Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-23T16:17:58.148Z Has data issue: false hasContentIssue false
  • English
  • Français

Solid-state mechanochemical activation of clay minerals and soluble phosphate mixtures to obtain slow-release fertilizers

Published online by Cambridge University Press:  02 January 2018

Roger Borges ,
Silvio F. Brunatto ,
Alexandre A. Leitão ,
Gustavo S. G. De Carvalho  and
Fernando Wypych
Roger Borges
Affiliation:
CEPESQ – Research Center in Applied Chemistry, Department of Chemistry, Federal University of Paraná – P.O. Box 19032, 81531-980 – Curitiba, PR, Brazil
Silvio F. Brunatto
Affiliation:
Department of Mechanical Engineering, Federal University of Paraná – P.O. Box 19081, 81531-980 – Curitiba, PR, Brazil
Alexandre A. Leitão
Affiliation:
Group of Physico-chemistry of Solids and Interfaces, Department of Chemistry, Federal University of Juiz de Fora, 36036-330, Juiz de Fora, MG, Brazil
Gustavo S. G. De Carvalho
Affiliation:
Group of Physico-chemistry of Solids and Interfaces, Department of Chemistry, Federal University of Juiz de Fora, 36036-330, Juiz de Fora, MG, Brazil
Fernando Wypych*
Affiliation:
CEPESQ – Research Center in Applied Chemistry, Department of Chemistry, Federal University of Paraná – P.O. Box 19032, 81531-980 – Curitiba, PR, Brazil
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

This work describes the development of potential multi-element slow-release fertilizers obtained by mechanochemical activation of mixtures of kaolinite and ammonium or potassium monohydrogen phosphates. Preliminary results of talc amorphization have also been included. The methodology consists of milling the materials in a high-energy ball mill, where the influence of rotation and time of milling were investigated. The samples were characterized by XRD, FTIR, TGA/DTA, SEM and MAS-NMR. The experimental results explain the slow-release behaviour of the amorphous nanostructured materials in aqueous suspensions, especially the MASNMR spectra, which showed the changes in the chemical environment of the elements analysed. The materials displayed slow-release behaviour for phosphates probably because the aluminium ions in the mineral structure interact more thoroughly with phosphate than potassium or ammonium. Nevertheless, in general, all of the nutrients were released slowly.

