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Selection of suitable bentonite and the influence of various acids on the preparation of a special clay for the removal of trace olefins from aromatics

Published online by Cambridge University Press:  01 December 2021

Hadi Rouhani ,
Fatola Farhadi Open the ORCID record for Fatola Farhadi [Opens in a new window] ,
Mahsa Akbari Kenari ,
Effat Eskandari Open the ORCID record for Effat Eskandari [Opens in a new window]  and
Seeram Ramakrishna Open the ORCID record for Seeram Ramakrishna [Opens in a new window]
Hadi Rouhani
Affiliation:
Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
Fatola Farhadi
Affiliation:
Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
Mahsa Akbari Kenari
Affiliation:
Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran
Effat Eskandari
Affiliation:
Department of Geology, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran
Seeram Ramakrishna*
Affiliation:
Center for Nanotechnology and Sustainability, Department of Mechanical Engineering, National University of Singapore, Singapore117581, Singapore
*
*E-mail: [email protected]
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Abstract

Acid-activated clays are inexpensive materials that are used extensively in the removal of unsaturated compounds on an industrial scale. The performance of bentonitic clays in removing these compounds relies heavily on the types of raw clays and acids used in the activation process. In this work, we report on the removal of olefins from aromatic streams by bentonitic clays activated via two different routes. After preliminary tests of four different natural clays, the best clay was selected in terms of it having high swelling index, cation-exchange capacity, specific surface area and suspension stability values. Activation was achieved with hydrochloric acid (HCl) and sulfuric acid (H2SO4), and olefin removal was evaluated after holistic clay characterization by means of X-ray diffraction, X-ray fluorescence, Brunauer–Emmett–Teller (BET) specific surface area analysis, ζ-potential analysis, Fourier-transform infrared (FTIR) spectroscopy after treatment with pyridine, scanning electron microscopy and transmission electron microscopy. The increased basal spacing, replacement of H+ with interlayer cations and retained structural stability of the clay after acid treatment contributed to the improvement of olefin removal for HCl-activated clay. The HCl-activated clay was more efficient in terms of olefin removal than its H2SO4-activated counterpart, removing up to 90% of olefin components after 40 h. Based on pyridine-FTIR spectra and quantitative measurement of the acidic properties of the samples, HCl treatment increased the total number acid sites (Brønsted and Lewis) by approximately ninefold compared to the pristine natural clay and by approximately fourfold compared to the H2SO4-activated clay.

Keywords

acid-activated bentoniteacid treatmentbentoniteinterlayer cationsolefin removal
Type
Article
Information
Clay Minerals , Volume 56 , Issue 3 , September 2021 , pp. 185 - 196
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

