Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-26T06:03:05.076Z Has data issue: false hasContentIssue false
  • English
  • Français

Infrared study of octahedral site populations in smectites

Published online by Cambridge University Press:  09 July 2018

J. Madejová ,
P. Komadel  and
B. Číčel
J. Madejová
Affiliation:
Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava, Slovakia
P. Komadel
Affiliation:
Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava, Slovakia
B. Číčel
Affiliation:
Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava, Slovakia
Get access Rights & Permissions [Opens in a new window]

Abstract

The hydroxyl stretching region of two montmorillonites (SWy-1, Crook County, Wyoming, USA, and JP, Jelšový Potok, Slovakia) and a ferruginous smectite (SWa-1, Grant County, Washington, USA) have been analysed using decomposition and curve-fitting. The positions and integrated intensities of component bands were correlated with the nearest cationic environment of the OH groups, and the populations of the octahedral sheet were calculated. The differences between the octahedral coefficients obtained and those from chemical analyses were 0.07 or less. This method provides reasonable contents of octahedral cations for the smectites with various iron contents, containing no other admixtures absorbing in the 3700-3500 cm–1 region. The cation distribution was found to be not completely disordered. Though some preferential pairing has been observed, no general rule could be established.

Type
Research Article
Information
Clay Minerals , Volume 29 , Issue 3 , September 1994 , pp. 319 - 326
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Besson, G., Bookin, A.S., Dainyak, L.G., Rautureau, M., Tsipurskv, S.I., Tchoubar, C. & Drits, V.A. (1983) Use of diffraction and Mössbauer methods for the structural and crystallo-chemical characterisation of nontronites. J. Appl. Cryst. 16, 374–383.CrossRefGoogle Scholar
Besson, G., Drits, V.A., Dainyak, L.G. & Smoliar, B.B. (1987) Analysis of cation distribution in dioctahedral micaceous minerals on the basis of IR spectroscopy data. Clay Miner. 22, 465–478.CrossRefGoogle Scholar
Cardile, C.M. (1987) Structural studies of montmoril-Ionites by 57Fe Mössbauer spectroscopy. Clay Miner. 22, 387–394.CrossRefGoogle Scholar
Cardile, C.M. (1988) Structural site occupation of iron within 2:1 dioctahedral phyllosilicates studied by 57Fe Mössbauer spectroscopy. Hyperfine Interactions 41, 767–770.CrossRefGoogle Scholar
Cardile, C.M. (1989) Tetrahedral iron in smectite: a critical comment. Clays Clay Miner. 37, 185–188.CrossRefGoogle Scholar
Cracium, C. (1984) Influence of the Fe3+ for Al3+ octahedral substitution on the IR spectra of montmorillonite minerals. Spectroscopy Lett. 17, 579–590.CrossRefGoogle Scholar
Dainyak, L.G. & Drits, V.A. (1987) Interpretation of Mössbauer spectra of nontronite, celadonite and glauco-nite. Clays Clay Miner. 35, 363–372.CrossRefGoogle Scholar
Dainyak, L.G., Drits, V.A. & Heifits, L.M. (1992) Computer simulation of cation distribution in dioctahedral 2:1 layer silicates using IR data: application to Mössbauer spectroscopy of a glauconite sample. Clays Clay Miner. 40, 470–479.CrossRefGoogle Scholar
Decarreau, A., Grauby, O. & Petit, S. (1992) The actual distribution of octahedral cations in 2:1 clay minerals: Results from clay synthesis. Appl. Clay Sci. 7, 147–167.CrossRefGoogle Scholar
Farmer, V.C. (1971) The characterization of adsorption bands in clays by infrared spectroscopy. Soil Sci. 112, 62–68.CrossRefGoogle Scholar
Farmer, V.C. (1974) Layer silicates. Pp. 331–363 in: Infrared Spectra of Minerals (Farmer, V.C., editor). Mineralogical Society, London.CrossRefGoogle Scholar
Fakmer, V.C. & Russell, J.D. (1967) Infrared absorption spectrometry in clay studies. Clays Clay Miner. 15, 121–142.Google Scholar