Keywords

Mechanochemical activationmineral fertilizersclay mineralmacronutrients
Type
Research Article
Information
Clay Minerals , Volume 50 , Issue 2 , June 2015 , pp. 153 - 162
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aglietti, E.F. (1994) The effect of dry grinding on the structure of talc. Applied Clay Science, 9, 139–147.CrossRefGoogle Scholar
Bhardwaj, D., Sharma, M., Sharma, P. & Tomar, R. (2012) Synthesis and surfactant modification of clinoptilolite and montmorillonite for the removal of nitrate and preparation of slow release nitrogen fertilizer. Journal of Hazardous Materials, 227, 292–300.CrossRefGoogle ScholarPubMed
Fernandez, R., Martirena, F. & Scrivener, K.L. (2011) The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite. Cement and Concrete Research, 41, 113–122.CrossRefGoogle Scholar
Frost, R.L., Mako, E., Kristó, F.J. & Horváth, E. (2003) A DRIFT spectroscopic study of potassium acetate intercalated, mechanochemically activated kaolinite. Spectrochimica Acta Part A, 59, 1183–1194.CrossRefGoogle ScholarPubMed
Frost, R.L., Mako, E., Kristó, F.J., Horváth, E. & Kloprogge, J.T. (2001) Modification of kaolinite surfaces by mechanochemical treatment. Langmuir, 17, 4731–4738.CrossRefGoogle Scholar
Fukamachi, C.R.B., Wypych, F. & Mangrich, A.S. (2007) Use of Fe3+ion probe to study the stability of ureaintercalated kaolinite by electron paramagnetic resonance. Journal of Colloid and Interface Science, 313, 537–541.CrossRefGoogle Scholar
Galhardo, C.X. & Masini, J.C. (2000) Spectrophotometric determination of phosphate and silicate bysequential injection using molybdenum blue chemistry. Analytica Chimica Acta, 417, 191–200.CrossRefGoogle Scholar
Garcia, F.G., Abrio, M.T.R. & Rodriguez, M.G. (1991) Effects of dry grinding on two kaolins of different degrees of crystallinity. Clay Minerals, 26, 549–565.CrossRefGoogle Scholar
Harfmann, R.G. & Crouch, S.R. (1989) Kinetic study of Berthelot reaction steps in the absence and presence of coupling reagents. Talanta, 36, 261–269.CrossRefGoogle ScholarPubMed
Holler, F.J., Skoog, D.A. & Crouch, S.R. (2009) Princípios de Análise Instrumental, pp. 1–1056.Google Scholar
Bookman, Porto Alegre. Hongbin, T. (2010) Preparation of plate-like a-Al2O3 particles in Na2SO4 flux using kaolin as the starting material. Clay Minerals, 45, 503–506.Google Scholar
Hrachová, J., Komadel, P. & Fajnor, V.S. (2007) The effect of mechanical treatment on the structure of montmorillonite. Materials Letters, 61, 3361–3365.CrossRefGoogle Scholar
Kristó, F.E., Juhász, A.Z. & Vassányi, I. (1993) The effect of mechanical treatment on the crystal structure and thermal behavior of kaolinite. Clays and Clay Minerals, 41, 608–612.CrossRefGoogle Scholar
Li, Y. & Zhang, J. (1999) Agricultural diffuse pollution from fertilizers and pesticides in China. Water Science and Technology, 39, 25–32.CrossRefGoogle Scholar
Lombardi, K.C., Guimaráes, J.L., Mangrich, A.S., Mattoso, N., Abatte, M., Schreiner, W.H. & Wypych, F. (2002) Structural and morphological characterization of PP-0559 kaolinite from the Brazilian Amazon region. Journal of the Brazilian Chemical Society, 13, 270–275.CrossRefGoogle Scholar
Lookman, R., Grobet, P., Merckx, R. & Riemsdijk, W.H.V. (1977) Application of 31P and 27Al MAS NMR for phosphate speciation studies in soil and aluminium hydroxides: promises and constraints. Geoderma, 80, 369–388.CrossRefGoogle Scholar
Makó, É., Kovács, A., Horváth, E. & Kristó F.J. (2014) Kaolinite-potassium acetate and halloysite-potassium acetate complexes prepared by mechanochemical, solution and homogenization techniques: a comparative study. Clay Minerals, 49, 457–471.CrossRefGoogle Scholar
McDowell, R. & Sharpley, A.N. (2001) Phosphorus losses in subsurface flow before and after manure application to intensively farmed land. Science of the Total Environment, 278, 113–125.CrossRefGoogle ScholarPubMed
Mendelovici, E. (2001) Selective mechanochemical reactions on dry grinding structurally different silicates. Journal of Materials Science Letters, 20, 81–83.CrossRefGoogle Scholar