‡

These authors contributed equally to this work

Associate Editor: Miroslav Pospíšil

References

Abdellaoui, Y., Olguín, M.T., Abatal, M., Ali, B., Méndez, S.E.D. & Santiago, A.A. (2019) Comparison of the divalent heavy metals (Pb, Cu and Cd) adsorption behavior by montmorillonite-KSF and their calcium-and sodium-forms. Superlattices Microstructures, 127, 165–175.CrossRefGoogle Scholar
Abuchenari, A., Hardani, K., Abazari, S., Naghdi, F., Keleshteri, M.A., Jamavari, A. & Chahardehi, A.M. (2020) Clay-reinforced nanocomposites for the slow release of chemical fertilizers and water retention. Journal of Composites Compounds, 2, 85–91.CrossRefGoogle Scholar
Al-Essa, K. (2018) Activation of Jordanian bentonite by hydrochloric acid and its potential for olive mill wastewater enhanced treatment. Journal of Chemistry, 2018, 8385692.CrossRefGoogle Scholar
Amari, A., Gannouni, H., Khan, M.I., Almesfer, M.K., Elkhaleefa, A.M. & Gannouni, A. (2018) Effect of structure and chemical activation on the adsorption properties of green clay minerals for the removal of cationic dye. Applied Sciences, 8, 2302.CrossRefGoogle Scholar
Andrini, L., Toja, R.M., Gauna, M.R., Conconi, M.S., Requejo, F.G. & Rendtorff, N. (2017) Extended and local structural characterization of a natural and 800°C fired Na-montmorillonite–Patagonian bentonite by XRD and Al/Si XANES. Applied Clay Science, 137, 233–240.CrossRefGoogle Scholar
Balbay, A., Selvitepe, N. & Saka, C. (2021) Fe doped-CoB catalysts with phosphoric acid-activated montmorillonite as support for efficient hydrogen production via NaBH4 hydrolysis. International Journal of Hydrogen Energy, 46, 425–438.CrossRefGoogle Scholar
Balci, S. (2016) Structural property improvements of bentonite with sulfuric acid activation. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 1, 201–212.Google Scholar
Bergaya, F. & Vayer, M. (1997) CEC of clays: measurement by adsorption of a copper ethylenediamine complex. Applied Clay Science, 12, 275–280.CrossRefGoogle Scholar
Boulaouche, T., Kherroub, D.E., Khimeche, K. & Belbachir, M. (2019) Green strategy for the synthesis of polyurethane by a heterogeneous catalyst based on activated clay. Research on Chemical Intermediates, 45, 3585–3600.CrossRefGoogle Scholar
Carrado, K.A. & Komadel, P. (2009) Acid activation of bentonites and polymer–clay nanocomposites. Elements, 5, 111–116.CrossRefGoogle Scholar
Chen, C., Wu, W., Zeng, X., Jiang, Z. & Shi, L. (2009) Study on several mesoporous materials catalysts applied to the removal of trace olefins from aromatics and commercial sidestream tests. Industrial & Engineering Chemistry Research, 48, 10359–10363.CrossRefGoogle Scholar
Chen, Y., Sun, Z., Cui, Y., Ye, W. & Liu, Q. (2019) Effect of cement solutions on the swelling pressure of compacted GMZ bentonite at different temperatures. Construction Building Materials, 229, 116872.CrossRefGoogle Scholar
Choudhary, T., Pham, T.N. & Uppili, S. (2020) Highly Selective Olefin Removal with Unsulfided Hydrotreating Catalysts. Patent and Trademark Office, Washington, DC. US Patent 10,562,829.Google Scholar
Choudhury, T. (2020) Clay hybrid materials. Pp. 17–32 in: Clay Science and Technology (Do Nascimento, G.M., editor). IntechOpen, London.Google Scholar
Christidis, G., Scott, P. & Dunham, A. (1997) Acid activation and bleaching capacity of bentonites from the islands of Milos and Chios, Aegean, Greece. Applied Clay Science, 12, 329–347.CrossRefGoogle Scholar
Dikmen, S., Yilmaz, G., Yorukogullari, E. & Korkmaz, E. (2012) Zeta potential study of natural- and acid-activated sepiolites in electrolyte solutions. Canadian Journal of Chemical Engineering, 90, 785–792.CrossRefGoogle Scholar
Dill, L.P., Kochepka, D.M., Lima, L.L., Leitão, A.A., Wypych, F. & Cordeiro, C.S. (2021) Brazilian mineral clays: classification, acid activation and application as catalysts for methyl esterification reactions. Journal of the Brazilian Chemical Society, 32, 145–157.Google Scholar
