Hostname: page-component-848d4c4894-jbqgn Total loading time: 0 Render date: 2024-07-04T22:11:16.194Z Has data issue: false hasContentIssue false

The effects of salt solutions on the properties of bentonite-sand mixtures

Published online by Cambridge University Press:  09 July 2018

P. G. Studds
Affiliation:
Department of Civil Engineering, University of Leeds, Leeds, LS2 9JT, UK
D. I. Stewart*
Affiliation:
Department of Civil Engineering, University of Leeds, Leeds, LS2 9JT, UK
T. W. Cousens
Affiliation:
Department of Civil Engineering, University of Leeds, Leeds, LS2 9JT, UK
*
*Corresponding author

Abstract

The swelling behaviour and hydraulic conductivity of Na-bentonite powder and bentonite-sand mixtures (10 and 20% of bentonite by dry weight) have been measured with distilled water and various salt solutions (0.01, 0.1 and 1 mol/l concentrations), It was found that in dilute solutions, the bentonite in mixtures subjected to small confining stresses swells sufficiently to separate the sand particles and reach a clay void ratio similar to that achieved by bentonite alone. At high stresses, or in strong solutions, the bentonite in a mixture has insufficient swelling capacity to force the sand particles apart and swelling is limited by the sand pore volume. The hydraulic conductivity of a mixture depends on the bentonite void ratio, and the porosity and tortuosity of the sand matrix. A design model is proposed to predict the engineering properties of a mixture over a range of confining stresses from the properties of its constituents and the permeant.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Archie, G.E. (1942) The electrical resistivity log as an aid in determining some reservoir characteristics. Petrol. Technol. 1, 5562.Google Scholar
Atkinson, J.H. & Bransby, P.L. (1978) The Mechanics of Soils, McGraw-Hill, London.Google Scholar
Boudreau, B.P. (1996) The diffusive tortuosity of finegrained unlithified sediments. Geochim. Cosmochim. Acta, 60, 31393142.CrossRefGoogle Scholar
British Standards Institute, BS 12 (1958) Portland Cement (Ordinary and Rapid Hardening), Appendix A. HMSO Stationery, London.Google Scholar
British Standards Institute, BS 1377 (1990) Methods of Test Jbr Soils Jbr Civil Engineering Purposes. HMSO Stationery, London.Google Scholar
Cowland, J.W. & Leung, B.N. (1991) A field trial of a bentonite landfill liner. Waste Management Res. 9, 277291.Google Scholar
Day, S.R. & Ryan, C. (1995) Containment, Stabilisation and Treatment of Contaminated Soils using in situ Soil Mixing. Geoenvironment 2000. ASCE Geotechnical Special Publication No. 46, 13491365.Google Scholar
Di Maio, C. (1996) Exposure of bentonite to salt solution: osmotic and mechanical effects. Geotechnique, 46, 4, 695707.Google Scholar
Dixon, D.A, Gray, M.N. & Thomas, A.W. (1985) A study of the compaction properties of potential clay-sand buffer mixtures for use in nuclear fuel waste disposal. Eng. Geol. 21, 247255.Google Scholar
Evans, J.C., Costa, M.J. & Cooley, B. (1995) The State-@ Stress in Soil-Bentonite Slurry Trench Cut-off Walls. Geoenvironment 2000. ASCE Geotechnical Special Publication No. 46, 11731191.Google Scholar
Graham, J., Gray, M.N., Sun, B.C. & Dixon, D.A. (1986) Strength and volume change characteristics of a sand-bentonite buffer. Proc. 2nd Int. Conf Radioactive Waste Management, Winnipeg, Man., 188-194.Google Scholar
Head, K.H.(1980) Manual of Soil Laboratory Testing, Vol. 1. Pentech Press, London.Google Scholar
Klute, A., (1986) Methods of Soil Analysis. Physical and Mineralogical Methods, Part l, 2nd edition. Am. Soc. Agronomy, Madison, Wis. USA.CrossRefGoogle Scholar
Kraus, J.F., Benson, C.H., Erickson, A.E. & Chamberlain, E.J. (1997) Freeze-thaw cycling and hydraulic conductivity of bentonitic barriers. ASCE J. Geotech. Eng., 123, 229238.Google Scholar
Lerman, A. (1979) Geochemical Processes in Water and Sediment Environments. John Wiley & Sons, New York.Google Scholar
Mollins, L.H. (1996) The design of bentonite-sand mixtures. PhD thesis, Univ. Leeds, UK.Google Scholar
Mollins, L.H., Stewart, D.I. & Cousens, T.W. (1996) Predicting the properties of bentonite-sand mixtures. Clay Miner. 31, 243252.Google Scholar
Porter, L.K., Kemper, W.D., Jackson, R.D. and Stewart B,A. (1960) Chloride diffusion in soils as influenced by moisture content. Proc. Soil Sci. Soc. Am. 24, 460463.CrossRefGoogle Scholar
Shackleford, C.D. & Daniel, D.E. (1991) Diffusion in saturated soil. I: Background. A.S.C.E. J. Geotech. Eng. 117, 467484.Google Scholar
Slade, P.G., Quirk, J.P. & Norrish, K. (1991) Crystalline swelling of smectite samples in concentrated NaCI solutions in relation to layer charge. Clays Clay Miner. 39, 234238.CrossRefGoogle Scholar
Studds, P.G., Stewart, D.I. & Cousens, T.W. (1996) The effect of ion valence on the swelling behaviour of sodium montmorillonite. Proc. 4th lnt. Conf. on Reuse of Contaminated Land and Landfills, 139–142. Engineering Technics Press, Edinburgh.Google Scholar
van Olphen, H. (1977) An Introduction to Clay Colloid Chemistry. John Wiley & Sons, London.Google Scholar