Miller, J.G. & Oulton, T.D. (1970) Prototropy in kaolinite during percussive grinding. Clays and Clay Minerals, 18, 313–323.CrossRefGoogle Scholar
Mingelgrin, U., Kliger, L., Gal, M. & Saltzman, S. (1978) The effect of grinding on the structure and behavior of bentonites. Clays and Clay Minerals, 26, 299–307.CrossRefGoogle Scholar
Patton, C.J. & Crouch, S.R. (1977) Spectrophotometric and kinetics investigation of the Berthelot reaction for the determination of urea. Analytical Chemistry, 49, 464–469.CrossRefGoogle Scholar
Petrovic, L.F., Gvozdenovic, L.K. & Antonic, S.E. (2002) The effects of the fine grinding on the physicochemical properties and thermal behavior of bentonite clay. Journal of the Serbian Chemical Society, 67, 753–760.CrossRefGoogle Scholar
Schreiner, W.H., Lombardi, K.C., Oliveira, A.J.A., Mattoso, N., Abatte, M., Wypych, F. & Mangrich, A.S. (2002) Paramagnetic anisotropy of a natural kaolinite and its modification by chemical reduction. Journal of Magnetism and Magnetic Materials, 241, 422–429.CrossRefGoogle Scholar
Searcy, R.L., Reardon, J.E. & Foreman, J.A. (1967) A new photometric method for serum urea nitrogen determination. The American Journal of Medical Technology, 33, 15–20.Google Scholar
Shaviv, A. (2001) Advances in Controlled-release Fertilizers, pp.1–49. Academic Press Inc., San Diego.CrossRefGoogle Scholar
Solihin, , Zhang, Q., Tongamp, W. & Saito, F. (2010) Mechanochemical route for synthesizing KMgPO4 and NH4MgPO4 for application as slow release fertilizers. Industrial & Engineering Chemistry Research, 49, 2213–2216.CrossRefGoogle Scholar
Solihin, , Zhang, Q., Tongamp, W. & Saito, F. (2011) Mechanochemical synthesis of kaolin–KH2PO4 and kaolin–NH4H2PO4 complexes for application as slow release fertilizer. Powder Technology, 212, 354–358.CrossRefGoogle Scholar
Sun, D., Li, B., Li, Y., Yu, C., Zhang, B. & Fei, H. (2011) Characterization of exfoliated/delamination kaolinite. Materials Research Bulletin, 46, 101–104.CrossRefGoogle Scholar
Tong, Z., Yuhai, L., Shihuo, Y. & Zhongvib, H. (2009) Superabsorbent hydrogels as carriers for the controlled release of urea: Experiments and a mathematical model describing the release rate. Biosystems Engineering, 102, 44–50.Google Scholar
Vizcayno, C., Gutiérrez, R.M., Castello, R., Rodriguez, E. & Guerrero, C.E. (2010) Pozzolan obtained by mechanochemical and thermal treatments of kaolin. Applied Clay Science, 49, 405–413.CrossRefGoogle Scholar
Wang, P., Yang, D., Hu, J., Xu, J. & Lu, G. (2013) Synthesis of SAPO-34 with small and tunable crystallite size by two-step hydrothermal crystallization and its catalytic performance for MTO reaction. Catalysis Today, 212, 62.e1–62.e8.CrossRefGoogle Scholar
Wu, L., Liu, M. & Liang, R. (2008) Preparation and properties of a double-coated slow-release NPK compound fertilizer with superabsorbent and waterretention. Bioresource Technology, 99, 547–554.CrossRefGoogle Scholar
Wypych, F. (2004) Chemical modification of clay surfaces. Pp. 1–56 in: Clay Surfaces – Fundamentals and Applications (F. Wypych & K.G. Satyanarayana, editors). Academic Press, Amsterdam.Google Scholar
Yariv, S. & Lapides, I. (2000) The effect of mechanochemical treatments on clay minerals and the mechanochemical adsorption of organic materials onto clay minerals. Journal of Materials Synthesis and Processing, 8, 223–233.CrossRefGoogle Scholar
Yariv, S. & Shoval, S. (1975) The nature of the interaction between water molecules and kaolin-like layers in hydrated halloysite. Clays and Clay Minerals, 23, 473–474.CrossRefGoogle Scholar
Zhang, Q.W., Solihin, & Saito, F. (2009) Mechanochemical synthesis of slow-release fertilizers through incorporation of alumina composition into potassium/ammonium phosphates. Journal of the American Ceramic Society, 92, 3070–3073.CrossRefGoogle Scholar
Zhou, D., Xu, J., Yu, J., Chein, L., Deng, F. & Xu, R. (2006) Solid-state NMR spectroscopy of anionic framework aluminophosphates: A new method to determine the Al/P ratio. The Journal of Physical Chemistry B, 110, 2131–2137.CrossRefGoogle Scholar