Dutta, D.K. (2019) Recent advances in metal nanoparticles supported on montmorillonite as catalysts for organic synthesis. Journal of Materials NanoScience, 6, 19–31.Google Scholar
El-Geundi, M., Ismail, H. & Attyia, K. (1995) Activated clay as an adsorbent for cationic dyestuffs. Adsorption Science Technology, 12, 109–117.CrossRefGoogle Scholar
Elmorsi, R.R., Mostafa, G.A.H. & Abou-El-Sherbini, K.S. (2021) Homoionic soda-activated bentonite for batch-mode removal of Pb(II) from polluted brackish water. Journal of Environmental Chemical Engineering, 9, 104606.CrossRefGoogle Scholar
Emam, E.A. (2018) Clay adsorption perspective on petroleum refining industry. Industrial Engineering, 2, 19–25.CrossRefGoogle Scholar
Faghihian, H. & Mohammadi, M.H. (2014) Acid activation effect on the catalytic performance of Al-pillared bentonite in alkylation of benzene with olefins. Applied Clay Science, 93, 1–7.CrossRefGoogle Scholar
Fayoyiwa, A.D. (2020) The Effects of the Chemical Composition and Interlayer Cations on the Swelling Pressure of Smectite Clay Minerals: A Molecular Dynamics Study. PhD dissertation. University of Eastern Finland, Kuopio, 49 pp.Google Scholar
Finevich, V., Allert, N., Karpova, T. & Duplyakin, V. (2007) Composite nanomaterials on the basis of acid-activated montmorillonites. Russian Journal of General Chemistry, 77, 2265–2271.CrossRefGoogle Scholar
Guo, H., Zhang, H., Li, Q., Peng, F., Xiong, L., Wang, C. et al. (2020) Removal of olefins from reforming aromatic hydrocarbons over metal-halide-modified acid-activated palygorskite. Energy & Fuels, 34, 9463–9472.CrossRefGoogle Scholar
Hao, J., Wei, Z., Wei, D., Mohamed, T.A., Yu, H., Xie, X. et al. (2019) Roles of adding biochar and montmorillonite alone on reducing the bioavailability of heavy metals during chicken manure composting. Bioresource Technology, 294, 122199.CrossRefGoogle ScholarPubMed
Hayakawa, T., Oya, M., Minase, M., Fujita, K.I., Teepakakorn, A.P. & Ogawa, M. (2019) Preparation of sodium-type bentonite with useful swelling property by a mechanochemical reaction from a weathered bentonite. Applied Clay Science, 175, 124–129.CrossRefGoogle Scholar
Huang, G.Q., Song, Y.H., Liu, C., Yang, J.M., Lu, J., Liu, Z.T. & Liu, Z.W. (2019) Acid activated montmorillonite for gas-phase catalytic dehydration of monoethanolamine. Applied Clay Science, 168, 116–124.CrossRefGoogle Scholar
Javed, U., Khushnood, R.A., Memon, S.A., Jalal, F.E. & Zafar, M.S. (2020) Sustainable incorporation of lime–bentonite clay composite for production of ecofriendly bricks. Journal of Cleaner Production, 263, 121469.CrossRefGoogle Scholar
Komadel, P. (2003) Chemically modified smectites. Clay Minerals, 38, 127–138.CrossRefGoogle Scholar
Komadel, P. & Madejová, J. (2013) Acid activation of clay minerals. Pp. 385–409 in: Developments in Clay Science (Bergaya, F. & Lagaly, G., editors). Elsevier, Amsterdam.Google Scholar
Kumar, A. & Lingfa, P. (2020) Sodium bentonite and kaolin clays: comparative study on their FT-IR, XRF, and XRD. Materials Today: Proceedings, 22, 737–742.Google Scholar
Leporatti, S., Cascione, M., De Matteis, V. & Rinaldi, R. (2020) Design of nano-clays for drug delivery and bio-imaging: can toxicity be an issue? Future Medicine, 15, 2429–2432.Google ScholarPubMed
Li, G., Luan, J., Zeng, X. & Shi, L. (2011) Removal of trace olefins from aromatics over metal-halides-modified clay and its industrial test. Industrial & Engineering Chemistry Research, 50, 6646–6649.CrossRefGoogle Scholar
Liu, J., Liu, N., Ren, K., Shi, L. & Meng, X. (2017) Sulfated zirconia synthesized in a one step solvent-free method for removal of olefins from aromatics. Industrial & Engineering Chemistry Research, 56, 7693–7699.CrossRefGoogle Scholar
Luan, J., Li, G. & Shi, L. (2011) Study of modified clay and its industrial testing in aromatic refining. Industrial & Engineering Chemistry Research, 50, 7150–7154.CrossRefGoogle Scholar
Mahmoud, O., Nasr-El-Din, H.A., Vryzas, Z. & Kelessidis, V.C. (2018) Effect of ferric oxide nanoparticles on the properties of filter cake formed by calcium bentonite-based drilling muds. SPE Drilling Completion, 33, 363–376.CrossRefGoogle Scholar