Farmer, V.C. & Russell, J.D. (1971) Interlayer complexes in layer silicates. The structure of water in lamellar ionic solutions. Trans. Faraday Soc. 67, 2737–2749.CrossRefGoogle Scholar
Goodman, B.A., Russell, J.D., Fraser, A.R. & Woodhams, F.W.D. (1976) A Mössbauer and IR spectroscopic study of the structure of nontronite. Clays Clay Miner. 24, 53–59.CrossRefGoogle Scholar
Kelley, W.P. (1955) Interpretation of chemical analysis of clays. Clays Clay Miner. 1, 92–94.CrossRefGoogle Scholar
Luca, V. (1991) Detection of tetrahedral Fe3+ sites in nontronite and vermiculite by Mössbauer spectroscopy. Clays Clay Miner. 39, 467–477.CrossRefGoogle Scholar
Madejová, J., Putyera, K. & Čičel, B. (1992) Proportion of central atoms in octahedra of smectites calculated from IR spectra. Geol. Carpathica, Ser. Clays, 43, 117–120.Google Scholar
Michaelian, K.H., Friesen, W.I., Yariv, S. & Nasser, A. (1991) Diffuse reflectance infrared spectra of kaolinite and kaolinite/alkali halide mixtures. Curve-fitting of the OH stretching region. Can. J. Chem. 69, 1786–1790.CrossRefGoogle Scholar
Morris, H.D., Bank, S. & Ellis, P.D. (1990) 27Al NMR spectroscopy of iron-bearing montmorillonite clays. J. Phys. Chem. 94, 3121–3129.CrossRefGoogle Scholar
Murad, E. (1987) Mössbauer spectra of nontronites: structural implications and characterization of associated iron oxides. Z. Pflanzenernähr. Bodenk. 150, 279–285.CrossRefGoogle Scholar
Petit, S., Prot, T., Decarreau, A., Mosser, C. & Toledo-Groke, M.C. (1992) Crystallochemical study of a population of particles in smectites from a lateritic weathering profile. Clays Clay Miner. 40, 436–445.CrossRefGoogle Scholar
Plastinina, M.A., Fedorenko, JU.G. & Shpigun, A.A. (1993) De-intercalated kaolinites: the nature of created defects and estimation of structural characteristics by the expert system of PlanÇon and Zacharie. Clay Miner. 28, 101–108.CrossRefGoogle Scholar
Rausell-Colom, J.A., Sanz, J., Fernandez, M. & Serra-Tosa, J.M. (1978) Distribution of octahedral ions in phlogopites and biotites. Proc. Int. Clay Conf. Oxford 27–36.Google Scholar
Rouxhet, P.G. (1970) Hydroxyl stretching bands in micas: a quantitative interpretation. Clay Miner. 8, 375–388.CrossRefGoogle Scholar
Russell, J.S. & Fraser, A.R. (1971) I.R. spectroscopic evidence for interaction between hydronium ions and lattice OH groups in montmorillonite. Clays Clay Miner. 19, 55–59.CrossRefGoogle Scholar
Sanz, J. & Serratoza, J.M. (1984) 29Si and 27Al high-resolution MAS-NMR spectra of phyllosilicates. J. Am. Chem. Soc. 106, 4790–4793.CrossRefGoogle Scholar
Saksena, B.D. (1964) Infrared hydroxyl frequencies of muscovite, phlogopite and biotite micas in relation to their structures. Trans. Faraday Soc. 60, 1715–1725.CrossRefGoogle Scholar
Slonimskaya, M.V., Besson, G., Dainyak, L.G., Tchoubar, C. & Drits, V. A. (1986) Interpretation of the IR spectra of celadonites and glauconites in the region of OH-stretching frequencies. Clay Miner. 21, 377–388.CrossRefGoogle Scholar
Sposito, G. & Anderson, D.M. (1975) Infrared study of exchangeable cation hydration in montmorillonite. Soil Sci. Soc. Amer. Proc. 39, 1095–1099.CrossRefGoogle Scholar
Tkáč, I., Komadel, P. & Müller, D. (1994) Acid-treated montmorillonites—a study by 29Si and 27Al MAS-NMR. Clay Miner. 29, 11–19.CrossRefGoogle Scholar
Tsipursky, S.I. & Drits, V.A. (1984) The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites. Clay Miner. 19, 177–193.CrossRefGoogle Scholar
Vedder, W. (1964) Correlation between infrared spectrum and chemical composition of mica. Am. Miner. 49, 736–768.Google Scholar
Woessner, D.E. (1989) Characterization of clay minerals by 27Al nuclear magnetic resonance spectroscopy. Am. Miner. 74, 203–215.Google Scholar