Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-26T09:46:42.265Z Has data issue: false hasContentIssue false
  • English
  • Français

An 57Fe Mössbauer spectroscopic and X-ray diffraction study of New Zealand glauconites

Published online by Cambridge University Press:  09 July 2018

C. M. Cardile  and
I. W. M. Brown
C. M. Cardile
Affiliation:
Chemistry Division, Department of Scientific and Industrial Research, Private Bag, Petone, New Zealand
I. W. M. Brown
Affiliation:
Chemistry Division, Department of Scientific and Industrial Research, Private Bag, Petone, New Zealand
Get access Rights & Permissions [Opens in a new window]

Abstract

A comprehensive Mössbauer spectroscopic and X-ray diffraction study of six purified glauconites is presented. The Mössbauer spectra were computer-fitted with three Fe3+ and three Fe2+ doublets, both Fe species occupying the trans-OH and two cis-OH octahedral sites. In addition, a seventh smaller doublet is assigned to Fe3+ in tetrahedral coordination. It has been shown that an increasing IVFe3+ content directs VIFe3+ substitution to the cis-OH octahedrally coordinated sites. A correlation between the d(060) reflection and elemental composition is demonstrated.

Type
Research Article
Information
Clay Minerals , Volume 23 , Issue 1 , March 1988 , pp. 13 - 25
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bancroft, G.M. (1913) Mössbauer Spectroscopy: An Introduction for Inorganic Chemists and Geochemists, p. 32. McGraw-Hill, London.Google Scholar
Besson, G., Mifsud, A., Tchoubar, C. & Mering, J. (1974) Order and disorder relationships in the distribution of the substitutions in smectites, illites and vermiculites. Clays Clay Miner. 22, 379–384.Google Scholar
Besson, G., Bookin, A.S., Dainyak, L.G., Rautureau, N., Tsipursky, S.I., Tchoubar, C. & Drits, V.A. (1983) Use of diffraction and Mössbauer methods for the structural and crystallo-chemical characterization of nontronites. J. Appl. Cryst. 16, 374–383.Google Scholar
Brigatti, M.F. (1983) Relationships between composition and structure in Fe-rich smectites. Clay Miner. 18, 177–186.CrossRefGoogle Scholar
Cardile, C.M. (1987) Structural studies of montmorillonites by 57Fe Mössbauer spectroscopy. Clay Miner. 22, 387–394.CrossRefGoogle Scholar
Cardile, C.M. (1988) Structural site occupation of iron within 2:1 dioctahedral phyllosilicates studied by 57Fe Mössbauer spectroscopy. Hyp. Int. (in press).CrossRefGoogle Scholar
Cardile, C.M., Childs, C.W. & Whitton, J.S. (1987) The effect of citrate/bicarbonate/dithionite treatment on standard and soil smectites as evidenced by 57Fe Mössbauer spectroscopy. Aust. J. Soil Res. 25,145-154.Google Scholar
Cardile, C.M. & Johnston, J.H. (1985) Structural studies of nontronites with different iron contents by 57Fe Mössbauer spectroscopy. Clays Clay Miner. 33, 295–300.Google Scholar
Cardile, C.M. & Johnston, J.H. (1986) A 57Fe Mössbauer spectroscopic study of montmorillonites: A new interpretation. Clays Clay Miner. 34, 307–313.Google Scholar
Cardile, C.M. & Slade, P.G. (1987) Structural study of a benzidine-vermiculite intercalate having a high tetrahedral-iron content by 57Fe Mössbauer spectroscopy. Clays Clay Miner. 35, 203–207.Google Scholar
Cardile, C.M. & Slade, P.G. (1988) Structural studies of vermiculites with different iron contents by 57Fe Mössbauer spectroscopy. N. 3b. Miner. Mh. (in press).Google Scholar
De Grave, E., Vandenbruwaene, J. & Elewaute, E. (1985) An 57Fe Mössbauer effect study on glauconites from different locations in Belgium and northern France. Clay Miner. 20, 171–179.CrossRefGoogle Scholar
