Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-22T19:54:30.843Z Has data issue: false hasContentIssue false
  • English
  • Français

Ammonium illite from anchimetamorphic shales associated with anthracite in the Zemplinicum of the western Carpathians

Published online by Cambridge University Press:  09 July 2018

V. Šucha ,
I. Kraus  and
J. Madejová
V. Šucha
Affiliation:
Department of Geology of Mineral Deposits, Comenius University, Mlynská dolina G, 842 15 Bratislava, Slovakia
I. Kraus
Affiliation:
Department of Geology of Mineral Deposits, Comenius University, Mlynská dolina G, 842 15 Bratislava, Slovakia
J. Madejová
Affiliation:
Department of Geology of Mineral Deposits, Comenius University, Mlynská dolina G, 842 15 Bratislava, Slovakia Institute of Inorganic Chemistry, Slovak Academy of Science, Dúbravská cesta 9, Bratislava, Slovakia
Get access Rights & Permissions [Opens in a new window]

Abstract

Ammonium-rich illite was identified in shales from the meta-anthracite coalfields of Zemplinicum (the Western Carpathians) together with K-illite and Na-illite using X-ray diffraction (XRD), infrared absorption and chemical analyses. The NH4-abundance in illite was quantified by the position of the 005 XRD reflection and by chemical analysis. Ammonium-bearing illite was probably formed in the temperature interval 200-270°C by illitization of a kaolinite precursor in the presence of ammonium.

Type
Research Article
Information
Clay Minerals , Volume 29 , Issue 3 , September 1994 , pp. 369 - 377
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Baronnet, A. (1982) Ostwald ripening in solution. The case of calcite and mica. Estudios Geologicos 38, 185–198.Google Scholar
Bouška, V. (1981) Geochemistry of Coal. Elsevier Scientific Publishing Company, Amsterdam.Google Scholar
Bremner, J.M. (1965) Inorganic forms of nitrogen. Pp. 1179–1237 in: Methods of Soil Analysis (Black, C.A., editor). Am. Soc. Agron., Madison, Wisconsin.Google Scholar
Chourabi, B. & Fripiat, J.J. (1981) Determination of tetrahedral substitutions and interlayer surface heterogeneity from vibrational spectra of ammonium in smectites. Clays Clay Miner. 29, 260–268.CrossRefGoogle Scholar
Compton, J.S., Williams, L.B. & Ferrell, Jr.R.E. (1992) Mineralization of organogenic ammonium in the Monterey Formation, Santa Maria and San Joaquin basins, California, USA. Geochim. Cosmochim. Ada 56, 1979–1991.Google Scholar
Cooper, J.E. & Abedin, K.Z. (1981) The relationship between fixed ammonium-nitrogen and potassium in clays from a deep well on the Texas Gulf Coast. Tex. J. Sci. 33, 103–111.Google Scholar
Daniels, E.I. & Altaner, S.P. (1990) Clay mineral authigenesis in coal and shale from the Anthracite region, Pennsylvania. Am. Miner. 75, 103–111.Google Scholar
Dopita, M. & Králík, I. (1977) Coal Tonsteins of Ostrava-Karviná Region. OKD Press (in Czech).Google Scholar
Eberl, D.D. & Środoń, J. (1988) Ostwald ripening and interparticle diffraction effects for illite crystals. Am. Miner. 73, 1335–1345.Google Scholar
Eberl, D.D., Środoń, J., Kralik, M., Taylor, B.E. & Peterman, Z.E. (1990) Ostwald ripening of clays and metamorphic minerals. Science 248, 474–477.CrossRefGoogle Scholar
Frey, M. (1987) Very low-grade metamorphism of clastic sedimentary rocks. Pp. 9–58 in: Low Temperature Metamorphism (Frey, M., editor), Blackie, London.Google Scholar
Higashi, S. (1971) Dioctahedral mica minerals with ammonium ions. Min. J. 9, 16–27.Google Scholar
Higashi, S. (1982) Tobelite, a new ammonium dioctahedral mica. Min. J. 11, 138–146.CrossRefGoogle Scholar
Juster, T.C., Brown, P.E. & Bailey, S.W. (1987) NH4 bearing illite in very low grade metamorphic rocks associated with coal, Northeastern Pennsylvania. Am. Miner. 72, 555–565.Google Scholar
Kisch, H.J. (1983) Mineralogy and petrology of burial diagenesis (burial metamorphism) and incipient meta-morphism in clastic rocks. Pp. 289–494 in: Diagenesis in Sediments and Sedimentary Rocks (Larsen, G. & Chilingar, G.V., editors). Developments in Sedimentology 25B, Elsevier, New York.Google Scholar
Klin, J. & Jungten, H. (1971) Studies on the emission of elemental nitrogen from coals of different rank and its release under geochemical conditions. Pp. 647–656. in: Advances in Organic Geochemistry 1971 (Gaertner, H.R. & Wehner, H., editors), Pergamon Press, Oxford.Google Scholar
Kozáč , J., Očenaáš, D. & Derco, J. (1977) Ammonium hydromica from Vihorlat Mts. Mineralia Slovaca 9, 479–494.Google Scholar
Milička, J., Francu, J., Horváth, I. & Toman, B. (1991) Optical, structural and thermal characterization of meta-anthracite from Zemplinikum, West Carpathians. Geo-logica Carpathica 45, 53–58.Google Scholar
Reynolds, R.C. Jr. (1985) NEWMOD, a computer program for the calculation of basal X-ray diffraction intensities and mixed-layered clays. R.C. Reynolds Jr., Hanover, New Hampshire.Google Scholar
Rudinec, R. (1980) Possibilities of oil and gas occurrences in the pre-Neogene basement of the East Sloakia Neogene Basin. Mineralia Slovaca 12, 507–531.Google Scholar
Środorń, J. (1979) Correlation between coal and clay diagenesis in the Carboniferous of Upper Silesian Coal Basin. Proc. Int. Clay Conf. Oxford, 251-260.Google Scholar
Środorń, J. (1984) X-ray identification of illitic materials. Clays Clay Miner. 32, 337–349.CrossRefGoogle Scholar
Środorń, J., Elsass, F., Mchardy, W.J. & Morgan, D.J. (1992) Chemistry of illite/smectite inferred from TEM measurements of fundamental particles. Clay Miner. 27, 137–158.CrossRefGoogle Scholar
Šmeral, J. & Urbánek, J. (1986) Organic and mineral carbon determination in a single analytical cycle. Zemný Plyn Nafta (Hodonín) 31/2, 199–203 (in Czech).Google Scholar
Šucha, V. & Eberl, D.D. (1992) Burial metamorphism of Permian sediments in the Northern Gemeric and Hronic units, West Carpathians. Mineralia Slovaca 24, 399–405.Google Scholar
Šucha, V. & Širáñová, V. (1991) Potassium and ammonium fixation in smectites by wetting and drying. Clays Clay Miner. 39, 556–559.CrossRefGoogle Scholar
Šucha, V., Širáñová, V. & Toman, B. (1990) Illite as an indicator of burial metamorphism of Permian sediments in northern Gemericum, West Carpathians. Geologica Carpathica 41, 540–560.Google Scholar
Vozárová, A. & Vozár, J. (1988) Late Paleozoic in West Carpathians. GÚDŠ, Bratislava.Google Scholar
Williams, L.B. & Ferrell, R.E. Jr. (1991) Ammonium substitution in illite during maturation of organic matter. Clays Clay Miner. 39, 400–408.Google Scholar