Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-24T02:28:14.493Z Has data issue: false hasContentIssue false
  • English
  • Français

Chemical and structural properties of clay minerals modified by inorganic and organic material

Published online by Cambridge University Press:  09 July 2018

T. J. Bandosz ,
J. Jagiełło ,
K. A. G. Amankwah  and
J. A. Schwarz
T. J. Bandosz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, NY 13244-1190, USA
J. Jagiełło
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, NY 13244-1190, USA
K. A. G. Amankwah
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, NY 13244-1190, USA
J. A. Schwarz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, NY 13244-1190, USA
Get access Rights & Permissions [Opens in a new window]

Abstract

Modification of clay minerals by exchange, intercalation, calcination and imbibition of organics followed by their polymerization and carbonization was studied. The surface properties of the clays were investigated by inverse gas chromatography at infinite dilution employing alkanes and alkenes as probes; the structural properties were measured directly by X-ray diffraction and inferred from the results of high pressure hydrogen adsorption. Calcination of pillared smectites prior to polymerization and carbonization of organic material in the interlayer space leads to a microporous “activated carbon” that demonstrates unique properties as an adsorbent for hydrogen, significantly different from clays that have not been calcined.

Type
Research Article
Information
Clay Minerals , Volume 27 , Issue 4 , December 1992 , pp. 435 - 444
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Agarwal, R.K. & Schwarz, J.A. (1988) Analysis of high-pressure adsorption of gases on activated carbon by potential theory. Carbon, 26, 873–887.Google Scholar
Barrer, R.M. (1978) Zeolites and Clay Minerals as Sorbents and Molecular Sieves. Academic Press, London.Google Scholar
Belyakova, L.D., Kiselev, A.V. & Soloyan, G.A. (1970) Specificity of adsorption and chromatographic separation of some cyclic olefins and aromatic hydrocarbons on barium sulfate. Chromatographia, 3, 254–;259.Google Scholar
Bezus, A.G., Kiselev, A.V., Sedlacek, Z. & Du, P.O. (1971) Adsorption of ethane and ethylene on X-zeolites containing Li+, Na+, K+, Rb+ and Cs+ cations. Trans, Faraday Soc. I, 67, 468–;482.Google Scholar
Brindley, G.W. & Sempels, R.E. (1977) Preparation and properties of some hydroxyaluminium beidellites. Clay Miner., 12, 229–236.Google Scholar
Brindley, G.W. & Yamanaka, S. (1979) A study of hydroxychromium montmorillonites and the form of the hydroxy-chromium polymers. Am. Miner., 64, 830–835.Google Scholar
Carrott, P.J.M. & Sing, K.S.W. (1987) Gas chromatographic study of microporous carbon. J. Chromatography,, 406, 139–144.Google Scholar
Conder, J.R. & Young, C.L. (1979) Physicochemical Measurement by Gas Chromatography. John Wiley & Sons, New York.Google Scholar
Diddams, P.A., Thomas, J.T., Jones, W., Ballantine, J.A. & Purnell, J.H. (1984) Synthesis, characterization, and catalytic activity of beidellite-montmorillonite layered silicas and their pillared analogues. J. Chem. Soc., Chem. Commun., 20, 1340–1342.Google Scholar
Dorris, G.M. & Gray, D.G. (1980) Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibres. J, Coll. Inter/. Sci., 77, 353–362.Google Scholar
Everett, D.H. & Powl, J.C. (1976) Adsorption in slit-like and cylindrical micropores in the Henry's law region. Trans. Soc. Farad., 72, 619–;636.Google Scholar
Jagiello, J., Bandosz, T.J., & Schwarz, J.A. (1992) Application of inverse gas chromatography at infinite dilution to study the effects of oxidation of activated carbons. Carbon,, 30, 63–69.Google Scholar
Kitutchi, E., Matsuda, T., Ueda, I. & Morita, Y. (1985) Conversion of trimethylbenzenes over montmorillonites pillared by aluminium and zirconium oxides. Appl. Cat., 16, 401–;410.Google Scholar
Kiselev, A.V. & Yashin, Y.I. (1969) Gas Adsorption Chromatography. Plenum Press, New York.Google Scholar
Lahav, M., Shani, U. & Shabtai, J. (1978) Cross-linked smectites, I. Synthesis and properties of hydroxy-aluminum- montmorillonite. Clays Clay Miner., 26, 107–115.Google Scholar
Occelli, M.L. & Tindwa, P.M. (1983) Physicochemical properties of montmorillonite interlayered with cationic oxyaluminum pillars. Clays Clay Miner., 31, 22–28.Google Scholar
Papirer, E., Vidal, A. & Balard, H. (1989) Inverse Gas Chromatography. Characterization of Polymers and Other Materials,pp. 248–;261. American Chemical Soc., Washington.Google Scholar
Pekala, R.W. & Hopper, R.W. (1987) Low-density microcellular carbon foams. J. Mater. ScL, 22, 1840–1844.Google Scholar
Pinnavaia, T.J. (1983) Intercalated clay catalysts. Science,, 220, 365–371.Google Scholar
Sidqi, M., Ligner, G., Jagiello, J., Balard, H. & Papirer, E. (1989) Characterization of specific interaction capacity of solid surfaces by adsorption of alkanes and alkenes. Part I: Adsorption on open surface. Chromatographia,, 28, 588–592.Google Scholar
Sonobe, N., Kyotani, T. & Tomita, A. (1990) Carbonization of polyfurfuryl alcohol and polyvinyl acetate between the lamellae of montmorillonite. Carbon,, 28, 483–;488.Google Scholar
Vaughan, D.E.W., Lussier, R.G. & Magee, J.S. Jr. (1979) Pillared interlayered clay materials useful as catalysts and sorbents. U.S. Pat., 4, 176,090.Google Scholar
Zyla, M. & Bandosz, T. (1987) Montmorillonite from Miiowice intercalated with hydroxy-aluminium oligocations as vapour and gas adsorbent. Min. Polon., 18, 39–50.Google Scholar