Dyar, M.D. & Burns, R.G. (1986) Mössbauer spectral study of ferruginous one-layer trioctahedral micas. Am. Miner. 71, 955–965.Google Scholar
Goodman, B.A. (1976) The effect of lattice substitutions on the derivation of quantitative site populations from the Mössbauer spectra of 2:1 layer lattice silicate. J. Physique C6 37, 819–823.Google Scholar
Goodman, B.A. (1978) The Mössbauer spectra of nontronites: Consideration of an alternative assignment. Clays Clay Miner. 36, 176–177.Google Scholar
Goodman, B.A., Russell, J.D., Fraser, A.R. & Woodhams, F.W.D. (1976) A Mössbauer and I.R. spectroscopic study of the structure of nontronite. Clays Clay Miner. 24, 53–59.Google Scholar
Heller-Kallai, L. & Rozenson, I. (1981) The use of Mössbauer spectroscopy of iron in clay mineralogy. Phys. Chem. Miner. 7, 223–238.Google Scholar
Ingalls, R. (1964) Electric-field gradient tensor in ferrous compounds. Phys. Rev. 133, 787–795.Google Scholar
Johnston, J.H. & Cardile, C.M. (1985) Iron sites in nontronite and the effect of interlayer cations from Mössbauer spectra. Clays Clay Miner. 33, 21–30.CrossRefGoogle Scholar
Johnston, J.H. & Cardile, C.M. (1987) Iron substitution in montmorillonite, illite and glauconite by 57Fe Mössbauer spectroscopy. Clays Clay Miner. 35, 170–176.Google Scholar
Kotlicki, A., Szczyrba, J. & Wiewiora, A. (1981) Mössbauer study of glauconites from Poland. Clay Miner. 16, 221–230.CrossRefGoogle Scholar
McConchie, D.M., Ward, J.B., McCann, J.H. & Lewis, D.W. (1979) A Mössbauer investigation of glauconite and its geological significance. Clays Clay Miner. 27, 339–348.Google Scholar
Mehra, O.P. & Jackson, M. (1960) Iron oxides removal from soils and clays by a dithionite-citrate system buffered with sodium carbonate. Clays Clay Miner. 7, 317–327.Google Scholar
Mineeva, R.M. (1978) Relationship between Mössbauer spectra and defect structure in biotites from electric field gradient calculations. Phys, Chem. Miner. 2, 267–277.Google Scholar
Odom, I.E. (1976) Microstructure, mineralogy and chemistry of Cambrian glauconite pellets and glauconite, central U.S.A. Clays Clay Miner. 24, 232–238.Google Scholar
Odom, I.E. (1984) Glauconite and celadonite minerals. Pp. 545-572 in: Reviews in Mineralogy: Vol. 13. Micas (S. W. Bailey, editor). Mineralogical Society of America.Google Scholar
Robert, M. (1973) The experimental transformation of mica toward smectite; relative importance of total charge and tetrahedral substitution. Clays Clay Miner. 21, 167–174.Google Scholar
Rolf, R.M., Kimball, C.W. & Odom, I.E. (1977) Mössbauer characteristics of Cambrian glauconite, central U.S.A. Clays Clay Miner. 25, 131–137.CrossRefGoogle Scholar
Ross, C. A.M. & Longworth, G. (1980) Mössbauer study of the attenuation of iron in an irrigated greensand lysimeter. Clays Clay Miner. 28, 43–49.CrossRefGoogle Scholar
Rozenson, I. & Heller-Kallai, L. (1977) Mössbauer spectra of dioctahedral smectites. Clay Clay 25, 94–101.Google Scholar
Rozenson, I. & Heller-Kallai, L. (1978) Mössbauer spectra of glauconite reexamined. Clays Clay Miner. 26, 173–175.Google Scholar
Russell, J.D. & Clark, D.R. (1978) The effect of Fe-for-Si substitution on the ^-dimension of nontronite. Clay Miner. 13, 133-136.Google Scholar
Slonimskaya M.V., , Besson, G., Dainyak, L.G., Tchoubar, C. & Drits, V.A. (1986) Interpretation of the IR spectra of celadonites and glauconites in the region of OH-stretching frequencies. Clay Miner. 21, 377388.Google Scholar
Thompson, G.R. & Hower, J. (1975) The mineralogy of glauconite. Clays Clay Miner. 23, 289–300.Google Scholar
Tsipursky, S.I. & Drits, V.A. (1984) The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction. Clay Miner. 19, 177–193.Google Scholar