Mannu, A., Vlahopoulou, G., Sireus, V., Petretto, G.L., Mulas, G. & Garroni, S. (2018) Bentonite as a refining agent in waste cooking oils recycling: flash point, density and color evaluation. Natural Product Communications, 13, 613–616.CrossRefGoogle Scholar
Monteiro, M.K.S., de Oliveira, V.R.L., dos Santos, F.K.G., de Barros Neto, E.L., de Lima Leite, R.H., Aroucha, E.M.M. & de Oliveira Silva, K.N. (2018) Influence of the ionic and nonionic surfactants mixture in the structure and properties of the modified bentonite clay. Journal of Molecular Liquids, 272, 990–998.CrossRefGoogle Scholar
Obayomi, K. & Auta, M.J.H. (2019) Development of microporous activated Aloji clay for adsorption of lead (II) ions from aqueous solution. Heliyon, 5, e02799.CrossRefGoogle ScholarPubMed
Özgüven, F.E., Pekdemir, A.D., Müşerref, Ö. & Sarikaya, Y. (2020) Characterization of a bentonite and its permanent aqueous suspension. Journal of the Turkish Chemical Society Section A: Chemistry, 7, 11–18.Google Scholar
Pérez-Cabrera, L., Diaz-de-León, J., Antúnez-García, J., Galván, D., Alonso-Núñez, G. & Fuentes-Moyado, S. (2019) Isomorphic substitution of Mg2+ by Al3+ on MgO: effects on basicity, textural properties and microstructure. Revista Mexicana de Ingeniería Química, 18, 339–347.CrossRefGoogle Scholar
Prandel, L.V., Dias, N.M.P., da Costa Saab, S., Brinatti, A.M., Giarola, N.F.B. & Pires, L.F. (2017) Characterization of kaolinite in the hardsetting clay fraction using atomic force microscopy, X-ray diffraction, and the Rietveld method. Journal of Soils Sediments, 17, 2144–2155.CrossRefGoogle Scholar
Pu, X., Liu, N., Jiang, Z. & Shi, L. (2012) Acidic and catalytic properties of modified clay for removing trace olefin from aromatics and its industrial test. Industrial & Engineering Chemistry Research, 51, 13891–13896.CrossRefGoogle Scholar
Qin, C., Yuan, X., Xiong, T., Tan, Y.Z. & Wang, H. (2020) Physicochemical properties, metal availability and bacterial community structure in heavy metal-polluted soil remediated by montmorillonite-based amendments. Chemosphere 261, 128010.CrossRefGoogle ScholarPubMed
Qureshi, D., Behera, K.P., Mohanty, D., Mahapatra, S.K., Verma, S., Sukyai, P. et al. 2021 (Synthesis of novel poly (vinyl alcohol)/tamarind gum/bentonite-based composite films for drug delivery applications. Colloids Surfaces A: Physicochemical Engineering Aspects, 613, 126043.CrossRefGoogle Scholar
Rautureau, M., Gomes, C.d.S.F., Liewig, N. & Katouzian-Safadi, M. (2017) Clay and clay mineral definition. Pp. 5–31 in: Clays and Health: Properties and Therapeutic Uses. Springer, Cham.CrossRefGoogle Scholar
Reddy, J.K., Lad, S., Mantri, K., Das, J., Raman, G. & Jasra, R.V. (2020) Zeolite-based catalysts for the removal of trace olefins from aromatic streams. Applied Petrochemical Research, 10, 107–114.CrossRefGoogle Scholar
Rihayat, T., Salim, S., Arlina, A., Fona, Z., Jalal, R., Alam, P. et al. (2018) Determination of CEC value (cation exchange capacity) of bentonites from North Aceh and Bener Meriah, Aceh Province, Indonesia using three methods. P. 012054 in: IOP Conference Series: Materials Science and Engineering (Vol. 334, No. 1). IOP Publishing, Bristol.Google Scholar
Rouhani, H. & Farhadi, F. (2020) Detecting and evaluating detrimental factors of clay's longevity, selecting, and optimizing an appropriate adsorbent for operating time elevation in the separation process of trace olefins from aromatics. Industrial & Engineering Chemistry Research, 59, 2796–2804.CrossRefGoogle Scholar
Rouhani, H., Sarrafi, A. & Tahmooresi, M. (2016) Synthesis of xanthene derivatives over acid activated clay in Kerman Province and kinetic modeling. Chemical Engineering Communications, 203, 289–299.CrossRefGoogle Scholar
Samudrala, S.P., Kandasamy, S. & Bhattacharya, S. (2018) Turning biodiesel waste glycerol into 1,3-propanediol: catalytic performance of sulphuric acid-activated montmorillonite supported platinum catalysts in glycerol hydrogenolysis. Scientific Reports, 8, 7484.CrossRefGoogle ScholarPubMed
