerals associated with gold in the Shewushan supergene gold deposit, China. Clays and Clay Minerals, 53, 162–170.Google Scholar
Hu, X.F., Yuan, G.D. & Gong, Z.T. (1998) Origin of Quaternary red clay of southern Anhui province. Pedosphere, 8, 267–272.Google Scholar
Jackson, M. L. (1978) Soil Chemical Analyses. Authors’ publication, University of Wisconsin, Madison, USA.Google Scholar
Jiang, F.C., Wu, X.H., Xiao, H.G., Wang, S.M. & Xue, B. (1997) Age of the vermicular red soil in Jiujiang area, central China. Journal of Geomechanics, 3(4), 11–111 (Chinese with English abstract).Google Scholar
Li, C.A. & Gu, Y.S. (1997) Stratigraphic study on the vermicular red earth at Xiushui county, Jiangxi province. Journal of Stratigraphy, 21, 226–232 (Chinese with English abstract).Google Scholar
MacLean, W.H. & Kranidiotis, P. (1987) Immobile elements as monitors of mass transfer in hydrothermal alteration: Phelps Dodge massive sulfide deposits, Matagami, Quebec. Economic Geology, 2, 951-962.Google Scholar
Nahon, D. (1991) Introduction to the Petrology of Soil and Chemical Weathering. John Wiley & Sons, New York.Google Scholar
Nedachi, Y., Nedachi, M., Bennett, G. & Ohmoto, H. (2005) Geochemistry and mineralogy of the 2.45 Ga Pronto paleosols, Ontario, Canada. Chemical Geology, 214, 21–44.CrossRefGoogle Scholar
Nesbitt, H.W. & Young, G.M. (1982) Proterozoic climates and plate motion inferred from the major element chemistry of lutites. Nature, 299, 715–717.Google Scholar
Papoulis, D., Tsolis-Katagas, P. & Katagas, C. (2004) Progressive stages in the formation of kaolin minerals of different morphologies in the weathering of plagioclase. Clays and Clay Minerals, 52, 275–286.Google Scholar
Robertson, I.D.M. & Eggleton, R.A. (1991) Weathering of granitic muscovite to kaolinite and halloysite and of plagioclase-derived kaolinite to halloysite. Clays and Clay Minerals, 39, 113–126.Google Scholar
Rosolen, V., Lamotte, M., Boulet, R., Trichet, J., Rouer, O. & Melfi, A.J. (2002) Genesis of a mottled horizon by Fe-depletion within a laterite cover in the Amazon basin. Comptes Rendus Geosdence, 334, 187–195.Google Scholar
Scheffler, K., Hoernes, S. & Schwark, L. (2003) Global changes during Carboniferous—Permian glaciation of Gondwana: Linking polar and equatorial climate evolution by geochemical proxies. Geology, 31, 605–608.Google Scholar
Singer, A. (1975) A Cretaceous laterite in the Negev Desert, southern Israel. Geological Magazine, 112, 151–162.Google Scholar
Singh, B. (1996) Why does halloysite roll? - a new model. Clays and Clay Minerals, 44, 191–196.Google Scholar
Singh, B. & Mackinnon, I.D.R. (1996) Experimental transformation of kaolinite to halloysite. Clays and Clay Minerals, 44, 825–834.Google Scholar
Tardy, Y. (1992) Diversity and terminology of lateritic profile. Pp. 379–405 in: Weathering, Soil and Paleosols (Martini, I.P. & Chesworth, W., editors). Elsevier, Amsterdam.Google Scholar
Tardy, Y. & Nahon, D. (1985) Geochemistry of laterites, stability of Al-goethite, Al-hematite, and Fe 3+- kaoUnite in bauxites and ferricretes: an approach to the mechanism of concentration formation. American Journal of Science, 285, 865–903.Google Scholar
Veneman, P.L.M. & Bodine, S.M. (1982) Chemical and morphological characteristics in a New England drainage-toposequence. Soil Science Society of America Journal, 46, 359–363.Google Scholar
West, S.L., White, G.N., Deng, Y., Mclnnes, K.J., Juo, A.S.R. & Dixon, J. B. (2004) Kaolinite, halloysite, and iron oxide influence on physical behavior of formulated soils. Soil Science Society of America Journal, 68, 1452–1460.Google Scholar
Xiong, S.F., Ding, Z.L. & Liu, D.S. (2000) Vermiform red earth in south China: Pedological evidence of palaeobotany root systems. Chinese Science Bulletin, 45, 1317–1321 (in Chinese).Google Scholar
Zhao, Q.G. & Yang, H. (1995) A preliminary study on red earth and changes of Quaternary environment in south China. Quaternary Sciences, 2, 107-116 (Chinese with English abstract).Google Scholar
Zhu, J.J. (1988) Genesis and research significance of the plinthitic horizon. Geographical Research, 7, 12–20 (Chinese with English abstract).Google Scholar