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Intercalation of Tb(III) into magadiite and characterization of Tb-intercalated magadiites

Published online by Cambridge University Press:  02 January 2018

Yufeng Chen ,
Bao Yao ,
Yan Zou  and
Yudong Yan
Yufeng Chen*
Affiliation:
College of Chemistry, Nanchang University, Nanchang 330031, P.R. China
Bao Yao
Affiliation:
College of Chemistry, Nanchang University, Nanchang 330031, P.R. China
Yan Zou
Affiliation:
College of Chemistry, Nanchang University, Nanchang 330031, P.R. China
Yudong Yan
Affiliation:
College of Chemistry, Nanchang University, Nanchang 330031, P.R. China
*
*E-mail: [email protected]
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Abstract

The intercalation of Tb(III) into layered magadiite is achieved by three-step ion exchanges with H+/Na+, TBA+ (tetra-n-butylammonium ions)/H+ and Tb(EDTA)3+/TBA+. Various techniques, including powder X-ray diffraction (XRD), scanning electron microscopy equipped with energy dispersive X-ray (SEM-EDX), thermogravimetric and differential thermogravimetry (TG-DTG), Fourier transform infrared (FTIR) spectroscopy, and photoluminescent spectroscopy (PL), were employed to characterize the Tb-intercalated magadiites. The XRD results revealed that the basal spacing of the Tb-intercalated magadiites was obviously larger than that of the Na-magadiite, confirming the intercalation. The IR spectra showed no bands attributable to EDTA in the Tb-intercalated magadiites, indicating that the EDTA has broken away from Tb(III)-ETDA complexes during ion exchange. Moreover, the basal spacing of Tb-intercalated magadiite tends to increase slightly with the increase in water content in the Tb-intercalated magadiite. The PL spectra show weak emissions, attributed to 5D4-7FJ (J = 3, 4, 5, 6) transitions of Tb3+.

Keywords

photoluminescenceTb3+ ionsmagadiiteion exchange
Type
Research Article
Information
Clay Minerals , Volume 51 , Issue 4 , September 2016 , pp. 697 - 706
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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