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The Adsorption of Aromatic, Heterocyclic and Cyclic Ammonium Cations by Montmorillonite

Published online by Cambridge University Press:  09 July 2018

E. F. Vansant  and
J. B. Uytterhoeven
E. F. Vansant
Affiliation:
Centrum voor Oppervlaktescheikunde en Colloïdale Scheikunde, De Croylaan 42, B-3030 Heverlee, Belgium
J. B. Uytterhoeven
Affiliation:
Centrum voor Oppervlaktescheikunde en Colloïdale Scheikunde, De Croylaan 42, B-3030 Heverlee, Belgium
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Abstract

The adsorption of organic ions derived from ammonium, containing aromatic and saturated rings, was studied using different techniques. The ions with acid character produced a complicated set of reactions including aluminium extraction, proton adsorption, a real ion-exchange with the organic ions and an excess adsorption of ammonium salts. With non-acidic compounds only a stoichiometric ion-exchange process was observed. X-ray diffraction and infrared spectroscopy were used to determine the orientation of the organic ions and to characterize the nature of the co-adsorbed organic material.

Type
Research Article
Information
Clay Minerals , Volume 10 , Issue 2 , December 1973 , pp. 61 - 69
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1973

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References

Cook, D. (1961) Can. J. Chem. 39, 2009.Google Scholar
Cowan, G.T. & White, D. (1952) Trans. Faraday Soc. 54, 691.Google Scholar
Farmer, V.C. & Mortland, M.M. (1966) J. Chem. Soc. A, 344.Google Scholar
Gaines, G.L. & Thomas, H.C. (1953) J. Chem. Phys. 21, 714.Google Scholar
Greene-Kelly, R. (1955) Trans. Faraday Soc. 51, 412 and 425.Google Scholar
Greene-Kelly, R. (1956) J. Phys. Chem. 60, 808.Google Scholar
Greenland, D.J. (1965) Soils Fertil. 28, 415.Google Scholar
Mortland, M.M. (1970) Adv. Agron. 22, 75.Google Scholar
Swoboda, A.R. & Kunze, G.W. (1965) Clays Clay Miner. In: Proc. 13th Conf. p. 277. Pergamon Press, London.Google Scholar
Swoboda, A.R. & Kunze, G.W. (1968) Proc Soil Sci. Soc. Am. 32, 806.CrossRefGoogle Scholar
Theng, B.K.G., Greenland, D.J. & Quirk, J.P. (1967) Clay Miner. 7, 1.CrossRefGoogle Scholar
Weast, R.C. (1966) Handbook of Chemistry and Physics. The Chemical Rubber Co. Cleveland, Ohio.Google Scholar