Schoonheydt, R.A., Johnston, C.T. & Bergaya, F. (2018) Clay minerals and their surfaces. Pp. 1–21 in :Developments in Clay Science (Bergaya, F. & Lagaly, G., editors). Elsevier, Amsterdam.Google Scholar
Selvitepe, N., Balbay, A. & Saka, C. (2019) Optimisation of sepiolite clay with phosphoric acid treatment as support material for CoB catalyst and application to produce hydrogen from the NaBH4 hydrolysis. International Journal of Hydrogen Energy, 44, 16387–16399.CrossRefGoogle Scholar
Shakiba, M., Kakoei, A., Jafari, I., Rezvani Ghomi, E., Kalaee, M., Zarei, D. et al. (2021) Kinetic modeling and degradation study of liquid polysulfide resin–clay nanocomposite. Molecules, 26, 635.CrossRefGoogle ScholarPubMed
Sims, A.P. (2019) Investigating Effect of Clay Composition on Safety Function Performance in a Geological Disposal Facility (GDF). PhD thesis. University of Manchester, 352 pp.Google Scholar
Stawinski, W.J. (2017) Modified Clay Minerals as High-Effective Adsorbents for Wastewater Laden with Heavy Metals and Textile Dyestuffs. University of Porto, 262 pp.Google Scholar
Sun, Y. & Shi, L. (2011) Removal of trace olefins from aromatics at room temperature using pyridinium and imidazolium ionic liquids. Industrial & Engineering Chemistry Research, 50, 9339–9343.CrossRefGoogle Scholar
Uddin, F. (2018) Montmorillonite: an introduction to properties and utilization. Pp. 3–23 in: Current Topics in the Utilization of Clay in Industrial and Medical Applications (Zoveidavianpoor, M., editor). IntechOpen, London.Google Scholar
Vaculíková, L., Plevová, E. & Ritz, M. (2019) Characterization of montmorillonites by infrared and Raman spectroscopy for preparation of polymer–clay nanocomposites. Journal of Nanoscience Nanotechnology, 19, 2775–2781.CrossRefGoogle ScholarPubMed
Wang, L., Meng, X., Wang, S., Shi, L., Hu, X. & Liu, N. (2021) Research and application of a non-noble metal catalyst in the removal of trace olefins from aromatics. New Journal of Chemistry, 45, 3901–3908.CrossRefGoogle Scholar
Wu, M., Han, H., Ni, L., Zhang, S., Li, S., Wang, Y. et al. (2018) Mesoporous zirconium phosphonate hybrid bentonite as a novel efficient catalyst for the removal of trace olefins from aromatics. Russian Journal of Applied Chemistry, 91, 758–763.CrossRefGoogle Scholar
Xin, Q., Alvarez-Majmutov, A., Dettman, H.D. & Chen, J. (2018) Hydrogenation of olefins in bitumen-derived naphtha over a commercial hydrotreating catalyst. Energy & Fuels, 32, 6167–6175.CrossRefGoogle Scholar
Yang, Y.L., Reddy, K.R., Du, Y.J. & Fan, R.D. (2018) Sodium hexametaphosphate (SHMP)-amended calcium bentonite for slurry trench cutoff walls: workability and microstructure characteristics. Canadian Geotechnical Journal, 55, 528–537.CrossRefGoogle Scholar
Yang, F., Weng, J., Ding, J., Zhao, Z., Qin, L. & Xia, F. (2020) Effective conversion of saccharides into hydroxymethylfurfural catalyzed by a natural clay, attapulgite. Renewable Energy, 151, 829–836.CrossRefGoogle Scholar
Yao, J., Liu, N., Shi, L. & Wang, X. (2015) Sulfated zirconia as a novel and recyclable catalyst for removal of olefins from aromatics. Catalysis Communications, 66, 126–129.CrossRefGoogle Scholar
Yu, H., Zang, J., Liu, G., Hong, M., Chen, R. & Chen, T. (2020) Acid-modified hierarchical porous rare-earth-containing Y zeolite as a highly active and stable catalyst for olefin removal. ACS Omega, 5, 18028–18034.CrossRefGoogle Scholar
Yu, C., Yang, Y., Wu, Z.X., Jiang, J.F., Liao, R. & Deng, Y.F. (2021) Experimental study on the permeability and self-healing capacity of geosynthetic clay liners in heavy metal solutions. Geotextiles Geomembranes, 49, 413–419.CrossRefGoogle Scholar
Yu, W., Wang, P., Zhou, C., Zhao, H., Tong, D., Zhang, H. et al. (2017) Acid-activated and WOx-loaded montmorillonite catalysts and their catalytic behaviors in glycerol dehydration. Chinese Journal of Catalysis, 38, 1087–1100.CrossRefGoogle Scholar