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The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction

Published online by Cambridge University Press:  09 July 2018

S. I. Tsipursky  and
V. A. Drits
S. I. Tsipursky
Affiliation:
Geological Institute of the USSR Academy of Sciences, Pyzhevsky per. 7, Moscow, USSR
V. A. Drits
Affiliation:
Geological Institute of the USSR Academy of Sciences, Pyzhevsky per. 7, Moscow, USSR
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Abstract

Olique-texture electron diffraction examination of K-saturated dioctahedral smectites after 70–100 wetting-drying cycles allows the determination of cation distribution between trans and cis octahedra of the 2:1 layers. Studies of smectites with different compositions has revealed a wide variety of occupancies of the available octahedral sites.

Type
Research Article
Information
Clay Minerals , Volume 19 , Issue 2 , April 1984 , pp. 177 - 193
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1984

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References

Bailey, S.W. (1966) The status of clay mineral structures. Clays Clay Miner. 14, 1–23.CrossRefGoogle Scholar
Besson, G. (1980) Structure des smectites dioctahedrique, parametres conditionnant lesfautes d’ empilement desfeuillets. Thèse de Doctorat d'etat et Sciences Physiques, Orléans.Google Scholar
Besson, G. & Tchoubar, C. (1972) Détérmination du group de symmétrie du feuillet élémentaire de la beidellite. C.R. Acad. Sci. Paris 275, 633–636.Google Scholar
Besson, G., de la Calle, C., Rautureau, M., Tchoubar, C, Tsipursky, S.I. & Drits, V.A. (1982) X-ray and electron diffraction study of the structure of the Garfield nontronite. Proc. Seventh Int. Clay Conf., Bologna and Pavia. 29–40.Google Scholar
Bookin, A.S., Dainyak, L.G. & Drits, V.A. (1978) Interpretation of the Mössbauer spectra of layer silicates on the basis of the structural modelling. Phys. Chem. Miner. 3, 58–59.Google Scholar
Bookin, A.S., Dainyak, L.G. & Drits, V.A. (1979) Interpretation of the Mössbauer spectra of Fe3+-containing layer silicates on the basis of the structural modelling. Pp. 23–41 in: Cation Ordering in Structures of Minerals (L. I. Lapides, , editor). Nauka, Novosibirsk.Google Scholar
Boutouzova, G.Yu., Drits, V.A., Lisitsina, N.A. & Tsipursky, S.Y. (1979) The dynamics of the formation of clay minerals in ore-bearing sediments of the Atlantis II (Red Sea) (in Russian). Litologiya i poleznye iskopaemye 1,20–42.Google Scholar
Dainyak, L.G. (1980) The interpretation of the Mössbauer spectra of some Fe3+ -containing silicates on the basis of structural modelling (in Russian). Thèsis, Geological Institute, Academy of Sciences, Moscow.Google Scholar
Donnay, G., Donnay, J.D.H. & Takeda, H. (1964) Trioctahedral one layer micas. II. Prediction of the structure from composition and cell dimension. Acta Cryst. 17, 1374–1377.CrossRefGoogle Scholar
Drits, V.A. (1969) Some general remarks on the structure of trioctahedral micas. Proc. Int. Clay Conf, Tokyo, 51–59.Google Scholar
Drits, V.A. (1975) Structural and crystal-chemical features of layer silicates. Pp. 32–35 in: Crystal Chemistry of Minerals and Geological Problems (Kossovskaya, A. G., editor). Nauka, Moscow.Google Scholar
Drits, V.A. & Kossovskaya, A.G. (1980) Geological crystal chemistry of rock-forming dioctahedral smectites. Litologiya ipoleznye iskopayemye 1, 84–112.Google Scholar
Glaeser, R. & Méring, J. (1954) Isothermes d'hydration des montmorillonites biioniques (Na,Ca). Clay Miner. Bull. 2, 188–190.Google Scholar
Goodman, B.A., Russell, J.D. & Fraser, A.R. (1976) A Mössbauer and IR spectroscopic study of the structure of nontronite. Clays Clay Miner. 24, 53–59.Google Scholar
Guggenheim, S. & Bailey, S.W. (1975) Refinement of the margarite structure in subgroup symmetry. Am. Miner. 60, 1023–1029.Google Scholar
Güven, N. (1971) The crystal structure of 2M phengite and 2M1-muskovite. Z. Krist. 134, 487–490.Google Scholar
Güven, N., Pease, R.W. & Murr, L.E. (1977) Fine structure in the selected area electron diffraction patterns of beidellite. Clay Miner. 12, 67–74.Google Scholar
Mamy, J. & Gaultier, J.P. (1976) Les phenomènes de diffraction de rayonnements X et électronique per les reseaux atomiques: application à l'étude de l'ordre cristalline dans les miréraux argileux. Ann. Agronomiques 27, 1–16.Google Scholar
Méring, J. & Glaeser, R. (1954) Sur le rôle de la valence de cations échangeables dans la montmorillonite. Bull. Soc. Fr. Miner. Crist. 77, 519–522.Google Scholar
Méring, J. & Oberlin, A. (1971) Smectite. Pp. 193–229 in: The Electron-Optical Investigation ofClays (Card, J. A., editor). Mineralogical Society, London.Google Scholar
Radoslovich, E.W. & Norrish, K. (1962) The cell dimensions and symmetry of layer-lattice silicates. I. Some structural considerations. Am. Miner. 47, 599–616.Google Scholar
Radoslovich, E.W. & Burnham, C.W. (1964) Crystal structure of coexisting muscovite 2M1 and paragonite 2M1 . Carnegie Inst. Year Book 63, 232–234.Google Scholar
Rozenson, I & Heller-Kallai, I. (1977) Mössbauer spectra of dioctahedral smectites. Clays Clay Miner. 25, 94–101.Google Scholar
Tsipursky, S.I. & Drits, V.A. (1977) Effectiveness of the electronometric method of measuring the intensities at the electron diffraction structural studies. Izv. AN SSSR, Series Phys. 2263–2271.Google Scholar
Tsipursky, S.I., Drits, V.A. & Chekin, S.S. (1978) Revealing of the structural ordering of nontronites by oblique texture electron diffraction. Izv. AN SSSR, Ser. geol. 10, 105–113.Google Scholar
Zvyagin, B.B. & Pinsker, Z.G. (1949) Electron diffraction study of the montmorillonite structure. Dokl. Acad. Nauk SSSR. 68, 30–35.Google Scholar
Zvyagin, B.B. (1967) Electron Diffraction Analysis of Clay Mineral Structures. Plenum Press, New York.Google Scholar
Zvyagin, B.B., Vrublevskaya, Z.V., Zhoukhlistov, A.P., Sidorenko, O.V., Soboleva, S.V. & Fedotov, A.F. (1979) In: High Voltage Electron Diffraction Study of Layer Minerals (Drits, V. A., editor). Nauka, Moscow.Google Scholar