Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-24T01:22:08.292Z Has data issue: false hasContentIssue false
  • English
  • Français

The effect of temperature on the swelling of montmorillonite

Published online by Cambridge University Press:  09 July 2018

F. Zhang ,
Z. Z. Zhang ,
P. F. Low  and
C. B. Roth
F. Zhang
Affiliation:
Agronomy Department, Purdue University, West Lafayette, Indiana 47907, USA
Z. Z. Zhang
Affiliation:
Agronomy Department, Purdue University, West Lafayette, Indiana 47907, USA
P. F. Low
Affiliation:
Agronomy Department, Purdue University, West Lafayette, Indiana 47907, USA
C. B. Roth
Affiliation:
Agronomy Department, Purdue University, West Lafayette, Indiana 47907, USA
Get access Rights & Permissions [Opens in a new window]

Abstract

The effect of temperature on the swelling of clay was studied by determining (1) the relation between the interlayer spacing, λ, and the swelling pressure,Π, at different values of the temperature, T, using the method of Viani et al. (1983) as modified by Wu et al. (1989); (2) the relation between λ and T at different values of Π; and (3) the relationship between Π and mw/mc, the mass ratio of water to clay, at different values of T using the method of Low (1980). The results showed that λ was essentially independent of T but that mw/mc decreased slightly with T at any value of Π. Such results are not consistent with electric double-layer theory. Therefore, it was concluded that the decrease in mw/mc with increasing T was due primarily to the thermal breakdown and consequent loss of water from the larger pores outside of the interlayer region.

Type
Research Article
Information
Clay Minerals , Volume 28 , Issue 1 , March 1993 , pp. 25 - 31
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Fraser, R.D.B. & Svzukl, E. (1966) Resolution of overlapping absorption bands by least squares procedures. Anal. Chem. 38, 1770–1773.CrossRefGoogle Scholar
Fraser, R.D.B. & Svzukl, E. (1969) Resolution of overlapping bands: functions for simulating band shapes. Anal. Chem. 41, 37–39.CrossRefGoogle Scholar
Klug, H.P. & Alexander, L.E. (1974) X-ray Diffraction Procedures for Polyerystalline and Amorphous Materials. John Wiley & Sons, New York.Google Scholar
Kolaian, J.H. & Low, P.F. (1962) Thermodynamic properties of water in suspensions of montmorillonite. Clays Clay Miner. 9, 71–84.Google Scholar
Low, P.F. (1980) The swelling of clay: II. Montmorillonites. Soil Sci. Amer. J. 44, 667–676.CrossRefGoogle Scholar
Low, P.F. (1987) Structural component of the swelling pressure of Clays. Langmuir 3, 18–25.Google Scholar
Miller, S.E. & Low, P.F. (1990) Characterization of the electrical double layer of montmorillonite. Langmuir 6, 572–578.CrossRefGoogle Scholar
Olwnant, J.L. & Low, P.F. (1982) The relative partial specific enthalpy of water in montmorillonite-water systems and its relation to the swelling of these systems. J. Coll. lnterf. Sci. 89, 366–373.Google Scholar
Pashley, R.M. (1981) Hydration forces between mica surfaces in aqueous electrolyte solutions. J. Coll. Interf. Sci. 80, 153–162.CrossRefGoogle Scholar
Van Olphen, H. (1963) An Introduction to Clay Colloid Chemistry. Interscienee, London.Google Scholar
Viani, B.E., Low, P.F. & Roth, C.B. (1983) Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite. J. Coll. Interf. ScL 96, 229–244.Google Scholar
Viani, B.E., Rotn, C.B. & Low, P.F. (1985) Direct measurement of the relation between swelling pressure and interlayer distance in Li-vermiculite. Clays Clay Miner. 33, 224–250.Google Scholar
Wu, J., Low, P.F. & Roth, C.B. (1989) Effects of octahedral-iron reduction and swelling pressure on interlayer distances in Na-montmorillonite. Clays Clay Miner. 37, 211–218.Google Scholar
Yong, R., Taylor, L.O. & Warkentin, B.P. (1963) Swelling pressures of sodium montmorillonite at depressed temperatures. Clays Clay Miner. 11, 268–281.Google Scholar